Electrochemical fuel cell stack with compression mechanism extending through interior manifold headers

• US 5,484,666 A
• Filed: 09/20/1994
• Issued: 01/16/1996
• Est. Priority Date: 09/20/1994
• Status: Expired due to Fees

• Current Assignee: Ballard Power Systems Corporation (Siemens AG)
• Original Assignee: Ballard Power Systems Corporation (Siemens AG)
• Inventors: Schlosser, Wolfgang, Gibb, Peter, Voss, Henry H., Pow, Eric G.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/309,124
• Time in Patent Office: 483 Days
• Field of Search: 429/34, 429/38, 429/39, 429/37, 429/12, 429/32
• US Class Current: 429/434
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: H01M 8/247 Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
• CPC Class Codes: H01M 8/248 Means for compression of the fuel cell stacks
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: H01M 8/2484 characterised by external manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrochemical fuel cell stack has a first end plate, a second end plate, and fuel cell assemblies interposed therebetween. Each fuel cell assembly includes a membrane electrode assembly having at least one manifold header opening formed in the assembly for directing at least one of a fluid fuel stream, a fluid oxidant stream and a fluid coolant stream through the assembly. A tie rod extends within the opening and through each of the first and second end plates. Fastening means are disposed at opposite ends of the tie rod. Compressive means are interposed between at least one of the fastening means and at least one of the first and second end plates. In operation, the fastening means and the compressive means urge the first end plate toward the second end plate, thereby applying compressive force to the fuel cell assemblies.

Claims

1. An electrochemical fuel cell stack for producing electrical energy and reaction product from a fluid fuel stream and a fluid oxidant stream, said stack comprising:

(a) a first end plate;

(b) a second end plate;

(c) at least one fuel cell assembly interposed between said first and second end plates, said at least one fuel cell assembly comprising a membrane electrode assembly having a catalytically active region and further having at least one opening formed therein extending through said catalytically active region;

(d) a compression assembly comprising at least one restraining member extending within said at least one opening, fastening means disposed at opposite ends of said at least one restraining member, and compressive means interposed between at least one of said fastening means and at least one of said first and second end plates;

whereby said fastening means and said compressive means urge said first end plate toward said second end plate, thereby applying compressive force to said at least one fuel cell assembly.

2. The electrochemical fuel cell stack of claim 1 wherein said compressive means is integral with said restraining member.

3. The electrochemical fuel cell stack of claim 1 wherein said at least one opening directs at least of one of said fluid fuel and oxidant streams through said at least one fuel cell assembly.

4. The electrochemical fuel cell stack of claim 1 wherein said at least one opening is substantially surrounded by said catalytically active region.

5. The electrochemical fuel cell stack of claim 1 wherein said at least one fuel cell assembly further comprises a pair of fluid flow field plates, said fluid flow field plates being disposed on opposite sides of said membrane electrode assembly and having at least one opening formed therein corresponding with said at least one opening formed in said at least one membrane electrode assembly, and said at least one restraining member extending through said at least one opening formed in said membrane electrode assembly and through said at least one opening formed in said fluid flow field plates.

6. The electrochemical fuel cell stack of claim 1 wherein at least one of said first end plate and said second end plate has a cavity formed on the side facing away from membrane electrode assembly, said compressive means mounted within said cavity.

7. The electrochemical fuel cell stack of claim 1 wherein said compressive means comprises at least one disc spring.

8. The electrochemical fuel cell stack of claim 7 wherein said at least one disc spring comprises a plurality of stacked disc springs.

9. The electrochemical fuel cell stack of claim 1 wherein said compressive means comprises a coiled spring.

10. The electrochemical fuel cell stack of claim 1 wherein said at least one restraining member is threaded at each of its opposite ends and said fastening means comprise correspondingly threaded nuts.

11. The electrochemical fuel cell stack of claim 1 wherein each of said first and second end plates is square, said at least one membrane electrode assembly has at least four openings formed therein, and said at least one restraining member comprises four restraining members extending through said openings, each of said restraining members extending through said first and second end plates substantially at the center of the quadrants thereof.

