Photochemical method for converting carbon dioxide gas to organic substances

• US 5,482,599 A
• Filed: 05/05/1994
• Issued: 01/09/1996
• Est. Priority Date: 06/17/1992
• Status: Expired due to Fees

• Current Assignee: Advantest Corporation
• Original Assignee: Advantest Corporation
• Inventors: Watanabe, Masao
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Wong, Edna
• Application Number:
  US08/196,113
• Time in Patent Office: 614 Days
• Field of Search: 204/157.15, 204/157.6, 204/157.9
• US Class Current: 204/157.15
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: C07C 1/12 from carbon dioxide with hydrogen
• CPC Class Codes: C07C 2523/06 of zinc, cadmium or mercury
• CPC Class Codes: C07C 2523/30 Tungsten
• CPC Class Codes: C07C 29/159 with reducing agents other than hydrogen or hydrogen-containing gases
• CPC Class Codes: C07C 31/04 Methanol
• CPC Class Codes: Y02P 20/141 Feedstock
• CPC Class Codes: Y02P 20/50 Improvements relating to the production of bulk chemicals
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

Fine particles of ZnO are subjected to heat treatment at 400° C. for four hours under vacuum to activate the surfaces thereof, the activated ZnO particles are brought into contact with saturated water vapor, and then subjected to irradiation by visible light under an atmosphere of CO₂ gas or CO₂ /H₂ O mixture gas at 5° C. and 33 atm, that is, under the clathrate hydrate phase forming conditions.

Claims

1. A photochemical method for converting carbon dioxide gas to an organic substance, comprising the steps of:

(a) heating metallic oxide particles to activate the surfaces thereof,

(b) forming a clathrate hydrate phase of water in contact with the surface activated metallic oxide particles,

(c) introducing carbon dioxide gas into the clathrate hydrate phase, and

(d) irradiating the surface activated metallic oxide particles with visible light and converting the carbon dioxide gas to the organic substance.

2. The method according to claim 1, wherein the clathrate hydrate phase is formed at a temperature of 0°

to 10°

C. and a pressure of 30 to 40 atm.

3. The method according to claim 1, wherein said metallic oxide particles comprise particles of ZnO.

4. The method according to claim 1, wherein said metallic oxide particles comprise particles of WO₃.