Silicone/acrylate vibration dampers

• US 5,464,659 A
• Filed: 09/13/1993
• Issued: 11/07/1995
• Est. Priority Date: 05/23/1991
• Status: Expired due to Fees

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Melancon, Kurt C., Driscoll, William A.
• Primary Examiner(s): Yoon, Tae H.
• Application Number:
  US08/121,031
• Time in Patent Office: 785 Days
• Field of Search: 525/477, 525/478, 525/479, 528/12, 528/26, 528/30, 528/148, 427/209, 427/387, 427/388.2
• US Class Current: 427/387
• CPC Class Codes: C08F 220/10 Esters
• CPC Class Codes: C08F 283/00 Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
• CPC Class Codes: C08F 283/12 on to polysiloxanes
• CPC Class Codes: C09J 4/00 Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
• CPC Class Codes: C09J 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
• CPC Class Codes: Y10T 428/249985 Composition of adhesive or bonding component specified
• CPC Class Codes: Y10T 428/2804 Next to metal
• CPC Class Codes: Y10T 428/2809 including irradiated or wave energy treated component
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers

Abstract

A method of vibrationally damping article, comprising applying to the article a vibration damper comprising a radiation curable vibration damping material which comprises (a) from about 5 parts to about 95 parts by weight acrylic monomer and (b) correspondingly, from about 95 parts to about 5 parts by weight of a silicone adhesive, wherein the sum of (a) plus (b) equal 100 parts by weight, whereby the vibration damper vibrationally damps the article.

Claims

1. A method of vibrationally damping an article, comprising applying a vibration damper to the article, wherein the vibration damper is the polymerization product of a radiation curable material that comprises (a) from about 5 parts to about 95 parts by weight polymerizable acrylic monomer and (b) correspondingly, from about 95 parts to about 5 parts by weight of a preformed silicone adhesive that is the reaction product of one or more polydiorganosiloxanes and one or more copolymeric silicone resins;

wherein the sum of (a) plus (b) equals 100 parts by weight, whereby the vibration damper vibrationally damps the article.

2. A method according to claim 1 wherein the radiation curable material comprises:

(a) from about 5 parts to about 95 parts by weight polymerizable acrylic monomer wherein the polymerizable acrylic monomer comprises;

(i) from about 5 parts to about 100 parts by weight of an alkyl acrylate monomer, the alkyl groups of which have an average of about 4 to about 14 carbon atoms; and

(ii) correspondingly, from about 95 parts to about 0 parts by weight of a monoethylenically unsaturated modifier monomer copolymerizable with the alkyl acrylate monomer;

wherein the sum of (i) plus (ii) equals 100 parts by weight of the polymerizable acrylic monomer; and

(b) correspondingly, from about 95 parts to about 5 parts by weight of a preformed silicone adhesive wherein the sum of (a) plus (b) equals 100 parts by weight;

(c) optionally, up to about 5 parts by weight of a photoinitiator based upon 100 parts by weight of the polymerizable acrylic monomer; and

(d) optionally, up to about 5 parts by weight of a crosslinker based upon 100 parts by weight of (a) plus (b).

3. A method according to claim 2 wherein the modifier monomer is selected such that a homopolymer thereof has a glass transition temperature which is greater than the glass transition temperature of a homopolymer of the alkyl acrylate monomer.

4. A method according to claim 1 wherein the radiation curable material comprises (a) from about 30 parts to about 95 parts by weight polymerizable acrylic monomer and, (b) correspondingly, from about 70 parts to about 5 parts by weight preformed silicone adhesive wherein the sum of (a) plus (b) equals 100 parts by weight.

15. A method according to claim 1 wherein the preformed silicone adhesive is dissolved in the polymerizable acrylic monomer prior to polymerization of the radiation curable material.

5. A method of vibrationally damping an article comprising applying a vibration damper to the article, wherein the vibration damper is the polymerization product of a radiation curable material that consists essentially of (a) from about 5 parts to about 95 parts by weight polymerizable acrylic monomer and (b) correspondingly, from about 95 parts to about 5 parts by weight of a preformed silicone adhesive that is the reaction product of one or more polydiorganosiloxanes and one or more copolymeric silicone resins;

wherein the sum of (a) plus (b) equals 100 parts by weight, whereby the vibration damper vibrationally damps the article.

