Process for the direct hydrogenation of triglycerides

• US 5,475,160 A
• Filed: 11/07/1994
• Issued: 12/12/1995
• Est. Priority Date: 11/07/1994
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Singleton, David M., Murray, Brendan D.
• Primary Examiner(s): LONE, WERREN
• Application Number:
  US08/335,021
• Time in Patent Office: 400 Days
• Field of Search: 568/861, 568/864, 568/884, 568/885
• US Class Current: 568/864
• CPC Class Codes: B01J 23/80 with zinc, cadmium or mercury
• CPC Class Codes: B01J 23/83 with rare earths or actinides
• CPC Class Codes: C07C 29/149 with hydrogen or hydrogen-containing gases
• CPC Class Codes: C07C 31/125 containing five to twenty-two carbon atoms

Abstract

This invention relates to a process for the direct hydrogenation of triglycerides which comprises contacting and reacting one or more triglyceride with hydrogen under liquid phase hydrogenation conditions in the presence of a catalyst comprising a copper compound, a zinc compound, at least one rare earth compound, and, optionally, a compound selected from the group consisting of aluminum, zirconium, magnesium, and mixtures thereof.

Claims

1. A process for the direct hydrogenation of triglycerides which comprises contacting and reacting one or more triglycerides with hydrogen under liquid phase hydrogenation conditions in the presence of a catalyst comprising a copper compound, a zinc compound and at least one rare earth compound.

2. The process of claim 1 wherein said catalyst additionally comprises at least one compound selected from the group consisting of aluminum, zirconium, magnesium and mixtures thereof.

3. The process of claim 1 wherein said triglyceride is selected from the group consisting of natural oils, vegetables oils and mixtures thereof.

4. The process of claim 3 wherein said triglyceride is a natural oil selected from the group consisting of palm kernel oil, coconut oil, rape seed oil, tallow, palm oil and mixtures thereof.

5. The process of claim 4 wherein said triglyceride is coconut oil.

6. The process of claim 4 wherein said triglyceride is palm kernel oil.

7. The process of claim 3 wherein said triglyceride is a vegetable oil selected from the group consisting of canola oil, soybean oil, safflower oil, corn oil, peanut oil and mixtures thereof.

8. The process of claim 7 wherein said triglyceride is corn oil.

9. The process of claim 1 wherein said catalyst contains from about 10 percent by weight to about 80 percent by weight, calculated as the oxide, basis the total weight of the catalyst, of copper.

10. The process of claim 1 wherein said catalyst contains from about 10 percent by weight to about 80 percent by weight, calculated as the oxide, basis the total weight of the catalyst, of zinc.

11. The process of claim 1 wherein said catalyst contains from about 0.1 percent by weight to about 20 percent by weight, calculated as the oxide, basis the total weight of the catalyst, of rare earth.

12. The process of claim 11 wherein said rare earth is selected from the group consisting of selected from the group consisting of praseodymium, neodymium, yttrium, lanthanum, samarium, thorium, cerium and mixtures thereof.

13. The process of claim 12 wherein said rare earth is lanthanum.

14. The process of claim 2 wherein said catalyst contains aluminum.

15. The process of claim 14 wherein said catalyst contains from about 0.05 percent by weight to about 30 percent by weight, basis the total weight of the catalyst, of aluminum.

16. The process of claim 2 wherein said catalyst contains zirconium.

17. The process of claim 16 wherein said catalyst contains from about 0.05 percent by weight to about 30 percent by weight, basis the total weight of the catalyst, of zirconium.

18. The process of claim 2 wherein said catalyst contains magnesium.

19. The process of claim 18 wherein said catalyst contains from about 0.05 percent by weight to about 30 percent by weight, basis the total weight of the catalyst, of magnesium.

20. The process of claim 1 wherein said process is carried out at a temperature in the range of from about 170°

C. to about 250°

C. and a pressure in the range of from about 300 psig to about 2000 psig.