Gas generant composition containing non-metallic salts of 5-nitrobarbituric acid

• US 5,472,534 A
• Filed: 01/06/1994
• Issued: 12/05/1995
• Est. Priority Date: 01/06/1994
• Status: Expired due to Fees

• Current Assignee: Alliant Techsystems Incorporated (Northrop Grumman Corporation)
• Original Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Inventors: Wardle, Robert B., Blau, Reed J.
• Primary Examiner(s): Nelson, Peter A.
• Application Number:
  US08/178,215
• Time in Patent Office: 698 Days
• Field of Search: 149/36, 149/109.6, 280/741, 544/301
• US Class Current: 149/36
• CPC Class Codes: C07D 239/62 Barbituric acids

Abstract

A composition is provided which comprises a fuel effective amount of a heterocyclic compound represented by the formula: ##STR1## wherein X is a non-metallic cation; and an oxidizing effective amount of an inorganic oxidizer. The oxidizer can be an inorganic nitrite, an inorganic nitrate, a metal peroxide, a metal oxide, a metal hydroxide, an inorganic perchlorate, or an inorganic chlorate. A binder can be added, if desired. An automotive air bag inflator and a method for generating gas are also disclosed.

Claims

1. A composition comprising:

(a) about 15 to about 60 % by weight of at least one heterocyclic compound represented by the formula;

##STR4## wherein X is a non-metallic cation; and

(b) about 85% to about 40% by weight of at least one oxidizer selected from the group consisting of inorganic nitrites, inorganic nitrates, metal oxides, metal hydroxides, metal peroxides, inorganic chlorates, inorganic perchlorates, and mixtures thereof.

2. A composition according to claim 1, wherein X is selected from the group consisting of organic cations and cations of non-carbon heterocycles.

3. A composition according to claim 2 wherein X is a cation of a high nitrogen-content base.

4. A composition according to claim 1, wherein X is selected from the group consisting of ammonium, hydrazinium, guanidinium, aminoguanidinium, diaminoguanidinium, triaminoguanidinium, biguanidinium, aminotriazolium, guanizinium, aminotetrazolium, and hydrazino tetrazolium.

5. A composition according to claim 4, wherein X is selected from the group consisting of guanyl and ammonium.

6. A composition according to claim 1, wherein the oxidizer is a compound having a cation selected from the group consisting of ammonium, a metal from Group I-A of the Periodic Table, barium, bismuth, calcium, cobalt, copper, iron, magnesium, manganese, molybdenum, strontium, tin, tungsten and zinc.

7. A composition according to claim 1, wherein the oxidizer does not contain a cation of a metal from Group I-A of the Periodic Table.

8. A composition according to claim 1, wherein said oxidizer is selected from the group consisting of a metal nitrate, a metal oxide and mixtures thereof.

9. A composition according to claim 8, wherein said oxidizer is selected from the group consisting of CuO, Co₂ O₃, Fe₂ O₃, MoO₃, Bi₂ MoO₆, Bi₂ O₃, Cu(OH)₂, Sr(NO₃)₂, and mixtures thereof.

10. A composition according to claim 1, wherein said oxidizer is selected from the group consisting of ammonium nitrate, strontium nitrate, copper oxide and mixtures thereof.

11. A composition according to claim 1, wherein said salt of 5-nitrobarbituric acid is present in an amount of about 22 to about 45% by weight.

12. A composition according to claim 1, wherein X is selected from the group consisting of ammonium, hydrazinium, guanidinium, aminoguanidinium, diaminoguanidinium, triaminoguanidinium, biguanidinium, aminotriazolium, guanizinium, aminotetrazolium, and hydrazino tetrazolium;

and the oxidizer is a salt having a cation selected from the group consisting of ammonium, a metal from Group I-A of the Periodic Table, barium, bismuth, calcium, cobalt, copper, iron, magnesium, manganese, molybdenum, strontium, tin, tungsten, and zinc.

13. A composition according to claim 12, wherein said oxidizer is a metal nitrate or metal oxide.

14. A method for generating gas which comprises igniting the composition according to claim 1.

15. A composition comprising a fuel effective amount of at least one heterocyclic compound represented by the formula:

##STR5## wherein X is a non-metallic cation; and

an oxidizing effective amount of at least one oxidizer selected from the group consisting of inorganic nitrites, inorganic nitrates, metal oxides, metal hydroxides, metal peroxides, inorganic chlorates, and inorganic perchlorates.

16. A hybrid gas-generating system comprising:

a pressure tank having a rupturable opening, said pressure tank containing an inert gas;

a gas-generating device for producing hot combustion gases and for rupturing said rupturable opening, said gas-generating device being configured in relation to said pressure tank such that hot combustion gases are mixed with and heat said inert gas, said gas-generating device containing a gas-generating composition comprising (a) a fuel effective amount of at least one heterocyclic compound represented by the formula;

##STR6## wherein X is a non-metallic cation; and

(b) an effective oxidizing amount of at least one oxidizer selected from the group consisting of inorganic nitrites, inorganic nitrates, metal oxides, metal hydroxides, metal peroxides, inorganic perchlorates, and inorganic chlorates; and

means for igniting said gas-generating composition.

17. A hybrid gas-generating system according to claim 16, wherein said inert gas is argon or helium.

18. An automobile air bag system comprising

a collapsed, inflatable air bag;

and a gas generating device connected to said air bag for inflating said air bag, said gas generating device containing a gas generating composition comprising a fuel and an oxidizer therefor, wherein said fuel is a fuel effective amount of at least one heterocyclic compound represented by the forumla;

##STR7## wherein X is a non-metallic cation; and

an oxidizing effective amount of at least one oxidizer selected from the group consisting of inorganic nitrites, inorganic nitrates, metal oxides, metal hydroxides, metal peroxides, inorganic perchlorates, and inorganic chlorates.