Stain-blocking and mildewcide resistant coating compositions

• US 5,460,644 A
• Filed: 12/14/1993
• Issued: 10/24/1995
• Est. Priority Date: 12/14/1993
• Status: Expired due to Fees

• Current Assignee: The Glidden Company (Nouryon BV)
• Original Assignee: O'Brien Corp. (Ametek Incorporated)
• Inventors: Thomassen, Ivar P.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/166,692
• Time in Patent Office: 679 Days
• Field of Search: 106/15.05, 106/18.36, 106/18.32, 514/494, 424/641, 523/122, 524/395, 524/399, 524/428, 524/434
• US Class Current: 106/18.32
• CPC Class Codes: C08K 3/10 Metal compounds
• CPC Class Codes: C09D 5/14 Paints containing biocides, e.g. fungicides, insecticides or pesticides C09D5/16 takes precedence

Abstract

A stain-blocking, mildewcide and biocide resistant aqueous coating compositions containing synthetic or natural polymer includes a soluble zinc ammonium complex. The zinc ammonium complex has the formula

Zn(NH.sub.3).sup.+2.sub.n X.H.sub.2 O

where n is a number from 4 to 6 and X is selected from a group consisting of acetate, borate, carbonate, citrate and phosphate.

Claims

1. A tannin stain-blocking aqueous coating composition for precipitating tannin stains containing a synthetic or natural polymer and a zinc ammonium complex solution, with said zinc ammonium complex solution being present in an amount of between about 1 to 25 percent by weight of the total weight of the coating composition and having a formula Zn(NH₃)²⁺_n X.H₂ O where n is a number from 4 to 6 and where X is selected from the group consisting of acetate, borate, carbonate, citrate, and phosphate, with said zinc ammonium complex precipitating said tannin stains thereby rendering said tannin stains insoluble.

2. The stain-blocking aqueous coating composition in accordance with claim 1 wherein the synthetic polymer is selected from the group consisting of acrylic acid esters, epoxy, vinyl-acrylic acid esters, styrene-butadiene co-polymers, acrylate-nitrile co-polymers and polyurethane.

3. The stain-blocking aqueous coating composition in accordance with claim 1 wherein the zinc ammonium complex solution is present in an amount of between about 5 to 10 percent by weight of the total weight of the coating composition.

4. The stain-blocking aqueous coating composition in accordance with claim 1 further containing a pigment.

5. The stain-blocking aqueous coating composition in accordance with claim 4 wherein said pigment is selected from the group consisting of titanium dioxide, zinc oxide and extender pigments.

6. The stain-blocking aqueous coating composition in accordance with claim 1 further containing a bactericide in an amount of between 0.1 to 3.0 percent by weight of the total weight of the composition.

7. The stain-blocking aqueous coating composition in accordance with claim 6 wherein said bactericide is selected from the group consisting of 5-chloro-2-methyl-4-isothiazolin-3-one and 1, 2-benzisothiazolin-3-one.

8. The stain-blocking aqueous coating composition in accordance with claim 7 wherein said bactericide is present in an amount of between about 0.25 to 1.0 percent by weight of the total weight of the composition.

9. The stain-blocking aqueous coating composition in accordance with claim 1 further containing a mildewcide in an amount of between 0.25 to 5.0 percent by weight of the total weight of the coating composition.

10. The stain-blocking aqueous coating composition in accordance with claim 9 wherein said mildewcide is selected from the group consisting of 2-N-octyl-4-isothiazolin-3-one, 3-iodo-2-propynyl butyl carbamate and tetrachloroisophthalonitrile.

11. The stain-blocking aqueous coating composition in accordance with claim 10 wherein said mildewcide is present in an amount of between 0.5 to 1.5 percent by weight of the total weight of the composition.

12. The stain-blocking aqueous coating composition in accordance with claim 1 wherein said zinc ammonium complex solution contains between about 25 to 35 percent solids by weight of the zinc ammonium complex.

13. The stain-blocking aqueous coating composition in accordance with claim 12 wherein said zinc ammonium complex solution contains 28 percent solids by weight of the zinc ammonium complex.