Method for producing synthesis gas

• US 5,478,370 A
• Filed: 07/01/1994
• Issued: 12/26/1995
• Est. Priority Date: 07/01/1994
• Status: Expired due to Fees

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Spangler, Michael J.
• Primary Examiner(s): KRATZ, PETER F
• Application Number:
  US08/269,699
• Time in Patent Office: 543 Days
• Field of Search: 48/92, 48/197 R, 48/198.2, 48/198.3, 48/198.5, 48/198.7, 252/373
• US Class Current: 48/197.00R
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0238 the reforming step being a carbon dioxide reforming step
• CPC Class Codes: C01B 2203/0415 Purification by absorption in liquids
• CPC Class Codes: C01B 2203/0475 the impurity being carbon dioxide
• CPC Class Codes: C01B 2203/06 Integration with other chemical processes
• CPC Class Codes: C01B 2203/061 Methanol production
• CPC Class Codes: C01B 2203/062 Hydrocarbon production, e.g. Fischer-Tropsch process
• CPC Class Codes: C01B 2203/0838 by heat exchange with exothermic reactions, other than by combustion of fuel
• CPC Class Codes: C01B 2203/0894 Generation of steam
• CPC Class Codes: C01B 2203/1011 Packed bed of catalytic structures, e.g. particles, packing elements
• CPC Class Codes: C01B 2203/1052 Nickel or cobalt catalysts
• CPC Class Codes: C01B 2203/1064 Platinum group metal catalysts
• CPC Class Codes: C01B 2203/1241 Natural gas or methane
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated

Abstract

The invention provides an improved method for producing synthesis gas from lower alkanes which utilizes molten baths as reactors. A molten metal oxide bath delivers oxygen to a feed stream containing lower alkanes and enhances oxidation of the lower alkanes to produce carbon dioxide and a molten elemental metal. In a molten metal bath, the metal is regenerated to metal oxide by contact with a regenerant such as air. Heat evolved in the molten baths is transferred to an endothermic reactor where a portion of the carbon dioxide is converted to a mixture of carbon oxides and hydrogen.

Claims

1. A process for producing synthesis gas, which comprises:

passing a feed stream composed substantially of a lower alkane having from one to four carbon atoms and an influent oxidant stream which includes a molten metal oxide through a combustion zone to produce an oxidized product stream which includes carbon dioxide and water and an effluent oxidant stream which includes relatively less of the metal oxide as compared to the influent oxidant stream;

passing the effluent oxidant stream and a regenerant stream including oxygen and nitrogen through an exothermic regeneration zone to produce a regenerated oxidant stream and an exhaust stream; and

passing the oxidized product stream to an endothermic reforming zone containing a reforming catalyst to produce a synthesis gas stream which includes carbon monoxide and hydrogen;

wherein at least a portion of the heat liberated in the regeneration zone is transferred to the reforming zone.

2. The process of claim 1 wherein the lower alkane in the feed stream is partially reacted in the combustion zone and an unreacted portion of the lower alkane is passed to the reforming zone.

3. The process of claim 1 wherein an additional quantity of the lower alkane is mixed with the oxidized product stream and the resulting mixture is passed to the reforming zone.

4. The process of claim 1 wherein the reforming zone is adjacent to a heat exchanger having two heat transfer surfaces, the regenerated oxidant stream is passed into proximity with one of the heat transfer surfaces, and the effluent oxidant stream is passed into proximity With another of the heat transfer surfaces.

5. The process of claim 1 wherein the molten metal oxide is the oxide of a metal selected from the group consisting of lead, antimony, bismuth, copper, zinc, tin, indium, and mixtures thereof.

6. The process of claim 1 wherein the regenerant stream is air.

7. The process of claim 1 wherein the exhaust stream contains a substantial amount of diatomic oxygen.

8. The process of claim 1 wherein the reforming catalyst contains a metal selected from the group consisting of nickel, copper, zinc, noble metals and mixtures thereof.

9. The process of claim 1 wherein steam is injected into the reforming zone.

10. The process of claim 1 wherein the combustion zone is at a temperature in the range of about 600°

C. to about 1200°

C.

11. The process of claim 1 wherein the synthesis gas stream is nitrogen-free.

12. The process of claim 1 wherein the lower alkane is methane.

13. A continuous process for producing synthesis gas which comprises:

passing a feed stream composed substantially of a lower alkane and an influent oxidant stream which includes a molten metal oxide through a combustion zone to produce a substantially oxidized product stream which contains carbon dioxide and water and an effluent oxidant stream which includes relatively less of the metal oxide as compared to the influent oxidant stream;

mingling the effluent oxidant stream and an air stream which reacts exothermically with the effluent oxidant stream to produce heat, an exhaust stream, and an at least partially regenerated oxidant stream;

transferring heat from the regenerated oxidant stream to the oxidized product stream through a heat exchanger having a relatively warmer heat transfer surface exposed to the regenerated oxidant stream and a cooler heat transfer surface exposed to the oxidized product stream;

passing the oxidized product stream to a reforming zone which contains a reforming catalyst to produce a synthesis gas stream by an endothermic chemical reaction; and

passing the regenerated oxidant stream to the combustion zone.

14. The process of claim 13 wherein an additional quantity of the lower alkane is mixed with the oxidized product stream.

15. The process of claim 13 wherein the molten metal oxide is the oxide of a metal selected from the group consisting of lead, antimony, bismuth, copper, zinc, tin, and mixtures thereof.

16. The process of claim 13 wherein steam is injected into the reforming zone.

17. The process of claim 13 wherein the synthesis gas is nitrogen-free.

18. The process of claim 13 wherein the effluent oxidant stream is atomized and sprayed into the air stream.

19. The process of claim 13 wherein the feed stream is preheated before being passed to the combustion zone.

20. The process of claim 13 wherein the lower alkane is methane.