Laser machining of ceramic cores

• US 5,465,780 A
• Filed: 11/23/1993
• Issued: 11/14/1995
• Est. Priority Date: 11/23/1993
• Status: Expired due to Fees

• Current Assignee: Alliedsignal Inc.
• Original Assignee: Alliedsignal Inc.
• Inventors: Perron, James S., Muntner, Michael S.
• Primary Examiner(s): Bradley, P. Austin
• Assistant Examiner(s): LIN, ING HOUR
• Application Number:
  US08/157,228
• Time in Patent Office: 721 Days
• Field of Search: 164/369, 164/228, 164/229, 164/516, 164/165, 164/166, 164/35, 164/70.1, 164/72
• US Class Current: 164/516
• CPC Class Codes: B22C 9/04 Use of lost patterns
• CPC Class Codes: B22C 9/10 Cores; Manufacture or installation of cores breaker cores B22C9/084
• CPC Class Codes: B22C 9/18 Finishing
• CPC Class Codes: B23K 2103/52 Ceramics
• CPC Class Codes: B23K 26/0006 taking account of the properties of the material involved B23K26/32, B23K26/40 take precedence
• CPC Class Codes: B23K 26/361 for deburring or mechanical trimming B23K26/351 takes precedence
• CPC Class Codes: B23K 26/40 taking account of the properties of the material involved
• CPC Class Codes: B28B 11/00 Apparatus or processes for treating or working the shaped or preshaped articles specially adapted for tubular articles B28B21/92; decoration or surface treatment in general B05, B44; compacting concrete in situ in connection with building E04G21/06; drying F26
• CPC Class Codes: B28B 11/04 for coating or applying engobing layersglazing, engobing C04B
• CPC Class Codes: B28B 11/08 for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads
• CPC Class Codes: B28B 11/12 for removing parts of the articles by cutting
• CPC Class Codes: C04B 2111/00939 for the fabrication of moulds or cores
• CPC Class Codes: C04B 35/00 Shaped ceramic products characterised by their composition porous ceramic products C04B38/00; ceramic articles characterised by particular shape, see the relevant classes, e.g. linings for casting ladles, tundishes, cups or the like B22D41/02; ceramic substrates for microelectronic semi-conductors H01L23/15; Ceramics compositions containing free metal bonded to carbides, diamond, oxides, borides, nitrides, silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides or sulfides other than as macroscopic reinforcing agents C22C; shaping of ceramics B28B; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products chemical preparation of powders of inorganic compounds C01; infiltration of sintered ceramic preforms with molten metal C04B41/51
• CPC Class Codes: C04B 41/0036 Laser treatment working by laser beam B23K26/00
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/80 of only ceramics

Abstract

A method is disclosed for producing a hollow airfoil, specifically, a blade or vane for a gas turbine engine, which is formed with a complex interior for cooling purposes. Broadly, the method comprises the steps of molding a green ceramic core having outer surfaces generally contoured to produce the intended interior surfaces of the completed airfoil, heating the green ceramic core to a sufficient extent to produce a fired core, and operating on the fired core with a laser to modify the characteristics of the fired core. Use of the laser enables the formation of detailed features having a transverse dimension less than approximately 0.020 inches. Specific operations may include labeling, trimming, cutting, drilling either by punching or trepanning, etching or milling, and glazing or strengthening. In another embodiment of the invention, a layer is produced on the core surface having a very high surface energy to promote the flow of the casting alloy around the core within the mold.

Claims

1. A method of producing a core for making a hollow blade comprising the steps of:

(a) molding a green ceramic core having outer surfaces generally contoured to produce the intended interior surfaces of the completed blade;

(b) heating the green ceramic core to a sufficient extent to produce a fired core; and

(c) operating on the fired core with a laser to modify the characteristics of the fired core.

2. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) applying the laser in such a manner that the outer surface of the fired core is smoothened.

3. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) applying the laser to the surface of the fired core in such a manner that the outer surface of the core is strengthened.

4. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (a) includes the steps of:

(d) positioning opposed mating core dies into juxtaposed relationship such that mutually opposed faying surfaces are proximately engaged; and

(e) injecting ceramic material into the cavity defined by opposed core dies; and

wherein step (c) includes the step of;

(f) directing the laser to remove excessive amounts of fired core material which intrudes between the mutually opposed faying surfaces during step (e).

5. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) cutting detailed features into the outer surfaces of the fired core by means of the laser.

6. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) using the laser to mill the outer surfaces of the fired core.

7. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) using the laser to heat localized outer surfaces of the fired core to a temperature at which glazing occurs.

8. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (a) includes the step of:

(d) providing temporary tie bar means for core stability during step (b); and

wherein step (c) includes the step of;

(d) directing the laser to remove the temporary tie bar means from the fired core.

9. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) forming indicia on the outer surfaces of the fired core which will subsequently, upon completion of a molding process, be x-ray readable on the interior surfaces of the completed blade.

10. A method of producing a core for making a hollow blade as set forth in claim 9

wherein step (d) includes the step of:

(e) operating the laser at a level of power such that the laser beam only superficially ablates the surface of the fired ceramic core.

11. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) drilling holes into the outer surfaces of the fired core by means of the laser.

12. A method of producing a core for making a hollow blade as set forth in claim 11

wherein step (d) includes the step of:

(e) punching holes into the outer surfaces of the fired core by centering the axis of the laser beam on the axis of the hole being formed.

13. A method of producing a core for making a hollow blade as set forth in claim 11

wherein step (d) includes the step of:

(e) using the laser to cut at least one disk having a desired diameter out of the outer surfaces of the fired core by directing the axis of the laser beam transverse to the plane of the outer surfaces at a plurality of locations substantially equidistant from the axis of the disk being removed.

14. A method of producing a core for making a hollow blade as set forth in claim 11

wherein step (d) includes the step of:

(e) using the laser to cut out of the outer surface of the fired core a disk having an irregular boundary by directing the axis of the laser beam transverse to the plane of the outer surface thereof.

15. A method of producing a core for making a hollow blade as set forth in claim 1 including the steps, after step (a) and before step (b), of:

(d) ejecting the green ceramic core from the core mold;

(e) placing the green ceramic core on refractory supporting means; and

(f) introducing the green ceramic core and refractory supporting means to the interior of a high temperature kiln.

16. A method of producing a core for making a hollow blade as set forth in claim 15 including the steps, after step (b), of:

(g) removing the fired core from the kiln and from the refractory supporting means;

(h) placing the fired core on refractory supporting means;

(i) holding the fired core stationary on the refractory supporting means while performing step (c).

17. A method of producing a core for making a hollow blade as set forth in claim 1

wherein step (c) includes the step of:

(d) operating the laser to form specific detailed features on the fired core desired for the interior passages of the completed blade.

18. A method of producing a core for making a hollow blade as set forth in claim 17

wherein step (d) includes the step of:

(e) operating the laser with a level of power adequate for melting and vaporizing the fired ceramic core so as to produce the specific detailed features desired.

19. A method of producing a core for making a hollow blade as set forth in claim 17

wherein the transverse dimension of the specific detailed features is less than approximately 0.020 inches.

20. A method of producing a core for making a hollow blade as set forth in claim 17 including the steps of:

(e) depositing a catalyst onto the surface of the fired core; and

(f) after step (e), immersing the fired core with the catalyst surface thereon into a heated solution of nickel salts to thereby form an electroless nickel coating on the surfaces of the core; and

(g) withdrawing the fired core from the heated solution when a sufficient thickness of the electroless nickel has been deposited on the surfaces thereof.

21. A method of producing a core for making a hollow blade as set forth in claim 20

wherein the wetting material is a metallo-organic compound containing at least one metal having a high melting point selected from the group consisting of:

copper, silver, gold, iron, ruthenium, osmium cobalt, rhodium, iridium, nickel, palladium, and platinum.

22. A method of producing a core for making a hollow blade as set forth in claim 17

wherein the transverse dimension of the specific detailed features is less than approximately 0.020 inches;

and

including the step of;

(d) applying to the surface of the fired core a coating of a wetting material having a surface energy in excess of approximately 750 dynes per centimeter.

23. A method of producing a core for making a hollow blade as set forth in claim 22

wherein step (d) is performed by an electroplating process.

24. A method of producing a core for making a hollow blade as set forth in claim 22

wherein step (d) is performed by a chemical vapor deposition process.

