Method for production of a coated substrate with controlled surface characteristics

• US 5,468,542 A
• Filed: 02/22/1990
• Issued: 11/21/1995
• Est. Priority Date: 12/23/1985
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Crouch, Earl T.
• Primary Examiner(s): Padgett, Marianne
• Application Number:
  US07/484,467
• Time in Patent Office: 2,098 Days
• Field of Search: 427/495, 427/508, 427/510, 428/412, 428/213, 428/215, 428/335, 428/337
• US Class Current: 428/215
• CPC Class Codes: B05D 2201/00 Polymeric substrate or laminate
• CPC Class Codes: B05D 2252/02 of indefinite length
• CPC Class Codes: B05D 3/0263 with IR heaters
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 3/068 using ionising radiations (gamma, X, electrons)
• CPC Class Codes: B29C 2035/0822 using IR radiation
• CPC Class Codes: B29C 2035/0827 using UV radiation
• CPC Class Codes: B29C 2035/0877 using electron radiation, e.g. beta-rays
• CPC Class Codes: B29C 35/10 for articles of indefinite length
• CPC Class Codes: B29C 39/148 characterised by the shape of the surface
• CPC Class Codes: B29C 39/18 incorporating preformed parts or layers, e.g. casting around inserts or for coating articles B29C39/206 takes precedence
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

A method for providing an abrasion-resistant, radiation-cured coating on a surface of a polymeric substrate is disclosed, as well as the article produced from the method. The uncured coating material is applied to the substrate, followed by the expulsion of air from the coating. The coating is then cured by directing the radiant energy through the substrate from the surface opposite the surface having the coating thereon to contact the radiation-curable coating.

Claims

1. A method for producing a high optical quality, flexible, transparent, abrasion resistant polycarbonate article, said article having a polycarbonate film substrate and an abrasion resistant radiation cured coating adhered to said substrate, said substrate having a thickness selected from the range of about 5 mil to about 30 mil, said coating having a thickness selected from the range of 0.05 mil to 5.0 mil, said method comprising the steps of:

(a) applying an ultraviolet radiation curable uncured coating material and a photoinitiator to at least one surface of the substrate;

(b) passing the substrate having the uncured coating thereon through a compression nip defined by a nip roll and a casting drum, said casting drum having a metal surface, said compression nip applying an exact pressure to said uncured coating and substrate to exclude air from within said coating and to press simultaneously said coating into full dual anaerobic contact with both (a) the substrate to remove and to exclude any air between said coating and said substrate to provide improved adhesion between said coating and said substrate and (b) the drum to exclude any air between said coating and said drum to provide improved surface appearance; and

(c) curing the uncured coating by directing the ultraviolet radiant energy through the substrate from the surface opposite the surface having the coating thereon to contact and cure the radiation-curable coating while the coating is in anaerobic contact with the drum.

2. The method of claim 1 wherein the surface of the casting drum contacting the uncured coating is patterned so as to impart to the coating a texture which is a mirror-image of the pattern on the casting drum surface.

3. The method of claim 1 wherein the uncured coating material is applied to the substrate by gravure roll means.

4. The method of claim 1 further comprising applying and curing a conventional coating on the surface of the radiation-cured coating after step (c).

5. The method of claim 4 wherein the conventional coating is a heat-curable thermosetting material.

6. The method of claim 4 wherein the conventional coating is a thermoplastic material.

7. The method of claim 1 wherein the uncuring coating is nonvolatile.

8. The method of claim 1 wherein the coating material is applied as two layers.

9. The method of claim 8 wherein the second layer of coating material is applied on the surface of the first layer of coating material while the first layer is in an uncured state.

10. The article produced by the method of claim 1.

11. The method of claim 1 wherein said pressure of said compression nip may be adjusted.

12. A method for producing an abrasion resistant, transparent polycarbonate film, said film comprising a transparent polycarbonate substrate having a thickness selected from the range of 5 mils to 30 mils, said film further comprising an abrasion resistant cured acrylate coating adhered to said substrate, said coating having a thickness selected from the range of 0.05 mil to 5.0 mils, said method comprising:

(a) contacting an ultraviolet radiation curable polyfunctional acrylate coating material and a photoinitiator with a surface of the substrate;

(b) passing the substrate having the uncured coating material thereon through a compression nip defined by a nip roll and a casting drum, said casting drum having a metal surface, said compression nip applying an exact pressure to said uncured coating material and substrate to exclude air from within said coating material and to press simultaneously said coating material by the nip roll into full dual anaerobic contact with both (a) the substrate to remove and to exclude any air between said coating and said substrate to provide improved adhesion between said coating and said substrate and (b) the drum to exclude any air between said coating and said drum to provide improved surface appearance; and

(c) curing the coating material by directing ultraviolet radiant energy through the transparent polycarbonate substrate to contact and cure the radiation-curable coating while the coating is in anaerobic contact with the drum.

13. The method of claim 12 wherein said metal surface is a chrome plated surface.

14. The method of claim 13 wherein said drum surface is highly polished and imparts a high degree of gloss to said coating.