Nonaqueous secondary battery
First Claim
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1. A nonaqueous secondary battery which comprises a cathode active material, an anode active material and an electrolytic solution;
- wherein said anode active material comprises a transition metal oxide, said cathode active material comprises a lithium-containing transition metal oxide represented by Liy Oz in which M is at least one transition metal selected from the group consisting of Co, Mn, Ni, V and Fe, y is in the range of 0.3 to 1.2, and z is in the range of 1.4 to 3, and said electrolytic solution comprises a fluorine-containing lithium salt in a mixed solvent which comprises ethylene carbonate in an amount of 5 to 40% by volume and at least one selected from the group consisting of diethyl carbonate, ethyl methyl carbonate and dimethoxyethane, the latter being present in an amount of 60 to 95% by volume.
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Abstract
A nonaqueous secondary battery comprises an anode active material, a cathode active material and an electrolytic solution. The anode active material comprises a transition metal oxide, and the electrolytic solution is prepared by dissolving a fluorine-containing lithium salt in a mixed solvent comprising ethylene carbonate and at least one selected from the group consisting of chain carbonic acid esters, cyclic carbonic acid esters, cyclic esters, chain ethers and cyclic ethers.
72 Citations
15 Claims
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1. A nonaqueous secondary battery which comprises a cathode active material, an anode active material and an electrolytic solution;
wherein said anode active material comprises a transition metal oxide, said cathode active material comprises a lithium-containing transition metal oxide represented by Liy Oz in which M is at least one transition metal selected from the group consisting of Co, Mn, Ni, V and Fe, y is in the range of 0.3 to 1.2, and z is in the range of 1.4 to 3, and said electrolytic solution comprises a fluorine-containing lithium salt in a mixed solvent which comprises ethylene carbonate in an amount of 5 to 40% by volume and at least one selected from the group consisting of diethyl carbonate, ethyl methyl carbonate and dimethoxyethane, the latter being present in an amount of 60 to 95% by volume. - View Dependent Claims (2, 3, 4, 5, 6)
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7. A nonaqueous secondary battery which comprises a cathode active material, an anode active material and an electrolytic solution;
wherein said anode active material comprises a transition metal oxide of which an inherent crystal structure has been changed by insertion of lithium ions and is in a condition that said changed crystal structure is essentially not changed during repeated charging and discharging, and said electrolytic solution comprises a fluorine-containing lithium salt in a mixed solvent which comprises ethylene carbonate and at least one selected from the group consisting of chain carbonic acid esters, cyclic carbonic acid esters having 5 or more carbon atoms, cyclic esters, chain ethers and cyclic ethers. - View Dependent Claims (8, 9, 10, 11, 12, 13, 14, 15)
Specification