Assessment of damage in keratin fibers

• US 5,461,925 A
• Filed: 03/28/1994
• Issued: 10/31/1995
• Est. Priority Date: 03/28/1994
• Status: Expired due to Term

• Current Assignee: Redken Laboratories, Inc. (Cosmair)
• Original Assignee: Redken Laboratories, Inc. (Cosmair)
• Inventors: Cannell, David W., Nguyen, Nghi V., Mathews, Roger A.
• Primary Examiner(s): Chilcot, Jr., Richard E.
• Assistant Examiner(s): Dombroske, George M.
• Application Number:
  US08/218,565
• Time in Patent Office: 582 Days
• Field of Search: 73/795, 73/794, 73/789, 73/817, 73/764, 73/160, 73/828, 73/830, 73/831, 73/834, 73/837
• US Class Current: 73/789
• CPC Class Codes: G01N 2203/0067 Fracture or rupture
• CPC Class Codes: G01N 2203/0089 Biorheological properties
• CPC Class Codes: G01N 2203/0212 Theories, calculations
• CPC Class Codes: G01N 2203/0278 Thin specimens
• CPC Class Codes: G01N 2203/028 One dimensional, e.g. filaments, wires, ropes or cables
• CPC Class Codes: G01N 3/08 by applying steady tensile or compressive forces G01N3/28 takes precedence
• CPC Class Codes: G01N 33/4833 of solid biological material, e.g. tissue samples, cell cultures tissue in vivo A61B5/00; cell suspensions G01N33/48735

Abstract

Keratin fiber condition is evaluated by testing dry hair to determine analysis factors. For each factor, two values of elongation are determined by measuring the force required to obtain a first value and a second value of elongation of the fiber. The percent total elongation of the fiber to its break point is also determined. The ratio of the two measured forces is used with the percent total elongation in empirically derived nonlinear equations to determine analysis factors, such as a condition factor and a moisture factor. It is found that each factor is independent of fiber diameter or the source of the fiber. It is also found that the factors change as a function of subjective or objective measures of chemical damage to, and moisture content of, the hair fiber. The factors can, therefore, be used for identifying hair care products suitable for application to the hair without inducing unacceptable damage. The tests may be performed with simple tensile testing apparatus without tedious examination of the hair under a microscope. Additionally, the hair diameter can be determined by wedging fiber clamps used in the test apparatus.

Claims

1. A method for analyzing keratin fiber comprising the steps of:

measuring a first force required to obtain a first value of elongation of a keratin fiber, wherein the first force is less than the force required to reach the break point elongation region of the force-elongation curve;

measuring a second force required to obtain a second, relatively higher, value of elongation of a keratin fiber wherein the second force is less than the force required to reach the break point elongation region of the force-elongation curve;

determining a force ratio of the second force and the first force;

determining a representation of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber; and

determining at least one analysis factor that is directly proportional to a nonlinear mathematical function of the force ratio and the representation of fiber elongation.

2. A method as recited in claim 1 comprising the substantially concurrent step of determining the diameter of the keratin fiber while measuring the forces.

3. A method as recited in claim 1 comprising the step of determining a logarithmic nonlinear function.

4. A method as recited in claim 1 wherein the nonlinear function is exponential.

5. A method as recited in claim 1 wherein an analysis factor is a condition factor F_c =Logarithm E_B ×

(F₂ /F₁)² ;

wherein E_B is a measured elongation to a break point of the fiber;

wherein F₁ is a measured force of a first elongation;

wherein F₂ is a measured force of a second elongation; and

wherein the Logarithm is a logarithm base 10.

6. A method as recited in claim 1 wherein an analysis factor is a moisture factor F_m =E_B ×

Logarithm (F₄ /F₃);

wherein E_B is a measured elongation to a break point of the fiber;

wherein F₃ is a measured force of a first elongation;

wherein F₄ is a measured force of a second elongation; and

wherein the Logarithm is a logarithm base 10.

7. A method as recited in claim 1 wherein the analysis factor is a measure of moisture content of a keratin fiber.

8. A method as recited in claim 1 wherein the analysis factor is a measure of cysteic acid content of a keratin fiber.

9. A method as recited in claim 1 comprising the step of selecting a hair care product as a function of at least one such analysis factor.

10. A method for analyzing keratin fiber comprising the steps of:

measuring a first force required to obtain a first value of elongation of a keratin fiber, wherein the first force is less than the force required to reach the break point elongation region of the force-elongation curve;

measuring a second force required to obtain a second, relatively higher, value of elongation of a keratin fiber wherein the second force is less than the force required to reach the break point elongation region of the force-elongation curve;

determining a force ratio of the second force and the first force;

determining a representation of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber; and

determining at least one analysis factor that is a measure of moisture content of a keratin fiber that is directly proportional to the mathematical product of the representation of fiber elongation and the logarithm of the force ratio.

