Detergent compositions which provide dye transfer inhibition benefits

• US 5,466,802 A
• Filed: 11/10/1993
• Issued: 11/14/1995
• Est. Priority Date: 11/10/1993
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Hughes, Larry J., Wertz, William C., Panandiker, Rajan K.
• Primary Examiner(s): Hollinden, Gary E.
• Assistant Examiner(s): Burn, Brian M.
• Application Number:
  US08/150,644
• Time in Patent Office: 734 Days
• Field of Search: 252/547, 252/545, 252/546, 252/553, 252/194.12, 252/174.15, 252/544, 252/551, 252/550, 252/542, 252/543, 544/193.2
• US Class Current: 510/320
• CPC Class Codes: C11D 1/14 derived from aliphatic hydrocarbons or mono-alcohols
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 1/525 Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/86 Mixtures of anionic, cationic, and non-ionic compounds
• CPC Class Codes: C11D 3/0021 Dye-stain or dye-transfer inhibiting compositions
• CPC Class Codes: C11D 3/3776 Heterocyclic compounds, e.g. lactam
• CPC Class Codes: C11D 3/3792 Amine oxide containing polymers
• CPC Class Codes: C11D 3/42 Brightening agents ; Blueing agents

Abstract

Disclosed are detergent compositions and methods which are suitable for washing colored fabrics in aqueous washing solution with little or no transfer of dye between fabrics. The compositions utilized comprise detersive surfactant, detergent builder, certain selected polymeric dye transfer inhibiting agents and certain selected hydrophilic optical brighteners. The polymeric dye transfer inhibiting agents are polyamine N-oxides such as poly(4-vinylpyridine-N-oxide), i.e., PVNO and/or copolymers of N-vinyipyrrolidone and N-vinylimidazole, i.e., PVPVI. The optical brighteners are selected from certain stilbenedisulfonic acid salts.

Claims

1. A laundry detergent composition that provides especially effective inhibition of dye transfer between fabrics being laundered in aqueous washing solutions formed from such a composition, which composition comprises:

(a) from about 1% to about 80% of a detersive surfactant;

(b) from about 0.1% to about 80% of detergent builder component;

(c) from about 0.01% to 10% by weight of a polymeric dye transfer inhibiting agent selected from the group consisting of polyamine N-oxide polymers, copolymers and N-vinylpyrrolidone and N-vinylimidazole and combinations of said polymers and copolymers; and

(d) from about 0.005% to 5% by weight of a hydrophilic optical brightener having the formula;

##STR7## wherein R₁ is selected from the group consisting of anilino, N-2-bis-hydroxyethyl and NH-2-hydroxyethyl;

R₂ is selected from the group consisting of N-2-bis-hydroxyethyl, N-2-hydroxyethyl-N-methylamino, morphilino, chloro and amino; and

M is a salt-forming cation.

2. A detergent composition according to claim 1 wherein

(a) the detersive surfactant is selected from the group consisting of anionic surfactants, nonionic surfactants and combinations thereof;

(b) the builder is selected from the group consisting of aluminosilicates, crystalline layered silicates, citrates and combinations thereof;

(c) the polymeric dye transfer inhibiting agent is a polyvinylpyridine N-oxide; and

(d) the hydrophilic optical brightener is 4,4'"'"'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-triazine-2yl)amino ]-2,2'"'"'-stilbenedisulfonic acid disodium salt.

3. A composition according to claim 2 wherein the polyvinylpyridine N-oxide has an amine to amine N-oxide molar ratio of from about 3:

1 to 1;

1,000,000 and an average molecular weight of from about 1,000 to 500,000.

