Molecular sieve - photoactive semiconductor membranes and reactions employing the membranes

• US 5,468,699 A
• Filed: 07/30/1992
• Issued: 11/21/1995
• Est. Priority Date: 07/30/1992
• Status: Expired due to Fees

• Current Assignee: Inrad Inc.
• Original Assignee: Inrad Inc.
• Inventors: Zhang, Zhenyu, Fehlner, James R.
• Primary Examiner(s): PAL, ASOKKUMAR
• Application Number:
  US07/921,786
• Time in Patent Office: 1,209 Days
• Field of Search: 502/4, 502/5, 502/60
• US Class Current: 502/60
• CPC Class Codes: B01J 2235/15 X-ray diffraction
• CPC Class Codes: B01J 29/04 having base-exchange properties, e.g. crystalline zeolites B01J29/005 takes precedence
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 35/59 Membranes
• CPC Class Codes: B01J 35/70 characterised by their crystalline properties, e.g. semi-crystalline catalysts comprising carbon B01J21/18; molecular sieves B01J29/00
• CPC Class Codes: B01J 37/0246 Coatings comprising a zeolite

Abstract

Methods for forming membranes of semiconductive material incorporating molecular sieve material therein can involve sol gel techniques and suction techniques. The semiconductors, such as metal oxides, sulfides or carbides have photoactivity and are useful in photocatalytic reactions. An example of such a membrane is titanium oxide including zeolite molecular sieve incorporated therein. The membranes can be used to perform useful chemical reactions such as the mineralization of organic chemicals in the presence of light. For example, many toxic organic chemicals can be converted to useful or benign products by contacting those chemicals with active metal oxide-molecular sieve membranes in accordance with the invention and illuminating the membranes with light of a suitable wavelength.

Claims

1. A membrane for affecting the composition of material coming in contact with the membrane, comprising:

an inert porous substrate having a pore size from about 2.5 to 50 microns and semiconductor material including TiO₂ supported by the porous substrate, the semiconductor material including a photoactive polymeric metal/semimetal oxide matrix and molecular sieve material impregnated within the matrix, the molecular sieve material including zeolitic material having pore size from about 3 to 12 angstroms.

2. The membrane of claim 1, wherein the membrane includes metal ions.

3. The membrane of claim 1, wherein the membrane includes transition metal ions.

4. The membrane of claim 2, wherein the metal ions are Cu²⁺ ions.

5. The membrane of claim 1, wherein the membrane includes transition metal ions.

6. The membrane of claim 5, wherein the metal ions are Cu²⁺ ions.

7. The membrane of claim 1, wherein the molecular sieve is selected from the group consisting of silicalite, ZSM-5, NaA, Y zeolite, mordenite, ETS-10 and combinations thereof.

8. The membrane of claim 1, wherein the molecular sieve is silicalite.

9. The membrane of claim 1, wherein the molecular sieve includes titanium.

10. The membrane of claim 1, wherein the semiconductor includes TiO₂ and the membrane also includes SiO₂.

11. The membrane of claim 1, wherein the substrate includes material selected from the group consisting of glass, fused silica, quartz and ceramic material.

12. A method of forming an inorganic membrane, comprising:

impregnating a porous substrate with molecular sieve particles and exposing the substrate with a titanium alkoxide to form a film of titania on the surface of the impregnated substrate.

13. The method of claim 12, wherein the molecular sieve is zeolite material.

14. The method of claim 12, wherein the alkoxide is titanium isopropoxide.

15. The method of claim 12, wherein the porous substrate impregnated with molecular sieve particles is reacted with a liquid solution to form titania on the impregnated substrate.

16. The method of claim 14, wherein the impregnated substrate is immersed in a neat titanium isopropoxide solution.

17. The method of claim 14, wherein the molecular sieve includes zeolite material.

18. The method of claim 12, wherein the alkoxide is applied from the vapor phase.

19. The method of claim 12, wherein metal ions are incorporated in the membrane.

20. The method of claim 12, wherein Cu²⁺ ions are incorporated in the membrane.