Sensor for determining gas components and/or gas concentrations of gas mixtures

• US 5,476,001 A
• Filed: 06/06/1994
• Issued: 12/19/1995
• Est. Priority Date: 12/23/1992
• Status: Expired due to Term

• Current Assignee: Robert Bosch GmbH
• Original Assignee: Robert Bosch GmbH
• Inventors: Neumann, Harald, Gruenwald, Werner, Friese, Karl-Hermann, Riegel, Johann, Hoetzel, Gerhard
• Primary Examiner(s): Chilcot, Richard
• Assistant Examiner(s): Dombroske, George M.
• Application Number:
  US08/244,660
• Time in Patent Office: 561 Days
• Field of Search: 73/116, 73/118.1, 73/23.2, 73/23.31, 73/23.32
• US Class Current: 73/23.31
• CPC Class Codes: G01N 27/419 Measuring voltages or currents with a combination of oxygen pumping cells and oxygen concentration cells

Abstract

A sensor for determining gas components and/or gas concentrations in gas mixtures, in particular in exhaust gases of internal combustion engines. The sensor has an oxygen pump cell and a measuring element having a sensitive region. Provided between the pump cell and the gas mixture is a diffusion path in which there are formed an oxygen gradient XO₂ and a gradient X_CO of the gas component to be determined, which extend respectively in opposite directions. The measuring element is positioned relative to the pump cell and the diffusion path in such a way that an excess of oxygen is present on the sensitive region of the measuring element.

Claims

1. Sensor for determining gas components and/or gas concentrations in gas mixtures, in particular of CO, NO_x and HC in exhaust gases of internal combustion engines, said sensor comprising:

a measuring element having a sensitive regional;

a pump cell with pump electrodes which are arranged on a solid electrolyte, with the pump electrodes causing a transfer of oxygen to the measuring element by utilizing the oxygen ion conduction of the solid electrolyte; and

, a diffusion path for the gas mixture and the oxygen pumped by the pump cell, with the gas mixture and the pumped oxygen being carried to the sensitive region of the measuring cell via the diffusion path; and

wherein;

an electrode of the pump cell is disposed in the diffusion path and is arranged in the direction of the gas mixture downstream of the sensitive region of the measuring element so that a concentration gradient of the gas component to be determined and an oxygen concentration gradient are formed in the diffusion path and run counter to one another; and

, the measuring element is arranged in the diffusion path relative to the gradients such that the oxygen concentration present in the sensitive region of the measuring element is larger than the concentration of the gas component to be determined in the sensitive region so that the measuring element is located in a region of high sensitivity relative to the gas component or gas components to be determined.

2. Sensor according to claim 1 wherein the gas concentration of the component to be measured is set such that a change in gas concentration delivers a change in the sensor signal which is substantially greater than the change in the sensor signal caused by the change in oxygen concentration.

3. Sensor according to claim 1 wherein the maximum concentration, occurring on the sensitive region of the measuring element, of the gas component to be determined is set approximately to the stoichiometric value with regard to the oxygen concentration and does not, however, exceed said value of the oxygen concentration, with the result that the concentration of the gas component to be determined delivers a maximum sensor signal.

4. Sensor according to claim 1, wherein the pump cell has an inner and an outer pump electrode, the measuring element forms an integrated layer system with the pump cell, and the diffusion path is formed by at least one porous layer, with the gradient of the gas component to be determined and the oxygen gradient build up extending respectively in opposite directions in the porous layer.

5. Sensor according to claim 4, wherein a semiconductor gas sensor made from a porous semiconducting metal oxide layer forming the sensitive region is provided as the measuring element.

6. Sensor according to claim 4, wherein a porous insulating layer which forms the diffusion path is arranged on the inner pump electrode, and a semiconducting metal oxide layer of a semiconductor gas sensor, which forms the measuring element, is arranged on the insulating layer.

7. Sensor according to claim 4, wherein the measuring element is an electrochemical measuring cell having an O^-2 -conducting solid electrolyte on which a measuring electrode and a reference electrode are arranged, with the O^-2 -conducting solid electrolyte being constructed in a porous fashion and forming the diffusion path.

8. Sensor according to claim 4, wherein the measuring element is a calorimetric sensor which is arranged on the solid electrolyte carrier, at least two resistors are provided, one of the resistors is embedded in a catalytically active layer, with the result that the temperature of this resistor varies, and the other resistor is assigned to a catalytically inactive layer.

9. Sensor according to claim 8, wherein the catalytically active layer is embodied in a porous fashion and forms the diffusion path.

10. Sensor according to claim 8, wherein a porous insulating layer which forms the diffusion path is arranged on the inner pump electrode.

11. Sensor according to claim 4, wherein the measuring element is an ionization detector having a catalytically active anode arranged in an ionization chamber and a cathode, where by at relatively high temperatures the anode forms positive ions which the cathode extracts by means of an extraction voltage, and the ionization chamber forms the diffusion path.

12. Sensor according to claim 1, wherein the pump cell and the measuring element are arranged spatially separated from one another and are interconnected via a diffusion gap, and the diffusion gap is exposed to the gas mixture by an opening, with the diffusion gap forming the diffusion path, and the oxygen gradient and the gradient of the gas component to be determined building up and extending respectively in opposite directions in the diffusion gap.

13. Sensor according to claim 12, wherein the pump cell has an inner and an outer pump electrode and is arranged at the closed end of the diffusion gap, and the measuring element is arranged in the diffusion gap.

14. Sensor according to claim 12, wherein the measuring element is a semiconductor gas sensor which is arranged on the large face of the diffusion gap introduced into the solid electrolyte.

15. Sensor according to claim 12, wherein the measuring element is an electrochemical measuring cell which is arranged on the large face of the diffusion gap introduced into the solid electrolyte.

16. Sensor according to claim 15, wherein the pump cell has an inner pump electrode and an outer pump electrode, the inner pump electrode simultaneously forms a reference electrode of the measuring cell, and a measuring electrode is arranged on the large face of the diffusion gap.

17. Sensor according to claim 12, wherein the measuring element is a calorimetric gas sensor, which is arranged on the large face of the diffusion gap introduced into the solid electrolyte.

18. Sensor according to claim 12, wherein the measuring element is an ionization detector which is arranged in the diffusion gap such that a catalytic anode and a cathode are situated opposite one another.

19. Sensor according to claim 12, wherein the opening on the exhaust-gas side of the diffusion gap is sealed by an oxidation catalyst which is permeable only to selected gas components.

20. Sensor according to claim 1, wherein the solid electrolyte of the pump cell is constructed in a porous fashion.

21. Sensor according to claim 20, wherein at least one diffusion channel which leads laterally to the porous solid electrolyte is provided for the oxygen to be pumped.

22. Sensor according to claim 20, wherein the diffusion channel is filled with a diffusion body.

23. Sensor according to claim 20, wherein the porous solid electrolyte consists of a mixed ceramic made from stabilized ZrO₂ and Al₂ O₃, preferably in the ration of 1:

1.

24. Sensor according to claim 20, wherein a the substrate is provided with at least one cover layer in which a cutout is provided over the pump cell, and the measuring element is arranged in the cutout.

25. Sensor according to claim 24, wherein at least one opening which leads to at least one of the lateral diffusion channels is provided on the cover layer.

26. Sensor according to claim 25, wherein a porous diffusion layer which is laid over the pump electrode and over which the measuring element is located, is provided in the cutout so that it is possible for the oxygen to diffuse from the pump cell to the measuring element via the porous layer.

27. Sensor according to claim 1, wherein a porous layer which forms a diffusion barrier is applied to the measuring element.