4. A composition according to claim 1 wherein

(a) the detersive surfactant is selected from the group consisting of anionic surfactants, nonionic surfactants and combinations thereof;

(b) the builder is selected from the group consisting of aluminosilicates, crystalline layered silicates, citrates and combinations thereof;

(c) the polymeric dye transfer inhibiting agent is a copolymer of N-vinylpyrrolidone and N-vinylimidazole having a molar ratio of N-vinylpyrrolidone to N-vinylimidazole of from about 0.8;

1 to 0.3;

1 and an average molecular weight of from about 5,000 to 200,000; and

(d) the hydrophilic optical brightener is 4,4'"'"'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-triazine-2yl)amino]-2,2'"'"'-stilbenedisulfonic acid disodium salt.

5. A composition according to claim 4 where the dye transfer inhibiting copolymer has a molar ratio of N-vinylpyrrolidone to N-vinylimidazole of from about 0.6:

1 to 0.4;

1 and an average molecular weight of from about 10,000 to 20,000.

15. A method for cleaning colored fabrics in the wash with little or no dye transfer between fabrics, said method comprising contacting said fabrics with a wash solution which contains an effective amount of a detergent composition according to claim 1.

6. A liquid laundry detergent composition that provides especially effective inhibition of dye transfer between fabrics and being laundered in aqueous washing solutions formed from such a composition, which composition comprises:

(a) from about 5% to 50% by weight of a detersive surfactant selected from the group consisting of

i) sodium, potassium and ethanolamine alkylsulfates wherein the alkyl group contains from 10 to 22 carbon atoms;

ii) sodium, potassium and ethanolamine alkylpolyethoxylate sulfates wherein the alkyl group contains from 10 to 22 carbon atoms and the polyethoxylate chain contains from 1 to 15 ethylene oxide moieties;

iii) polyhydroxy fatty acid amides of the formula ##STR8## wherein R is a C_9-17 alkyl or alkenyl and Z is glycityl derived from a reduced sugar or alkoxylated derivatives thereof;

iv) alcohol ethoxylates of the formula R¹ (OC₂ H₄)_n OH where R¹ is a C₁₀ -C₁₆ alkyl group or a C₈ -C₁₂ alkyl phenyl group and n is from about 3 to 80; and

(b) from about 1% to 10% by weight of a detergent builder component selected from the group consisting of carboxylate and polycarboxylate builders;

(c) from about 0.05% to 0.5% by weight of a polymeric dye transfer inhibiting agent selected from the group consisting of

i) polyamine N-oxides having an anionic to amino N-oxide molar ratio of from about 10;

1 to 1;

1,000,000 and having an average molecular weight of from about 500 to 1,000,000; and

ii) polymers of N-vinylpyrrolidone and N-vinylimidazole having a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of from about 1;

1 to 0.2;

1 and having an average molecular weight of from about 5,000 to 1,000,000; and

(d) from about 0.01% to 1% of a hydrophilic optical brightener selected from the group consisting of

i) 4,4'"'"'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-triazine-2yl)amino]-2,2'"'"'-stilbenedisulfonic acid disodium salt;

ii) 4,4'"'"'- bis[(4-anilino-6-(N-2 -hydroxyethyl-N-methylamino)-s-triazine-2-yl)amino]-2,2'"'"'-stilbenedisulfonic acid disodium salt; and

iii) 4,4'"'"'-bis[(4-anilino-6-morphilino-s-triazine-2-yl)amino]-2,2'"'"'-stilbenedisulfonic acid, sodium salt.

7. A liquid detergent composition according to claim 6 wherein

a) the dye transfer inhibiting agent is poly(4-vinylpyridine-N-oxide) having an amine to amine N-oxide ratio of about 1:

10 and an average molecular weight of about 10,000; and

b) the optical brightener is Tinopal UNPA-GX.

8. A liquid detergent composition according to claim 6 wherein

a) the dye transfer inhibiting agent is a copolymer of N-vinylpyrrolidone and N-vinylimidazole having an N-vinylpyrrolidone to N-vinylimidazole molar ratio of from about 0.6:

1 to 0.4;

1 and an average molecular weight of from about 10,000 to 20,000; and

b) the optical brightener is Tinopal UNPA-GX.

