Method and apparatus for liquefaction of natural gas

• US 5,473,900 A
• Filed: 04/29/1994
• Issued: 12/12/1995
• Est. Priority Date: 04/29/1994
• Status: Expired due to Term

• Current Assignee: Conocophillips Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Low, William R.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/235,775
• Time in Patent Office: 592 Days
• Field of Search: 62/38, 62/39, 62/9, 62/40
• US Class Current: 62/611
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0207 as at least a three level SCR refrigeration cascade
• CPC Class Codes: F25J 1/0281 characterised by the type of prime driver, e.g. hot gas expander
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: Y10S 62/912 External refrigeration system

Abstract

A process and apparatus for liquefying a natural gas, having a pressure above about 800 psig, in which the natural gas is introduced into an expander which operates to reduce the pressure of the natural gas and extract work from the expansion of the natural gas during the pressure reduction so that the resulting effluent from the expander can be cooled to sequentially lower temperatures by passing the gas through a plurality of cooling stages, in indirect heat exchange with at least one refrigerant, until the gas is substantially completely condensed in the last of the cooling stages.

Claims

1. An apparatus comprising:

pretreater means;

means for introducing a lean natural gas stream at a pressure above about 800 psig and at about ambient temperature to said pretreater means;

closed cycle refrigeration means for cryogenically liquefying said natural gas stream by indirect heat exchange with at least one refrigerant; and

an expander operatively connected between said pretreater means and said refrigeration means for reducing the pressure of said natural gas stream and extracting useful work from said natural gas stream during the pressure reduction wherein said expander is in fluid flow communication with said pretreater and said refrigeration means such that said expander receives said natural gas stream from said pretreater and after pressure reduction, introduces said natural gas stream to said refrigeration means.

2. An apparatus according to claim 1 wherein said refrigeration means is a cascade refrigeration system which receives natural gas effluent from said expander and expands and cools said effluent to about atmospheric pressure and to a temperature below about -258°

F. by indirect heat exchange with at least two refrigerants.

3. An apparatus according to claim 2 wherein said cascade refrigeration system uses ethylene and methane as refrigerants.

4. An apparatus according to claim 2 wherein said expander is a turboexpander.

5. An apparatus according to claim 2 wherein after said expander reduces the pressure of said natural gas stream, said natural gas stream is at a pressure between about 600 psig and about 650 psig and at a temperature below about 0°

F.

6. An apparatus according to claim 1 further comprising:

a first flow conduit having a first end operatively connected between said pretreater means and said expander and having a second end operatively connected between said expander and said refrigeration means to form a parallel bypass flow path for said natural gas stream; and

a Joule-Thomson valve interposed in said first flow conduit, said Joule-Thomson valve being selectively closable to preclude flow of said natural gas stream when said expander is in service and openable to allow flow of said natural gas stream and effect a reduction in the pressure of the feed stream when said expander is out of service.

7. An apparatus according to claim 1 further comprising:

means for converting the work extracted by said expander from said natural gas stream into mechanical or electrical energy, said means for converting work being operatively connected to said expander.

8. In a process for producing liquefied natural gas, a method of improving liquid natural gas production and conserving energy, comprising:

feeding a pressurized natural gas feed stream, at a pressure above about 800 psig and at about ambient temperature, to an expander means, prior to refrigeration of said feed stream;

conducting said feed stream through said expander to reduce the pressure of the stream to a pressure below about 650 psig and to cool the stream to a temperature below about 0°

F.;

extracting work from the feed stream during the reduction of pressure by means of said expander; and

feeding said feed stream from an outlet of said expander to a refrigeration cycle of said process to produce a liquefied natural gas stream at about atmospheric pressure and at a temperature below about -258°

F.

9. A process according to claim 8 wherein said expander is a turboexpander.

10. A process according to claim 8 wherein said refrigeration cycle is a cascade cycle comprising:

(a) cooling said feed stream to a reduced temperature in at least one cooling stage by indirect heat exchange with a first refrigerant having a boiling point;

(b) cooling said feed stream in at least a first additional cooling stage by indirect heat exchange with a second refrigerant, having a boiling point lower than said first refrigerant'"'"'s boiling point;

(c) compressing said first refrigerant after said step (a) to produce a compressed first refrigerant;

(d) cooling said compressed first refrigerant to produce a cooled first refrigerant;

(e) compressing said second refrigerant after step (b) to produce a compressed second refrigerant; and

(f) cooling said compressed second refrigerant by indirect heat exchange with said cooled first refrigerant to produce a cooled second refrigerant.

11. A process according to claim 10 wherein said cascade cycle further comprises:

(g) cooling said feed stream in at least a second additional cooling stage by indirect heat exchange with a third refrigerant, having a boiling point lower than said second refrigerant'"'"'s boiling point;

(h) compressing said third refrigerant after said step (g) to produce a compressed third refrigerant; and

(i) cooling said compressed third refrigerant by indirect heat exchange with either said cooled first refrigerant or said cooled second refrigerant.

12. A process according to claim 8 further comprising pretreating the pressurized natural gas feed stream prior to feeding it to said expander means in order to remove carbon dioxide, hydrogen sulfide and water.