Light valve employing a film comprising an encapsulated liquid suspension, and method of making such film

• US 5,463,491 A
• Filed: 11/06/1992
• Issued: 10/31/1995
• Est. Priority Date: 11/01/1991
• Status: Expired due to Term

• Current Assignee: Research Frontiers Incorporated
• Original Assignee: Research Frontiers Incorporated
• Inventors: Check, III, Joseph A.
• Primary Examiner(s): Epps, Georgia Y.
• Assistant Examiner(s): Robbins, Thomas
• Application Number:
  US07/972,826
• Time in Patent Office: 1,089 Days
• Field of Search: 359/296, 359/52, 252/582, 252/583, 252/585
• US Class Current: 359/296
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: G02F 1/172 based on a suspension of orientable dipolar particles, e.g. suspended particles displays

Abstract

A film suitable for use as the light modulating unit of a light valve comprises a cross-linked polymer matrix having droplets of a liquid light valve suspension distributed in the cross-linked polymer matrix, and a light valve comprising such a film.

Claims

1. A film suitable for use as the light-modulating unit of a light valve, comprising a cross-linked polymer matrix having droplets of a liquid light valve suspension distributed in and in direct contact with the cross-linked poller matrix, said liquid light valve suspension comprising organic particles suspended in a liquid suspending medium.

2. The film according to claim 1, wherein said liquid suspending medium is electrically resistive and has a polymeric stabilizer dissolved therein that prevents agglomeration of said particles.

3. The film according to claim 1, wherein said suspension is in the form of droplets that are substantially disconnected from one another.

4. The film according to claim 1, wherein said cross-linked poller selected matrix is selected from the group consisting of a cross-linked polybutadiene, cross-linked polystyrene, cross-linked polyacrylamide, cross-linked polyester, cross-linked polyether, cross-linked polyurethane and cross-linked polyalkene.

5. The film according to claim 1, wherein an electrode is in contact with each surface of the film.

6. The film according to claim 1, wherein an electrode is in contact with each surface of the film and a protective layer is in contact with the outer surface of each of said electrodes.

7. The film according to claim 1, wherein a protective layer is in contact with both surfaces of the film.

8. The film according to claim 1, wherein a protective layer is in contact with each surface of the film and an electrode is in contact with the outer surface of each of the protective layers.

9. In a light valve having opposed cell walls, the improvement wherein the film according to claim 1 is between said cell walls as the light-modulating unit of the light valve.

12. The film according to claim 2, wherein the film is swollen with liquid toluene or xylene or a liquid, low molecular weight fluorocarbon polymer having a specific gravity of at least 1.5 and having at least about 50% of its atoms constituted by halogen atoms, at least 60% of the halogen atoms being fluorine and the balance chlorine and/or bromine.

13. The film according to claim 2, wherein said particles are organic particles.

14. The film according to claim 2, wherein said particles are light-polarizing.

10. A film suitable for use as the light-modulating unit of a light valve, comprising a cross-linked polymer matrix in the form of a film having droplets of a liquid light valve suspension distributed in the cross-linked polymer matrix, said liquid light valve suspension comprising particles suspended in a liquid suspending medium, said film, while in its cured, cross-linked form, having been swollen with a liquid applied to the surface thereof to form a liquid-swollen film that is less light-scattering as compared to said film prior to being swollen with said liquid.

11. The film according to claim 10, wherein the film is swollen with a liquid selected from the group consisting of liquid aliphatic ester, ether, straight or branched chain aliphatic, cycloalipatic or aromatic hydrocarbon and halogenated or perhalogented hydrocarbon.

15. In a light valve having opposed cell walls, the improvement wherein the film according to claim 10 is between said cell walls as the light-modulating unit of the light valve.

16. A film suitable for use as the light-modulating unit of a light valve, comprising a cross-linked polyorganosiloxane polymer matrix having droplets of a liquid light valve suspension distributed in the cross-linked polyorganosiloxane polymer matrix, said light valve suspension comprising particles suspended in a liquid suspending medium.

17. The film according to claim 16, wherein said cross-linked polyorganosiloxane polymer is a polyorganosiloxane homopolymer or copolymer.

18. The film according to claim 16, wherein said cross-linked polyorganosiloxane polymer is a cross-linked polydimethylsiloxane polymer.

19. The film according to claim 16, wherein said cross-linked polyorganosiloxane polymer is a cross-linked polyorganosiloxane copolymer of a polydimethylsiloxane and a polyalkylphenylsiloxane.

20. The film according to claim 16, wherein said film, while in its cured, cross-linked form, has been swollen with a liquid to form a liquid-swollen film that is less light-scattering as compared to said film prior to being swollen with said liquid.

21. The film according to claim 20, wherein the film is swollen with a liquid selected from the group consisting of liquid aliphatic ester, ether, straight or branched chain aliphatic, cycloalipatic or aromatic hydrocarbon and halogenated or perhalogented hydrocarbon.

22. The film according to claim 20, wherein the film is swollen with liquid toluene or xylene or a liquid, low molecular weight fluorocarbon polymer having a specific gravity of at least 1.5 and having at least about 50% of its atoms constituted by halogen atoms, at least 60% of the halogen atoms being fluorine and the balance chlorine and/or bromine.

23. In a light valve having opposed cell walls, the improvement wherein the film according to claim 16 is between said cell walls as the light-modulating unit of the light valve.

24. A method of preparing a film suitable for use as the light-modulating unit of a light valve, comprising a cross-linked polyorganosiloxane polymer matrix having droplets of a liquid light valve suspension distributed in the cross-linked polyorganosiloxane polymer matrix, said light valve suspension comprising particles suspended in a liquid suspending medium;

which comprises admixing a liquid cross-linkable polyorganosiloxane oligomer or polymer, said liquid light valve suspension and a copolymer of an organosiloxane and a copolymerizable organic monomer as emulsifier, emulsifying the resulting admixture to form an emulsion of said liquid light valve suspension in said cross-linkable liquid polyorganosiloxane oligomer or polymer, and cross-liking said cross-linkable liquid polyorganosiloxane oligomer or polymer while said admixture is in the form of a thin layer of said emulsion.