9. A liquid detergent composition according to claim 6 which also comprises from about 0.1% to 2.5% by weight of an enzyme component selected from the group consisting of proteases, lipases, amylases, cellulases and combinations of said enzymes.

17. A method for cleaning colored fabrics in the wash with little or no dye transfer between fabrics, said method comprising contacting said fabrics with a wash solution which contains an effective amount of a detergent composition according to claim 6.

10. A granular laundry detergent composition that provides especially effective inhibition of dye transfer between fabrics being laundered in aqueous washing solutions formed from such a composition, which composition comprises:

(a) from about 5% to 50% by weight of a detersive surfactant selected from the group consisting of

i) sodium and potassium alkylpolyethoxylate sulfates wherein the alkyl group contains from 10 to 22 carbon atoms and the polyethoxylate chain contains from 1 to 15 ethylene oxide moieties;

ii) sodium and potassium C9 to C15 alkyl benzene sulfonates;

iii) sodium and potassium C8 to C18 alkyl sulfates;

iv) polyhydroxy fatty acid amides of the formula ##STR9## wherein R is a C_9-17 alkyl or alkenyl and Z is a glycityl derived from a reduced sugar or alkoxylated derivatives thereof; and

v) combinations of these surfactants;

(b) from about 1% to 50% by weight of a detergent builder selected from the group consisting of sodium carbonate, sodium silicate, crystalline layered silicates, aluminosilicates, oxydisuccinates and citrates;

(c) from about 0.05% to 0.5% by weight of a polymeric dye transfer inhibiting agent selected from the group consisting of

i) polyamine N-oxides having an anionic to amine N-oxide molar ratio of from about 10;

1 to 1;

1,000,000 and having an average molecular weight of from about 500 to 1,000,000; and

ii) copolymers of N-vinylpyrrolidone and N-vinylimidazole having a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of from about 1;

1 to 0.2;

1 and having an average molecular weight of from about 5,000 to 1,000,000; and

(d) from about 0.01% to 1% of a hydrophilic optical brightener selected from the group consisting of

i) 4,4'"'"'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-trizine-2yl)amino]-2,2'"'"'-stilbenedisulfonic acid disodium salt;

12. A granular detergent composition according to claim 10 wherein

a) the dye transfer inhibiting agent is poly(4-vinylpyridine-N-oxide) having an amine to amine N-oxide ratio of about 1:

10 and an average molecular weight of about 10,000; and

b) the optical brightener is Tinopal UNPA-GX.

13. A granular detergent composition according to claim 10 wherein

a) the dye transfer inhibiting agent is a copolymer of N-vinylpyrrolidone and N-vinylimidazole having an N-vinylpyrrolidone to N-vinylimidazole molar ratio of from about 0.6:

1 to 0.4;

1 and an average molecular weight of from about 10,000 to 20,000; and

b) the optical brightener is Tinopal UNPA-GX.

14. A granular detergent composition according to claim 10 which also comprises from about 0.1% to 2.5% by weight of an enzyme component selected from the group consisting of proteases, lipases, amylases, cellulases and combinations of said enzymes.

16. A method according to claim 14 wherein the detergent composition used comprises PVNO and Tinopal UNPA-GX brightener.

18. A method according to claim 16 wherein the detergent composition used comprises PVNO and Tinopal UNPA-GX brightener.

19. A method for cleaning colored fabrics in the wash with little or no dye transfer between fabrics, said method comprising contacting said fabrics with a wash solution which contains an effective amount of a detergent composition according to claim 10.

20. A method according to claim 18 wherein the detergent composition used comprises PVNO and Tinopal UNPA-GX brightener.

11. 4'"'"'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-trizine-2-yl)amino]-2,2'"'"'-stilbenedisulfonic acid disodium salt;

and

iii) 4,4'"'"'-bis[(4-anilino-6-morphilino-s-trizine-2yl)amino]-2,2'"'"'-stilbenedisulfonic acid, sodium salt.