11. A method for analyzing keratin fiber comprising the steps of:

measuring a first force required to obtain a first value of elongation of a keratin fiber, wherein the first force is less than the force required to reach the break point elongation region of the force-elongation curve;

measuring a second force required to obtain a second, relatively higher, value of elongation of a keratin fiber wherein the second force is less than the force required to reach the break point elongation region of the force-elongation curve;

determining a force ratio of the second force and the first force;

determining a representation of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber; and

determining at least one analysis factor that is a measure of cysteic acid content of a keratin fiber that is directly proportional to the mathematical product of the logarithm of the representation of fiber elongation and the square of the force ratio.

12. A method for evaluating the condition of hair comprising the steps of:

measuring the force required to elongate a strand of hair a first percentage of its length;

measuring the force required to elongate the strand of hair a second percentage of its length;

determining a force ratio between the first and second forces;

determining a measure of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber; and

determining at least one analysis factor that is proportional to the force ratio and the measure of fiber elongation at the break point of the fiber, wherein the proportionality is to the logarithm of the measure of fiber elongation to the break point of the fiber.

13. A method as recited in claim 12 wherein the first and second percentages each lie within the range defined by the yield and post-yield regions of a force-elongation curve of the strand.

14. A method as recited in claim 12 comprising the step of selecting a hair care product as a function of at least one such analysis factor.

15. A method for evaluating the condition of hair comprising the steps of:

measuring the force required to elongate a strand of hair a first percentage of its length;

measuring the force required to elongate the strand of hair a second percentage of its length;

determining a force ratio between the first and second forces;

determining a measure of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber; and

determining at least one analysis factor that is proportional to the force ratio and the measure of fiber elongation at the break point of the fiber, wherein the proportionality is to the logarithm of the force ratio.

16. A method as recited in claim 15 wherein the first and second percentages each lie within the range defined by the yield and post-yield regions of a force-elongation curve of the strand.

17. A method as recited in claim 15 comprising the step of selecting a hair care product as a function of at least one such analysis factor.

18. A method for evaluating the condition of hair comprising the steps of:

measuring the force required to elongate a strand of hair a first percentage of its length;

measuring the force required to elongate the strand of hair a second percentage of its length;

determining a force ratio between the first and second forces;

determining a measure of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber; and

determining at least one analysis factor that is proportional to the force ratio and the measure of fiber elongation at the break point of the fiber, wherein the proportionality is to the square of the force ratio.

19. A method for evaluating the condition of hair comprising the steps of:

measuring the force required to elongate a strand of hair a first percentage of its length;

measuring the force required to elongate the strand of hair a second percentage of its length;

determining a force ratio between the first and second forces;

determining a measure of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber;

determining at least one analysis factor that is proportional to the force ratio and the measure of fiber elongation at the break point of the fiber; and

determining the moisture content of a keratin fiber as a function of the determined analysis factor.

20. A method as recited in claim 19 wherein the first and second percentages each lie within the range defined by the yield and post-yield regions of a force-elongation curve of the strand.

21. A method as recited in claim 19 comprising the step of selecting a hair care product as a function of at least one such analysis factor.

22. Apparatus for assessing condition of a keratin fiber comprising:

means for applying an elongating force to a keratin fiber;

means connected to the means for applying force, for determining a ratio of forces required to obtain each of two selected values of elongation of the keratin fiber within the range defined by the yield and post-yield regions of the force-elongation curve for the fiber;

means connected to the means for applying force, for determining fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber;

means for determining the fiber diameter by determining a distance from a means for clamping without a fiber present to the means for clamping with a fiber present, wherein the means for clamping is moved along a line that converges relative to a length of the fiber;

means connected to the means for determining a ratio and to the means for determining a quantity of fiber elongation, for determining at least one analysis factor as a function of both the force ratio and the quantity of elongation; and

means connected to the means for determining at least one analysis factor, for displaying at least one analysis factor.

23. Apparatus as recited in claim 22 wherein the means for displaying comprises means for displaying a cysteic acid index which is a function of at least one analysis factor.

24. Apparatus as recited in claim 22 wherein the means for displaying comprises means for displaying a moisture index which is a function of at least one analysis factor.

25. Apparatus as recited in claim 22 further comprising means for selecting a hair care product as a function of at least one such analysis factor.

