Reversible thermoelectric converter

• US 5,470,395 A
• Filed: 06/30/1994
• Issued: 11/28/1995
• Est. Priority Date: 03/30/1992
• Status: Expired due to Term

• Current Assignee: Jane A. Yater, Joan E. Yater, Joseph C. Yater
• Original Assignee: Jane A. Yater, Joan E. Yater, Joseph C. Yater
• Inventors: Yater, Jane A., Yater, Joan E., Yater, Joseph C.
• Primary Examiner(s): Walsh, Donald P.
• Assistant Examiner(s): CARROLL, CHRISMAN DION
• Application Number:
  US08/269,654
• Time in Patent Office: 516 Days
• Field of Search: 136/200, 136/203, 136/204, 136/224, 136/225, 136/205, 136/208, 62/3.2, 62/3.3, 62/35, 62/3.7, 250/338.3
• US Class Current: 136/203
• CPC Class Codes: F25B 2321/003 by using thermionic electron cooling effects
• CPC Class Codes: H10N 10/00 Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects integrated devices or assemblies of multiple devices H10N19/00
• CPC Class Codes: H10N 10/17 characterised by the structure or configuration of the cell or thermocouple forming the device

Abstract

A reversible thermoelectric converter includes first and second quantum well diodes and an electrical connection between the first and second quantum well diodes without a thermal barrier between them. Each quantum well diode includes first and second electrodes wherein electrons are quantized in discrete energy levels and a dielectric layer providing a potential barrier between the first and second electrodes. When electrons in the first quantum well diode have a higher temperature than the electrons in the second quantum well diode, electric voltage fluctuations resulting from transitions of the electrons between the energy levels in the first quantum well diode are coupled from the first quantum well diode to the second quantum well diode. The reversible thermoelectric converter can be operated for power conversion of thermal energy to electric energy, as a heat pump or a refrigerator, or as an amplifier. A planar array of reversible thermoelectric converter elements provides a desired output voltage and current.

Claims

1. Apparatus for converting thermal energy from an external source to thermal energy at a higher temperature than the external source, comprising:

a first device comprising first and second regions wherein electric carriers are quantized in discrete energy levels, and a third region providing a potential barrier between said first and second regions, said first device receiving thermal energy from the external source and converting the thermal energy into electric voltage fluctuations;

a second device comprising first and second regions wherein electric carriers are quantized in discrete energy levels, and a third region providing a potential barrier between said first and second regions, said second device converting electric voltage fluctuations to thermal energy at a higher temperature than the temperature of the external source;

means for supplying to said first device a DC voltage sufficient to reverse a contact potential across said first device; and

means for electrically connecting said first device to said second device without a thermal barrier between them such that the electric voltage fluctuations generated by said first device in response to energy fluctuations from said external source are coupled to said second device and are converted by said second device to thermal energy at a higher temperature than the temperature of said external source.

2. Apparatus as defined in claim 1 wherein said first and second devices each comprise quantum well diodes.

3. Apparatus as defined in claim 1 wherein the first and second regions of said first device and said second device comprise electrode pairs and said first device comprises two or more electrode pairs connected in series and said second device comprises two or more electrode pairs connected in series.

4. Apparatus as defined in claim 1 wherein said first and second devices each comprise tunnel diodes.

5. Apparatus as defined in claim 1 wherein said first and second regions each comprise thin metal films and said third region comprises a thin dielectric film, said first and second devices each further including means for applying a contact potential between the metal films of said first and second regions.

6. Apparatus as defined in claim 1 wherein said first and second regions each comprise thin metal films and said third region comprises a thin dielectric film, said first and second devices each further including auxiliary electrodes for applying an electric field between the metal films of said first and second regions.

7. Apparatus as defined in claim 1 wherein the first region of said first and second devices comprises a first thin metal film, wherein the second region of said first and second devices comprises a second thin metal film and the third region of said first and second devices comprises a thin dielectric film, said first and second thin metal films being fabricated of metals with different work functions.

