Production of toner for developing electrostatic images

• US 5,464,722 A
• Filed: 01/03/1994
• Issued: 11/07/1995
• Est. Priority Date: 01/11/1993
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Kobori, Takakuni, Yusa, Hiroshi, Tomiyama, Koichi
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US08/176,231
• Time in Patent Office: 673 Days
• Field of Search: 430/109, 430/110, 430/137
• US Class Current: 430/137.21
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C09C 1/3081 Treatment with organo-silicon compounds
• CPC Class Codes: C09C 1/3684 Treatment with organo-silicon compounds
• CPC Class Codes: G03G 9/081 by mixing the toner components in a liquefied state; melt kneading; reactive mixing
• CPC Class Codes: G03G 9/0817 Separation; Classifying

Abstract

A toner for developing electrostatic images is produced through a process including the steps of: pre-mixing binder resin particles carrying or containing inorganic fine powder to prepare a premix; melt-kneading the premix to obtain a kneaded product; cooling the kneaded product to obtain a colored resinous solid; pulverizing the colored resinous solid to obtain a pulverized product; and classifying the pulverized product to obtain toner particles. The inclusion of the resin particles carrying or containing inorganic fine powder improves the performance of the pre-mixing to provide an improved dispersion of toner materials within the product toner particles. A fine powder fraction from the classifying step can also be recycled to the premixing step. The resin particles can be toner particles per se. The inorganic fine powder may preferably be silica fine powder treated with silicone oil.

Claims

1. A process for producing a toner for developing electrostatic images, comprising:

pre-mixing binder resin particles, a colorant and resin particles carrying or containing inorganic fine powder to prepare a premix,

melt-kneading the premix to obtain a kneaded product,

cooling the kneaded product to obtain a colored resinous solid,

pulverizing the colored resinous solid to obtain a pulverized product, and

classifying the pulverized product to obtain toner particles.

2. The process according to claim 1, wherein the inorganic fine powder has been externally added to the surfaces of the resin particles prior to the premixing.

3. The process according to claim 1, wherein said inorganic fine powder comprises silica fine powder.

4. The process according to claim 3, wherein said inorganic fine powder comprises hydrophobic silica fine powder.

5. The process according to claim 4, wherein said inorganic fine powder comprises hydrophobic silica fine powder treated with silicone oil.

6. The process according to claim 1, wherein said inorganic fine powder comprises hydrophobic titanium oxide fine powder.

7. The process according to claim 6, wherein said inorganic fine powder comprises hydrophobic titanium oxide fine powder.

8. The process according to claim 7, wherein said inorganic fine powder comprises hydrophobic titanium oxide fine powder treated with silicone oil.

9. The process according to claim 1, wherein said inorganic fine powder is carried or contained by the resin particles in the form of particles having a secondary particle size of at most 100 mμ

prior to the pre-mixing.

10. The process according to claim 1, wherein said pulverized product is classified into at least coarse powder, medium powder and fine powder, and the classified fine powder is recycled to the pre-mixing.

11. The process according to claim 1, wherein said resin particles carrying or containing inorganic fine powder are contained in a proportion of 1-50 wt. % of the premix.

12. The process according to claim 10, wherein the recycled fine powder and said resin particles carrying or containing inorganic fine powder are contained in a proportion in total of 2-60 wt. % of the premix.

13. The process according to claim 12, wherein the recycled fine powder and said resin particles carrying or containing inorganic fine powder are contained in a weight ratio of 1:

20 to 20;

1 in the premix.

14. The process according to claim 1, wherein the inorganic fine powder comprises hydrophobic silica fine powder treated with silicone oil, the hydrophobic silica fine powder is dry-blended with resin particles in advance to be carried on the surfaces of the resin particles in the form of secondary particles having an average particle size of at most 100 mμ

, and the resin particles carrying the inorganic fine powder, the binder resin powders and the colorant are subjected to the pre-mixing.

15. The process according to claim 1, wherein the inorganic fine powder comprises hydrophobic silica fine powder treated with silicone oil, the hydrophobic silica fine powder is dry-blended with resin particles in advance to be carried on the surfaces of the resin particles in the form of secondary particles having an average particle size of at most 100 mμ

, the dry-blend of the hydrophobic silica fine powder and the resin particles are shaped into resin particles, and the resultant resin particles containing the inorganic fine powder, the binder resin powders and the colorant are subjected to the pre-mixing.

16. The process according to claim 1, wherein the binder resin particles have a number-average particle size of 10-1000 μ

m.

17. The process according to claim 1, wherein the colorant has a number-average particle size of at most 3 μ

m.

18. The process according to claim 1, wherein said premix contains 100 wt. parts of the binder resin particles, 2-150 wt. parts of the colorant, 0.1-5 wt. parts of the inorganic fine powder and 1-50 wt. parts of the resin particles.

19. The process according to claim 1, wherein said inorganic fine powder comprises silica fine powder and said resin particles comprise toner particles.

20. The process according to claim 19, wherein said inorganic fine powder comprises hydrophobic silica fine powder.

21. The process according to claim 19, wherein said inorganic fine powder comprises hydrophobic silica fine powder treated with silicone oil.

22. The process according to claim 1, wherein said inorganic fine powder comprises titanium oxide fine powder, and said resin particles comprise toner particles.

23. The process according to claim 22, wherein said inorganic fine powder comprises hydrophobic titanium oxide fine powder.

24. The process according to claim 22, wherein said inorganic fine powder comprises hydrophobic titanium oxide fine powder treated with silicone oil.

25. The process according to claim 5, wherein 100 wt. parts of the silica fine powder has been treated with 1-35 wt. parts of silicone oil.

26. The process according to claim 8, wherein 100 wt. parts of the titanium oxide fine powder has been treated with 1-35 wt. parts of silicone oil.

27. The process according to claim 1, wherein the inorganic fine powder has been treated with silicone oil, and the binder resin particles, the colorant and the resin particles carrying or containing the inorganic fine powder treated with silicone oil are pre-mixed under the action of a shearing force by means of a blender having plural stirring blades.

28. The process according to claim 1, wherein the premix is melt-kneaded by means of an extruder having a kneading shaft length L and a diameter D satisfying a ratio L/D in the range of 17-50.

29. A toner for developing electrostatic images, comprising toner particles each containing a binder resin, a colorant and inorganic fine powder, said toner particles having been produced through a process according to any one of claims 1-28.