Photostable self-erasing electrochromic device

• US 5,471,337 A
• Filed: 08/25/1994
• Issued: 11/28/1995
• Est. Priority Date: 08/25/1994
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Babinec, Susan J.
• Primary Examiner(s): Ben, Loha
• Application Number:
  US08/296,300
• Time in Patent Office: 460 Days
• Field of Search: 359/265, 359/267, 359/268, 359/271, 359/271, 359/273, 359/269, 252/500, 252/600, 502/154, 502/162, 549/157.15, 549/157.6
• US Class Current: 359/269
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions

Abstract

An electrochromic device comprising three elements. The first element is a first electrode. The second element is a second electrode. The second electrode is spaced apart from the first electrode so that there is a space between the first electrode and the second electrode. The third element is a dispersion positioned in the space. The dispersion is in electrical contact with the first electrode and with the second electrode. The dispersion comprises a polyoxometalate such as H₃ PW₁₂ O₄₀, a counter electrode couple such as ferrocene and a solvent selected from the group consisting of propylene carbonate, ethylene carbonate, nitriles, cyanoethyl ether, water, dimethylsulfoxide, nitromethane, nitrobenzene, acetic acid, dimethoxy benzene, toluene, tetramethylene sulfone, 3-methyl sulfolane, 2-methyl glutaronitrile, cyanoethyl ether, gamma butyrolactone, gamma valerolactone and acetone. The dispersion is resistant to photodegradation such as discoloring in sunlight.

Claims

1. An electrochromic device comprising:

(a) a first electrode;

(b) a second electrode, the second electrode spaced apart from the first electrode so that there is a space between the first electrode and the second electrode; and

(c) a dispersion positioned in the space between the first electrode and the second electrode, the dispersion being in electrical contact with the first electrode and with the second electrode, the dispersion comprising a polyoxometalate, a counter electrode couple and a solvent, the solvent selected from the group consisting of propylene carbonate, ethylene carbonate, gamma valerolactone, acetone, methylene chloride, ethylene dichloride, alkanes and water.

2. The device of claim 1, wherein the counter electrode couple is selected from the group consisting of ferrocene, cobaltocene, ruthenocene, vanadocene, ferricyanide salts, thioferricyanide salts, iron-EDTA, ruthenium-EDTA, cobalt-EDTA, manganese-EDTA, and ferroin.

3. The device of claim 1, wherein the dispersion further comprises a thickening agent.

4. The electrochromic device of claim 3, wherein the liquid solvent comprises propylene carbonate, the counter electrode couple is a ferrocene, the thickening agent is poly(methylmethacrylate), the first electrode is indium tin oxide coated glass, the second electrode is indium tin oxide coated glass, and the polyoxometalate is H₃ PW₁₂ O₄₀.

5. The electrochromic device of claim 1, wherein the polyoxometalate is a molybdenum polyoxometalate.

6. The electrochromic device of claim 1, wherein the polyoxometalate is a tungsten polyoxometalate.

7. An electrochromic device comprising:

(a) a first electrode;

(b) a second electrode, the second electrode spaced apart from the first electrode so that there is a space between the first electrode and the second electrode; and

(c) a dispersion positioned in the space between the first electrode and the second electrode, the dispersion being in electrical contact with the first electrode and with the second electrode, the dispersion comprising a tungsten polyoxometalate, a counter electrode couple and a solvent, the solvent selected from the group consisting of propylene carbonate, ethylene carbonate, nitriles, cyanoethyl ether, water, dimethylsulfoxide, nitromethane, nitrobenzene, acetic acid, dimethoxy benzene, toluene, tetramethylene sulfone, 3-methyl sulfolane, 2-methyl glutaronitrile, cyanoethyl ether, gamma butyrolactone, gamma valerolactone, chlorinated hydrocarbons and acetone.

8. The device of claim 7, wherein the counter electrode couple is selected from the group consisting of ferrocene, cobaltocene, ruthenocene, vanadocene, ferrocene carboxylate, butyl ferrocene, decamethyl ferrocene, ferricyanide salts, thioferricyanide salts, iron-EDTA, ruthenium-EDTA, cobalt-EDTA, manganese-EDTA, and ferroin.

9. The device of claim 7, wherein the dispersion further comprising a thickening agent.

10. The electrochromic device of claim 9 wherein the liquid solvent comprises propylene carbonate, the counter electrode couple is a ferrocene, the thickening agent is poly(methylmethacrylate), the first electrode is indium tin oxide coated glass, the second electrode is indium tin oxide coated glass, and the tungsten polyoxometalate is H₃ PW₁₂ O₄₀.