Method for the direct determination of physical properties of hydrocarbon products

• US 5,475,612 A
• Filed: 03/04/1994
• Issued: 12/12/1995
• Est. Priority Date: 08/18/1987
• Status: Expired due to Term

• Current Assignee: Topnir Systems
• Original Assignee: BP Oil International Limited (BP PLC)
• Inventors: Pasquier, Antoine, Martens, Andre, Lambert, Didier C., Ventron, Gilbert, Espinosa, Alain
• Primary Examiner(s): ZANELLI, MICHAEL J
• Application Number:
  US08/206,250
• Time in Patent Office: 648 Days
• Field of Search: 364/502, 364/497, 364/498, 364/499, 324/307, 324/310, 324/312, 356/300, 356/303, 356/326, 382/17, 250/226, 250/339.07, 250/339.08, 250/339.09, 250/339.12
• US Class Current: 700/268
• CPC Class Codes: F02B 3/06 with compression ignition compression ignition engines using air or gas for blowing fuel into compressed air in cylinder F02B13/02
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: G01N 33/2829 Mixtures of fuels

Abstract

The properties of a liquid hydrocarbon blend are determined from the NIR (Near Infra Red) spectrum of the components of the blend. This is accomplished by: (a) determining with an IR spectrometer, the absorbance of the components of the blend at a certain number of frequencies in the spectral range 16667 to 3840 cm^-1 starting from a defined base line, (b) determining for each component and each property, a spectral mixture index (SMI) by applying a correlation between the SMI and the absorbance values, and then (c) calculating the property (J) to be determined by applying a linear expression, J=f_a SMI_a^J +f_s SMI_b^J +f_c SMI_c^J + . . . f_o SMI_o^J where SMI^J.sub.(a, b, c . . . ) is the Spectral Mixture Index for property J for each component (a, b, c . . . ) and f.sub.(a, b, c . . . ) is the fraction by volume of that component in the final blend. The correlation in (b) is determined experimentally by multivariate regression, and is dependent upon the type of spectrometer used, the property to be determined, and the frequencies used.

Claims

1. A method for preparing a blend of liquid hydrocarbon components and controlling at least one physical property of the blend, the method comprising the following steps:

(a) determining with an IR spectrometer, an absorbance at each of a selected number of frequencies in a spectral range 16667 to 3840 cm^-1 for each component starting from a defined base line,

(b) determining for each component I and each physical property J, a spectral mixture index (SMI)^J_I by applying a correlation with measured absorbance values, wherein the correlation is determined experimentally by multivariate regression of a set of blends serving for calibration and is dependent upon the spectrometer used, the property selected and the frequencies used,

(c) selecting one or more physical properties desired in the blend,

(d) calculating for the selected property J of the blend the quantity of the components required to obtain such physical property by applying a linear expression;

space="preserve" listing-type="equation">J=f.sub.a ·

SMI.sup.J.sub.a +f.sub.b ·

SMI.sup.J.sub.b +f.sub.c ·

SMI.sup.J . . . +f.sub.o ·

SMI.sup.J.sub.o(

     1)

each term of which is a product of the spectral mixture index (SMI_a . . . ) of the property J for a component (A . . . ) and a fraction by volume (f_a . . . ) of this component, and

(e) mixing the calculated quantities of the components to obtain the desired blend.

2. The method according to claim 1 wherein the frequencies are in the spectral range 12500 to 3840 cm^-1.

3. The method according to claim 2 wherein the frequencies are in the spectral range 4760 to 4000 cm^-1.

4. The method according to claim 3 wherein the frequencies used are selected from the following list:

4670 cm^-1

4640 cm^-1

4615 cm^-1

4585 cm^-1

4485 cm^-1

4405 cm^-1

4385 cm^-1

4332 cm^-1

4305 cm^-1

4260 cm^-1

4210 cm^-1

4170 cm^-1

4135 cm^-1

4100 cm^-1

4060 cm^-1 and

4040 cm^-1.

5. The method according to claim 1, wherein the base line is taken as 4780 cm^-1.

6. The method according to claim 1 wherein the spectrometer is linked to a signal processing device to permit numerical treatment of the spectrum.

7. The method according to claim 6 wherein the numerical treatment is by Fourier transformation.

8. The method according to claim 1 wherein the method is on-line and in real time.

9. The method according to claim 1 wherein the properties calculated are non-additive properties of the components.

10. The method according to claim 1 wherein the liquid hydrocarbon blend additionally contains a liquid organic additive.

11. The method according to claim 1 wherein the product is a motor spirit and the property determined is selected from at least one of research and motor octane numbers (clear and leaded), product density, product vapor pressure and product distillation characteristics.

12. The method according to claim 11 wherein the frequencies are selected from the following:

4670 cm^-1

4485 cm^-1

4332 cm^-1

4305 cm^-1

4210 cm^-1

4100 cm^-1 and

4060 cm^-1.

13. The method according to claim 1 wherein the product is a diesel oil and the property determined is selected from the following:

cloud point, pour point, filterability, cetane index, distillation characteristics, flash point and viscosity.

14. The method according to claim 1 wherein the product is a fuel oil and the property determined is selected from the following:

density, viscosity, thermal stability, distillation characteristics and flash point.

15. The method of claim 1 wherein blending equipment is used to produce the blend of liquid hydrocarbon components and said blending equipment is computer controlled by a feedback control system for altering the fraction by volume of each component in the blend in response to variations from a desired value for a property of the blend.

16. A method according to claim 1 wherein the physical property is any one of octane number, research octane number, motor octane number, cloud point, flash point, pour point, cetane index, filterability, viscosity, density, vapor pressure, distillation characteristic, thermal stability, solvent power, and precipitation capacity.

17. A method according to claim 1 wherein the spectral mixture index of a property of a component is determined directly from absorbances obtained for said component alone.

18. A method according to claim 1 wherein the spectral mixture index of a property of a component is determined from the theoretical absorbance of said component by preparing an arbitrary mixture with a fraction of said component in a matrix, determining the NIR spectra for the matrix and the mixture, respectively, and calculating a theoretical absorbance.