25. A method of producing a core for making a hollow blade as set forth in claim 22

wherein step (d) is performed by a physical vapor deposition process.

26. A method of producing a core for making a hollow blade as set forth in claim 22

wherein step (d) includes the step of:

(e) applying to the surface of the fired core by an ion sputtering process a coating of a material selected from the group consisting of titanium diboride and titanium carbide;

wherein step (c) includes the step of;

(d) operating the laser to form specific detailed features on the fired core desired for the interior passages of the completed blade.

27. A method of producing a core for making a hollow blade as set forth in claim 22

wherein the wetting material is a metallo-organic compound containing at least one metal having a high melting point selected from the group consisting of:

copper, silver, gold;

iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, and platinum.

28. A method of producing a core for making a hollow blade as set forth in claim 27

wherein step (d) includes the steps of:

(e) heating the fired core with the wetting material thereon to a temperature in the range of approximately 400°

C. to 600°

C. to drive off the organic compound thereby leaving only the high temperature metal on the outer surface of the fired core.

29. A method of producing a core for making a hollow blade as set forth in claim 28

wherein steps (d) and (e) are performed at least twice.

30. A method of producing a core for making a hollow blade as set forth in claim 28 including the step of:

(f) after steps (d) and (e), immersing the fired core into an electroless nickel bath to form a nickel coating onto the outermost surface of the core.

31. A method of making a hollow blade comprising the steps of:

(a) molding a green ceramic core having outer surfaces generally contoured to produce the intended interior surfaces of the completed blade;

(b) heating the green ceramic core to a sufficient extent to produce a fired core;

(c) operating on the fired core with a laser to modify the characteristics of the fired core;

(d) inserting the modified fired core into a wax injection mold having the negative contour of a desired blade;

(e) injecting molten wax into the wax injection mold to form a wax mold/core combination;

(f) removing the wax mold/core combination from the wax injection mold;

(g) generously coating the wax mold/core combination with a ceramic slurry;

(h) causing the ceramic slurry applied in step (g) to harden so as to form an outer shell;

(h) heating the outer shell to melt the wax of the wax mold/core combination within the interior of the outer shell;

(i) draining off the melted wax from the interior of the outer shell;

(j) pouring molten alloy into the interior of the outer shell to thereby fill the cavity defined by the interior surfaces of the outer shell and the surfaces of the fired core;

(k) allowing the alloy to solidify to form a casting having a desired external surface with the desired contour; and

(l) leaching out the fired core from the interior of the casting substantially resulting in the desired hollow blade.

32. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) operating the laser in such a manner that the surface of the fired core is smoothened.

33. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) directing the beam of the laser to the surface of the fired core in such a manner that the surface of the core is strengthened.

34. A method of making a hollow blade as set forth in claim 31

wherein step (a) includes the steps of:

(d) positioning opposed mating core dies into juxtaposed relationship such that mutually opposed faying surfaces are proximately engaged; and

(e) injecting ceramic material into the cavity defined by opposed core dies; and

wherein step (c) includes the step of;

(f) directing the laser to remove excessive amounts of fired core material which intrudes between the mutually opposed faying surfaces during step (e).

35. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) cutting detailed features into the outer surfaces of the fired core by means of the laser.

36. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) using the laser to mill the outer surfaces of the fired core.

37. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) using the laser to heat localized outer surfaces of the fired core to a temperature at which glazing occurs.

38. A method of making a hollow blade as set forth in claim 31

wherein step (a) includes the step of:

(d) providing temporary tie bar means for core stability during step (b); and

wherein step (c) includes the step of;

(d) directing the laser to remove the temporary tie bar means from the fired core.

39. A method of making a hollow blade as set forth in claim 32

wherein step (d) includes the step of:

(e) operating the laser with a level of power adequate for melting and vaporizing the fired ceramic core so as to produce the specific detailed features desired.

40. A method of making a hollow blade as set forth in claim 39

wherein the laser used in steps (c) and (d) is a CO₂ laser.

41. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) forming indicia on the outer surfaces of the fired core which will subsequently, upon completion of a molding process, be x-ray readable on the interior surfaces of the completed blade.

42. A method of making a hollow blade as set forth in claim 41

wherein step (d) includes the step of:

(e) operating the laser at a level of power such that the laser beam therefrom only superficially ablates the surface of the fired ceramic core.

