Method and system for photocatalytic decontamination

• US 5,462,674 A
• Filed: 03/03/1994
• Issued: 10/31/1995
• Est. Priority Date: 03/03/1994
• Status: Expired due to Term

• Current Assignee: Purifics Environmental Technologies Incorporated
• Original Assignee: Purifics Environmental Technologies Incorporated
• Inventors: Powell, Anthony L., Butters, Brian E.
• Primary Examiner(s): McCarthy, Neil
• Application Number:
  US08/205,699
• Time in Patent Office: 607 Days
• Field of Search: 210/763, 210/748, 210/321.8, 210/321.69, 210/408, 210/791
• US Class Current: 210/748.11
• CPC Class Codes: C02F 1/325 Irradiation devices or lamp constructions
• CPC Class Codes: C02F 2201/3223 Single elongated lamp located on the central axis of a turbular reactor
• CPC Class Codes: C02F 2201/326 Lamp control systems

Abstract

A method and system for purifying a contaminated fluid in a continuous manner is herein disclosed. The present invention provides for the irradiation of a slurry between a defined surface(s) such that substantially all of the contaminants are removed from the slurry, and a turbulent flow of the slurry is achieved. The present invention further provides for the separation of decontaminated effluent from the slurry by employing ceramic membrane filters. Air is applied to the ceramic membrane filters at relatively high pressures in order to remove any photoreactive catalyst particles that have collected in the ceramic membranes.

Claims

1. A method for purifying a contaminated fluid, comprising:

mixing a contaminated fluid with a photocatalyst to form a slurry;

passing the slurry through a space irradiated by ultraviolet light to bring about a photocatalytic reaction of the slurry whereby decontaminated effluents are rendered in the slurry;

segregating the decontaminated effluents from the slurry by filtration through a plurality of ceramic filter elements;

intermittently removing any collections of photocatalyst in the plural ceramic filter elements by passing a shock wave therethrough; and

repeating the above steps with a substantially constant charge of photocatalyst.

2. The method according to claim 1, wherein:

the shock wave is generated by applying a pressure of at least 25 psi.

3. The method according to claim 1, further comprising:

detecting a magnitude of the contaminants in the slurry; and

continuously repeating the method with a constant charge of photocatalyst until a selected level of contaminants is reached.

4. The method according to claim 1, wherein:

the photocatalyst is TiO₂.

5. The method according to claim 1, wherein:

the photocatalyst is selected from the group consisting of TiO₂, ZnO, CdS, CdSe, SnO₂, SvTiO₃, WO₃, Fe₂ O₃, and Ta₂ O₅.

6. The method according to claim 1, wherein:

the distance across the irradiated space is substantially equal to the sum of a diameter of a photocatalyst particle and the diameter of a contaminant molecule.

7. The method according to claim 6, wherein:

the space induces the turbulent flow of slurry therebetween.

8. The method according to claim 7, wherein:

the surfaces that define the irradiated space are textured.

9. A method for the purification of fluid containing contaminant compounds, comprising:

mixing the fluid with anatase TiO₂ to form a slurry;

exposing the slurry to ultraviolet light through an irradiated annulus to effect an oxidation of the contaminant compounds, the oxidation providing a decontaminated effluent in the slurry;

passing the slurry through one or more ceramic membrane filters;

recovering the decontaminated effluent once it is segregated from the slurry; and

removing collections of anatase TiO₂ from the plural ceramic membrane filters by applying a shock wave through the ceramic membrane filter(s).

10. The method according to claim 9, further comprising:

adding an oxidant to the slurry.

11. The method according to claim 10, wherein:

the oxidant is peroxide.

12. The method according to claim 10, wherein:

the oxidant is oxygen.

13. The method according to claim 10, wherein:

the oxidant is air.

14. A method for purifying a contaminated fluid, comprising:

mixing a contaminated fluid with anatase TiO₂ particles to form a slurry;

passing the slurry through an annulus that is exposed to an ultraviolet light source;

irradiating the slurry with the light source to effect a photocatalytic reaction;

supplying the irradiated slurry to one or more ceramic membrane filters to provide a retentate;

intermittently removing collections of TiO₂ particles from the ceramic membrane filter(s); and

intermittently removing metals deposited on some of the TiO₂ particles present in the slurry.

15. The method according to claim 14, wherein:

the annulus is defined by a plurality of surfaces having a radial distance therebetween, the radial distance between the surfaces defining the annulus being approximately 1 mm or less.

16. The method according to claim 14, further comprising:

recirculating some of the retentate through the ceramic membrane filter(s).

17. The method according to claim 16, further comprising:

mixing the retentate not recirculated through the ceramic membrane filter(s) with a decontaminated fluid.

18. The method according to claim 16, wherein the step of intermittently removing metals from some of the TiO₂ particles present in the slurry includes:

isolating a portion of the slurry;

separating the TiO₂ particles from the slurry portion; and

removing metal deposits from the separated TiO₂ particles by applying a chemical solution thereto.

19. The method according to claim 18, wherein:

the isolated portion of the slurry is replaced with a substantially equal portion of slurry having metal deposits already removed therefrom.

20. A method for purifying a contaminated fluid, comprising:

mixing the contaminated fluid with TiO₂ particles to form a slurry;

treating the slurry through photocatalysis by irradiating the slurry with ultraviolet light as it passes through an irradiated annulus so as to render a decontaminated effluent in the slurry;

separating the decontaminated fluid from the slurry by passing the slurry through one or more ceramic membrane filters;

periodically removing collections of TiO₂ particles from the plural ceramic membrane filter(s); and

concurrently repeating the steps of treating of the slurry and separating the decontaminated effluent from the slurry to different portions of the slurry.

21. The method according to claim 20, wherein:

a substantially constant charge of TiO₂ particles are used in association with the method.