12. The electrochemical fuel cell stack of claim 1 wherein said at least one restraining member is a single restraining member extending through said first and second end plates substantially at the center thereof.

13. An electrochemical fuel cell stack for producing electrical energy and reaction product from a fluid fuel stream and a fluid oxidant stream, said stack comprising:

(a) a fluid coolant stream;

(b) a first end plate;

(c) a second end plate;

(d) at least one fuel cell assembly interposed between said first and second end plates, said at least one fuel cell assembly comprising a membrane electrode assembly having a catalytically active region and further having at least one opening formed therein extending through said catalytically active region;

(e) a compression assembly comprising at least one restraining member extending within said at least one opening, fastening means disposed at opposite ends of said at least one restraining member, and compressive means interposed between at least one of said fastening means and at least one of said first and second end plates;

whereby said fastening means and said compressive means urge said first end plate toward said second end plate, thereby applying compressive force to said at least one fuel cell assembly.

14. The electrochemical fuel cell stack of claim 13 wherein said compressive means is integral with said restraining member.

15. The electrochemical fuel cell stack of claim 13 wherein said at least one opening directs at least of one of said fluid fuel, oxidant and coolant streams through said fuel cell assembly.

16. The electrochemical fuel cell stack of claim 13 wherein said at least one opening is substantially surrounded by said catalytically active region.

17. The electrochemical fuel cell stack of claim 13 wherein said at least one fuel cell assembly further comprises a pair of fluid flow field plates, said fluid flow field plates disposed on opposite sides of said membrane electrode assembly and having at least one opening formed therein corresponding with said at least one opening formed in said at least one membrane electrode assembly, said at least one restraining member extending through said at least one opening formed in said membrane electrode assembly and through said at least one opening formed in said fluid flow field plates.

18. The electrochemical fuel cell stack of claim 13 wherein at least one of said first end plate and said second end plate has a cavity formed on the side facing away from said membrane electrode assembly, said compressive means mounted within said cavity.

19. The electrochemical fuel cell stack of claim 13 wherein said compressive means comprises at least one disc spring.

20. The electrochemical fuel cell stack of claim 19 wherein said at least one disc spring comprises a plurality of stacked disc springs.

21. The electrochemical fuel cell stack of claim 13 wherein said compressive means comprises a coiled spring.

22. The electrochemical fuel cell stack of claim 13 wherein said at least one restraining member is threaded at each of its opposite ends and said fastening means comprise correspondingly threaded nuts.

23. The electrochemical fuel cell stack of claim 13 wherein each of said first and second end plates is square, said at least one membrane electrode assembly has at least four openings formed therein, and said at least one restraining member comprises four restraining members extending through said openings, each of said restraining members extending through said first and second end plates substantially at the center of the quadrants thereof.

24. The electrochemical fuel cell stack of claim 13 wherein said at least one restraining member is a single restraining member extending through said first and second end plates substantially at the center thereof.

25. An electrochemical fuel cell stack for producing electrical energy and reaction product from a fluid fuel stream and a fluid oxidant stream, said stack comprising a fuel stream inlet, an oxidant stream inlet, and at least one fuel cell assembly comprising a membrane electrode assembly having a catalytically active region, said at least one fuel cell assembly having openings formed therein extending through said catalytically active region, said openings comprising an inlet fuel stream header opening and an inlet oxidant stream header opening, wherein said inlet fuel stream header opening is in direct, unbranched fluid communication with said fuel stream inlet and said inlet oxidant stream header opening is in direct, unbranched fluid communication with said oxidant stream inlet.

26. The electrochemical fuel cell stack of claim 25 further comprising a fuel stream outlet and an oxidant stream outlet, wherein said openings further comprise an outlet fuel stream header opening and an outlet oxidant stream header opening.

27. The electrochemical fuel cell stack of claim 26 wherein said outlet fuel stream header opening is in direct, unbranched fluid communication with said fuel stream outlet and said outlet oxidant stream header opening is in direct, unbranched fluid communication with said oxidant stream outlet.