6. A method according to claim 5 wherein radiation curable material consists essentially of:

(a) from about 5 parts to about 95 parts by weight polymerizable acrylic monomer wherein the polymerizable acrylic monomer comprises;

(i) from about 5 parts to about 100 parts by weight of an alkyl acrylate monomer, the alkyl groups of which have an average of about 4 to about 14 carbon atoms; and

(ii) correspondingly, from about 95 parts to about 0 parts by weight of a monoethylenically unsaturated modifier monomer copolymerizable with the alkyl acrylate monomer;

wherein the sum of (i) plus (ii) equals 100 parts by weight of the polymerizable acrylic monomer; and

(b) correspondingly, from about 95 parts to about 5 parts by weight of a preformed silicone adhesive wherein the sum of (a) plus (b) equals 100 parts by weight;

(c) optionally, up to about 5 parts by weight of a photoinitiator based upon 100 parts by weight of the polymerizable acrylic monomer; and

(d) optionally, up to about 5 parts by weight of a crosslinker based upon 100 parts by weight of (a) plus (b).

7. A method according to claim 6 wherein the modifier monomer is selected such that a homopolymer thereof has a glass transition temperature which is greater than the glass transition temperature of a homopolymer of the alkyl acrylate monomer.

8. A method according to claim 5 wherein the radiation curable material consists essentially of (a) from about 30 parts to about 95 parts by weight polymerizable acrylic monomer and, (b) correspondingly, from about 70 parts to about 5 parts by weight preformed silicone adhesive wherein the sum of (a) plus (b) equals 100 parts by weight.

16. A method according to claim 5 wherein the preformed silicone adhesive is dissolved in the polymerizable acrylic monomer prior to polymerization of the radiation curable material.

9. A method of vibrationally damping an article comprising applying a vibration damper to the article, wherein the vibration damper is the polymerization product of a radiation curable material that comprises:

(a) from about 5 parts to about 95 parts by weight polymerizable acrylic monomer;

(b) correspondingly, from about 95 parts to about 5 parts by weight of a preformed silicone adhesive that is the reaction product of one or more polydiorganosiloxanes and one or more copolymeric silicone resins;

wherein the sum of (a) plus (b) equals 100 parts by weight; and

(c) from about 0.01 to about 5 parts by weight of a photoinitiator based upon 100 parts by weight of the polymerizable acrylic monomer;

whereby the vibration damper vibrationally damps the article.

10. A method according to claim 9 wherein the radiation curable material comprises:

(a) from about 5 parts to about 95 parts by weight polymerizable acrylic monomer wherein the polymerizable acrylic monomer comprises;

(i) from about 5 parts to about 100 parts by weight of an alkyl acrylate monomer, the alkyl groups of which have an average of about 4 to about 14 carbon atoms; and

(ii) correspondingly, from about 95 parts to about 0 parts by weight of a monoethylenically unsaturated modifier monomer copolymerizable with the alkyl acrylate monomer;

wherein the sum of (i) plus (ii) equals 100 parts by weight of the polymerizable acrylic monomer; and

(b) correspondingly, from about 95 parts to about 5 parts by weight of a preformed silicone adhesive wherein the sum of (a) plus (b) equals 100 parts by weight; and

(c) optionally, up to about 5 parts by weight of a crosslinker based upon 100 parts by weight of (a) plus (b).

11. A method according to claim 10 wherein the radiation curable material comprises from about 0.01 to about 2 parts by weight of the photoinitiator.

12. A method according to claim 11 wherein the radiation curable material comprises from about 0.01 to about 5 parts by weight of the crosslinker.

13. A method according to claim 10 wherein the radiation curable material comprises (a) from about 30 parts to about 95 parts by weight polymerizable acrylic monomer and, (b) correspondingly, from about 70 parts to about 5 parts by weight preformed silicone adhesive wherein the sum of (a) plus (b) equals 100 parts by weight.

14. A method according to claim 9 wherein the radiation curable material was polymerized by ultraviolet radiation.

17. A method according to claim 9 wherein the preformed silicone adhesive is dissolved in the polymerizable acrylic monomer prior to polymerization of the radiation curable material.