43. A method of making a hollow blade as set forth in claim 42

wherein the laser used in steps (c) and (e) is a YAG laser.

44. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) drilling holes into the outer surfaces of the fired core by means of the laser.

45. A method of making a hollow blade as set forth in claim 44

wherein step (d) includes the step of:

(e) punching holes into the outer surfaces of the fired core by centering the axis of the laser beam on the axis of the hole being formed.

46. A method of making a hollow blade as set forth in claim 44

wherein step (d) includes the step of:

(e) using the laser to cut at least one disk having a desired diameter out of the outer surfaces of the fired core by directing the axis of the laser beam transverse to the plane of the outer surfaces at a plurality of locations substantially equidistant from the axis of the disk being removed.

47. A method of making a hollow blade as set forth in claim 44

wherein step (d) includes the step of:

(e) using the laser to cut out of the outer surface of the fired core a disk having an irregular boundary by directing the axis of the laser beam transverse to the plane of the outer surface thereof.

48. A method of making a hollow blade as set forth in claim 31 including the steps, after step (a) and before step (b), of:

(d) ejecting the green ceramic core from the core mold;

(e) placing the green ceramic core on refractory supporting means; and

(f) introducing the green ceramic core and refractory supporting means to the interior of a high temperature kiln.

49. A method of making a hollow blade as set forth in claim 48 including the steps, after step (b), of:

(g) removing the fired core from the kiln and from the refractory supporting means;

(h) placing the fired core on refractory supporting means;

(i) holding the fired core stationary on the refractory supporting means while performing step (c).

50. A method of making a hollow blade as set forth in claim 31

wherein step (c) includes the step of:

(d) operating the laser to form specific detailed features on the fired core desired for the interior passages of the completed blade.

51. A method of making a hollow blade as set forth in claim 50

wherein the transverse dimension of the specific detailed features is less than approximately 0.020 inches.

52. A method of making a hollow blade as set forth in claim 50 including the steps of:

(e) depositing a catalyst onto the surface of the fired core; and

(f) after step (e), immersing the fired core with the catalyst surface thereon into a heated solution of nickel salts to thereby form an electroless nickel coating on the surfaces of the core; and

(g) withdrawing the fired core from the heated solution when a sufficient thickness of the electroless nickel has been deposited on the surfaces thereof.

53. A method of making a hollow blade as set forth in claim 52

wherein the wetting material is a metallo-organic compound containing at least one metal having a high melting point selected from the group consisting of:

copper, silver, gold, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, and platinum.

54. A method of making a hollow blade as set forth in claim 50

wherein the transverse dimension of the specific detailed features is less than approximately 0.020 inches;

and

including the step of;

(d) applying to the surface of the fired core a coating of a wetting material having a surface energy in excess of approximately 750 dynes per centimeter.

55. A method of making a hollow blade as set forth in claim 54

wherein step (d) is performed by an electroplating process.

56. A method of making a hollow blade as set forth in claim 54

wherein step (d) is performed by a chemical vapor deposition process.

57. A method of making a hollow blade as set forth in claim 54

wherein step (d) is performed by a physical vapor deposition process.

58. A method of making a hollow blade as set forth in claim 54

wherein step (d) includes the step of:

(e) applying to the surface of the fired core by an ion sputtering process a coating of a material selected from the group consisting of titanium diboride and titanium carbide.

59. A method of making a hollow blade as set forth in claim 54

wherein the wetting material is a metallo-organic compound containing at least one metal having a high melting point selected from the group consisting of:

copper, silver, gold;

iron, ruthenium, osomium;

cobalt, rhodium, iridium nickel, palladium, and platinum.

60. A method of producing a core for making a hollow blade as set forth in claim 59

wherein step (d) includes the steps of;

(e) heating the fired core with the wetting material thereon to a temperature in the range of approximately 400°

C. to 600°

C. to drive off the organic compound thereby leaving only the high temperature metal on the outer surface of the fired core.

61. A method of producing a core for making a hollow blade as set forth in claim 60

wherein steps (d) and (e) are performed at least twice.

62. A method of making a hollow blade as set forth in claim 60 including the step of:

(f) after steps (d) and (e), immersing the fired core into an electroless nickel bath to form a nickel coating onto the outermost surface of the core.