26. Apparatus for evaluating condition of hair comprising:

means for elongating a hair fiber;

means connected to the means for elongating, for measuring force applied to the fiber at each of first and second selected elongations;

means connected to the means for measuring, for determining the ratio of the first and second forces;

means connected to the means for elongating, for determining an assessment of fiber elongation that occurs as measured from substantially no elongation to a break point of the fiber;

means connected to the means for determining a ratio and to the means for determining an assessment of fiber elongation, for determining at least one analysis factor that is proportionally related to a nonlinear equation of the force ratio and the assessment of fiber elongation; and

means connected to the means for determining at least one analysis factor, for displaying at least one analysis factor.

27. Apparatus as recited in claim 26 wherein the means for determining a nonlinear mathematical function comprises means for determining an exponential function of the force ratio.

28. Apparatus as recited in claim 26 wherein the means for determining a nonlinear mathematical function comprises means for determining a logarithm function of the force ratio.

29. Apparatus as recited in claim 26 wherein the means for determining a nonlinear mathematical function comprises means for determining a logarithm function of the assessment of fiber elongation.

30. Apparatus as recited in claim 26 wherein the means for displaying comprises means for displaying a moisture index which is a function of at least one analysis factor.

31. Apparatus as recited in claim 26 wherein the means for displaying comprises means for displaying a cysteic acid index which is a function of at least one analysis factor.

32. Apparatus as recited in claim 26 further comprising means for selecting a hair care product as a function of at least one such analysis factor.

33. A method for analysis of keratin fibers comprising:

determining a fiber "condition factor," designated F_c, according to the following equation;

space="preserve" listing-type="equation">F.sub.c =Logarithm E.sub.B ×

(F.sub.2 /F.sub.1).sup.2 ;

wherein E_B is a measured elongation to a break point of the fiber;

wherein F₁ is a measured force of a first elongation;

wherein F₂ is a measured force of a second elongation;

wherein the Logarithm is a logarithm base 10; and

determining the cysteic acid content of a keratin fiber as a function of the determined condition factor.

34. A method for analysis of keratin fibers comprising:

determining a fiber "moisture factor," designated F_m, according to the following equation;

space="preserve" listing-type="equation">F.sub.m =E.sub.B ×

Logarithm (F.sub.4 /F.sub.3);

wherein E_B is a measured elongation to a break point of the fiber;

wherein F₃ is a measured force of a first elongation;

wherein F₄ is a measured force of a second elongation;

wherein the Logarithm is a logarithm base 10; and

determining the moisture content of a keratin fiber as a function of the determined moisture factor.

35. A method as recited in claim 34 comprising the step of selecting a hair care product as a function of at least one such moisture factor.

36. A method as recited in claim 34 comprising the step of selecting a hair care product as a function of at least one such moisture factor and at least one factor related to hair condition.

37. Apparatus for clamping and determining the diameter of a hair fiber comprising:

a fixed surface for receiving a hair fiber;

a member movable along a path parallel to the length of a fiber on the fixed surface and converging toward the fixed surface for clamping the fiber;

means for measuring travel of the movable member in a direction along the length of the fiber; and

means for determining the thickness of the fiber as a trigonometric function of travel of the movable member.

38. Apparatus as recited in claim 37 wherein the means for measuring travel comprises:

means for measuring travel of the movable member parallel to the fiber, and further comprising

means for multiplying the distance traveled by the tangent of the angle of convergence.

39. Apparatus as recited in claim 37 wherein the movable member comprises a cylindrical surface.

40. Apparatus as recited in claim 37 comprising a stepping motor for moving the movable member and the means for measuring travel comprises means for counting the number of steps between a first position where the member is in contact with the fixed surface and a second position where the member is in contact with a hair fiber clamped between the member and the fixed surface.

41. A method for measuring hair diameter comprising the steps of:

placing a hair fiber on a flat surface;

moving a member along a path converging toward the flat surface until the member engages the hair fiber and clamps the hair fiber between the member and the flat surface;

determining the distance between the locus of the member when engaged with the hair fiber and the locus of the member when engaged with the flat surface; and

multiplying the distance by a trigonometric function of the angle of convergence.

42. A method comprising performing the clamping, determining, and multiplying steps as recited in claim 41 on a second portion of the hair fiber and averaging the diameters determined.

43. A method as recited in claim 41 further comprising the steps of:

wedging a part of the fiber between the member and the flat surface with sufficient pressure to immobilize the fiber such that a portion of the fiber can be elongated to a break point of the fiber.

44. A method as recited in claim 41 comprising counting the number of steps of a stepping motor between a first position where the member is in contact with the fixed surface and a second position where the member is in contact with a hair fiber clamped between the member and the fixed surface.