Hollow fiber cartridge

• US 5,470,469 A
• Filed: 09/16/1994
• Issued: 11/28/1995
• Est. Priority Date: 09/16/1994
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Eckman, Thomas J.
• Primary Examiner(s): Fortuna, Ana M.
• Application Number:
  US08/305,948
• Time in Patent Office: 438 Days
• Field of Search: 210/321.78, 210/321.79, 210/321.8, 210/321.88, 210/321.89, 210/433.1, 210/446, 210/335, 210/336, 210/450, 210/323.1, 210/323.2, 210/500.23 , 210/437, 210/456, 96/7, 96/8
• US Class Current: 210/321.8
• CPC Class Codes: B01D 2313/083 Bypass routes
• CPC Class Codes: B01D 2313/44 Cartridge types
• CPC Class Codes: B01D 2313/54 Modularity of membrane module elements
• CPC Class Codes: B01D 63/043 with separate tube sheets
• CPC Class Codes: B01D 65/00 Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
• CPC Class Codes: Y02A 20/131 Reverse-osmosis

Abstract

A cartridge containing a plurality of hollow fiber membranes is disclosed. The cartridge comprises a plurality of fibers arranged in a bundle and at least one end of the bundle embedded in a tubesheet. The tubesheets are fitted with end caps to provide a chamber for the permeate. A feed tube extends longitudinally through the bundle and a permeate discharge tube is housed, preferably concentrically, within a feed tube. The cartridge does not require a high pressure seal, such as an O-ring seal, against the inner wall of the pressure vessel. The cartridge is configured as a single unit adapted for simple drop-in installation into a pressure vessel. Multiple cartridges may readily be inserted into a pressure vessel, and arranged so as to operate in series or in parallel. The hollow fiber membrane cartridge is adapted for industrial performance with high volumetric efficiency and high solute rejection. In addition, a process for installing the cartridges in a pressure vessel previously using spiral wound elements is disclosed.

Claims

1. A hollow fiber membrane separation apparatus comprising a pressure vessel having one or more slide-in, replaceable hollow fiber membrane cartridges disposed longitudinally therein,

(A) each said cartridge comprising a bundle of hollow fibers longitudinally aligned with said cartridge having at least one end of said bundle mounted in a tubesheet, said hollow fibers having selective permeability to fluid;

an elongated feed member through which fluid to be treated can flow radially into and through the hollow fiber bundle;

an elongated discharge member concentrically housed inside said elongated feed member;

end caps mounted to the ends of said bundle wherein the facing ends of the tubesheet(s) and the adjacent end cap define a permeate collection space which is in fluid communication with (i) the open ends of the hollow fibers and (ii) said elongated discharge member;

one or more of said end caps having a feed fluid port;

wherein the feed member has a lip seal at said end cap;

wherein the end caps are mounted over the ends of the bundle with epoxy; and

(B) wherein the cartridges are disposed within the pressure vessel so as to form a first space between the outside of each bundle and the inner wall of the pressure vessel;

a first opening at an end of the pressure vessel and offset from its center, which is in communication with the elongated feed member through which the fluid to be treated is fed;

a second opening or openings at an end of the pressure container and concentric therewith, in fluid communication with the open end of hollow fibers through which the permeate is discharged; and

a third opening at an end of the pressure vessel, opposite said end through which fluid to be treated is fed, and offset from the center, through which the residue fluid is discharged.

2. The separation apparatus of claim 1 wherein in any cartridge said hollow fibers have an inner diameter of about 20 microns to about 200 microns and a hollow ratio of about 10% to about 50%.

3. The separation apparatus of claim 2 wherein in any cartridge said hollow fibers have an inner diameter of about 40 microns and a hollow ratio of about 20%.

4. The separation apparatus of claim 1 containing 2 to 10 cartridges, wherein the cartridges are aligned in series.

5. The separation apparatus of claim 4 in which the cartridges are substantially identical in size and configuration.

6. The separation apparatus of claim 4 wherein each said cartridge additionally comprises an input bypass member to feed said fluid to be treated directly to one or more cartridges downstream within the apparatus.

7. The separation apparatus of claim 1 wherein the first opening is in fluid communication with said first space between the outside of the bundle and the inner wall of the pressure vessel and the elongated feed member, and wherein the relative flow of the feed fluid to said first space and said elongated feed member is regulated by a valve or orifice.