Ultraviolet ray absorbent glass and method for preparing the same

• US 5,480,722 A
• Filed: 06/30/1993
• Issued: 01/02/1996
• Est. Priority Date: 07/03/1992
• Status: Expired due to Fees

• Current Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Original Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Inventors: Morimoto, Takeshi, Tomonaga, Hiroyuki, Hiratsuka, Kazuya
• Primary Examiner(s): Robinson, Ellis P.
• Assistant Examiner(s): Speer, Timothy M.
• Application Number:
  US08/083,526
• Time in Patent Office: 916 Days
• Field of Search: 428/428, 428/432, 428/697, 428/699, 428/701, 428/702, 428/333, 428/336, 428/201, 428/210, 359/350, 359/359, 359/361
• US Class Current: 428/428
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/72 Decorative coatings
• CPC Class Codes: C03C 2217/74 UV-absorbing coatings
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: Y10T 428/24851 Intermediate layer is discontinuous or differential
• CPC Class Codes: Y10T 428/24926 including ceramic, glass, porcelain or quartz layer
• CPC Class Codes: Y10T 428/261 In terms of molecular thickness or light wave length
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

A ultraviolet ray absorbent glass comprises a substrate glass, a ultraviolet ray absorbent film including as the major component at least one selected from the group consisting of zinc oxide, titanium oxide and cerium oxide, and an intermediate film having an intermediate refractive index which is between the refractive indices of the ultraviolet absorbent film and the substrate glass, the intermediate film being located between the ultraviolet absorbent film and the substrate glass, whereby iridescence by the ultraviolet ray absorbent film is reduced, and a heat reflecting function is imparted.

Claims

1. An ultraviolet ray absorbent glass which comprises:

a substrate glass,

an ultraviolet ray absorbent film having a thickness of 100-800 nm comprising at least two members selected from the group consisting of zinc oxide, titanium oxide and cerium oxide, and

a transparent metal oxide intermediate film comprising at least two components selected from the group consisting of silicon oxide, germanium oxide, aluminum oxide, zirconium oxide, titanium oxide, tin oxide, indium oxide, tantalum oxide, zinc oxide and cerium oxide, provided that at least one component is selected from the group consisting of zing oxide, titanium oxide and cerium oxide, having refractive index which is between the refractive indices of the ultraviolet ray absorbent film and the substrate glass, the intermediate film having an optical film thickness of λ

/4±

10% as large as the wavelength of visible light of 400-700 nm, said intermediate film being located between the ultraviolet ray absorbent film and the substrate glass, whereby iridescence by the ultraviolet ray absorbent film is reduced, and a heat reflecting function is imparted.

2. The ultraviolet ray absorbent glass according to claim 1, wherein the intermediate film is an intermediate film which satisfies the equation of n_m =(n_f ×

n_g)^1/2 ±

10% where n_f is the refractive index of the ultraviolet ray absorbent film, n_g is the refractive index of the substrate glass and n_m is the refractive index of the intermediate film.

3. The ultraviolet absorbent glass according to claim 2, wherein n_m =(n_f ×

n_g)^1/2.

4. The ultraviolet ray absorbent glass according to claim 1, wherein the ultraviolet ray absorbent film comprises cerium oxide, titanium oxide and silicon oxide.

5. The ultraviolet ray absorbent glass according to claim 1, wherein the intermediate film includes an electric conductive component.

6. The ultraviolet ray absorbent glass according to claim 1, wherein the intermediate film is partially omitted while the ultraviolet ray absorbent film is formed whereby an interference color is produced at the portion of the ultraviolet ray absorbent film where the intermediate film is partially omitted, thereby providing a transparent ornament or a design in the glass.

7. The ultraviolet ray absorbent glass according to claim 1, wherein the optical film thickness of the intermediate film is λ

/4.

8. The ultraviolet ray absorbent glass according to claim 1, wherein said ultraviolet ray absorbent film has a refractive index in the range of about 1.9-2.1.

9. The ultraviolet ray absorbent glass according to claim 1, wherein said metal oxide intermediate film is a two metal oxide component film selected from the group consisting of ZnO--SiO₂, ZnO--Al₂ O₃, ZnO--GeO₂, ZnO--ZrO₂, TiO₂ --SiO₂, TiO₂ --Al₂ O₃, TiO₂ GeO₂, TiO₂ --ZrO₂, CeO₂ --SiO₂, CeO₂ --Al₂ O₃, CeO₂ --GeO₂ and CeO₂ --ZrO₂.