8. Apparatus as defined in claim 1 wherein the first region of said first and second devices comprises a first thin metal film, wherein the second region of said first and second devices comprises a second thin metal film and the third region of said first and second devices comprises a thin dielectric film, said first and second thin metal films being fabricated of metals with the same work function.

9. Apparatus as defined in claim 1 wherein the first region of said first and second devices comprises a thin aluminum film, the second region of said first and second devices comprises a thin copper film and the third region of said first and second devices comprises a thin aluminum oxide film.

10. Apparatus as defined in claim 1 wherein the first region of said first and second devices comprises a thin copper film, the second region of said first and second devices comprises a thin copper film and the third region of said first and second devices comprises a thin aluminum oxide film.

11. Apparatus as defined in claim 3 wherein said means for electrically connecting said first device to said second device comprises a conducting lead, wherein the electrical conductance of said conducting lead allows the efficiency of the heat pump process to approach the efficiency of the Carnot cycle.

12. Apparatus as defined in claim 11 wherein a sum of added voltage for said first device and a sum of added voltage for said second device are selected to achieve a required output voltage for a given thermal energy output to said second device, wherein the number n of electrode pairs connected in series in said first device is selected such that a voltage to current ratio of the electric energy from said first device is sufficient to achieve efficient transmission of said thermal energy output of said first device such that said first and second devices can be physically separated.

13. A two-stage reversible thermoelectric converter comprising:

a power conversion stage comprising a first quantum well diode for receiving thermal energy and converting the thermal energy to electric voltage fluctuations, a second quantum well diode for converting electric voltage fluctuations to electric energy, and means for electrically connecting the first quantum well to the second quantum well diode without a thermal barrier between them such that the electric voltage fluctuations generated by the first quantum well diode are coupled to the second quantum well diode and are converted to electric energy by the second quantum well diode; and

a heat pump stage for reducing the temperature of the second quantum well diode in the power conversion stage, said heat pump stage comprising a third quantum well diode for receiving thermal energy from the second quantum well diode and converting the thermal energy into electric voltage fluctuations, a fourth quantum well diode for converting electric voltage fluctuations to thermal energy at a higher temperature than the temperature of the second quantum well diode, means for supplying to the third quantum well diode a DC voltage sufficient to reverse the contact potential across the third quantum well diode, and means for electrically connecting the third quantum well diode to the fourth quantum well diode without a thermal barrier between them such that electric voltage fluctuations generated by the third quantum well diode are coupled to the fourth quantum well diode and are converted by the fourth quantum well diode to thermal energy at a higher temperature than the temperature of the second quantum well diode.

14. A two-stage reversible thermoelectric converter as defined in claim 13 wherein said first quantum well diode, said second quantum well diode, said third quantum well diode and said fourth quantum well diode each comprises two or more electrode pairs connected in series.

15. A two-stage reversible thermoelectric converter as defined in claim 13 wherein said second and third quantum well diodes are enclosed in a quasi-static heat reservoir.

16. A two-stage reversible, thermoelectric converter as defined in claim 13 wherein said first, second and third quantum well diodes are enclosed in a quasi-static heat reservoir.

17. A two-stage reversible thermoelectric converter as defined in claim 13 wherein said first, second and third quantum well diodes are enclosed in a quasi-static heat reservoir for mounting in a high temperature environment.

18. A two-stage reversible thermoelectric converter as defined in claim 13 wherein said first, second, and third quantum well diodes are enclosed in a quasi-static heat reservoir for mounting in a furnace environment.

19. A two-stage reversible thermoelectric converter as defined in claim 13 wherein said first and third quantum well diodes are enclosed in a quasi-static heat reservoir for mounting in a furnace environment.

20. A two-stage reversible thermoelectric converter as defined in claim 13 further including means for supporting the converter in space.

21. A two-stage reversible thermoelectric converter as defined in claim 13 further including means for mounting the converter on the roof of a home.