Diffusion vent for a rechargeable metal-air cell

• US 5,486,429 A
• Filed: 04/24/1995
• Issued: 01/23/1996
• Est. Priority Date: 04/24/1995
• Status: Expired due to Fees

• Current Assignee: Gillette Company (The Procter & Gamble Company)
• Original Assignee: AER Energy Resources, Inc.
• Inventors: Thibault, William C.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/428,005
• Time in Patent Office: 274 Days
• Field of Search: 429/27.4, 429/53, 429/54, 429/55, 429/57, 429/72, 429/82, 429/89, 429/86, 220/89.1, 220/367.1, 220/203.1, 220/203.11, 220/203.13
• US Class Current: 429/403
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present invention provides a system for venting gas from within a case housing a metal-air cell having a cathode and an anode with a separator positioned therebetween. The cell has at least one gas vent on the anode side of the separator that extends from the interior surface of the case to the exterior surface. Each gas vent has a gas vent cap thereon on the interior surface of the case. A gas permeable, hydrophobic membrane is positioned between each gas vent and gas vent cap. The gas vent, with the gas vent cap positioned thereon, prevents the anode from blocking the venting of gas through the membrane.

Claims

1. A system for venting gas from within a case housing a metal-air cell having a cathode and an anode with a separator position therebetween, said case having an interior surface and an exterior surface, comprising:

at least one gas vent in said case on the anode side of said separator;

said gas vent extending from said interior surface of said case to said exterior surface of said case;

a gas vent cap covering each one of the said gas vents on said interior surface of said case; and

a gas permeable, hydrophobic membrane positioned between each pair of said gas vents and said gas vent caps;

said gas vent cap being configured to prevent said anode from blocking the venting of gas through said membrane.

2. The apparatus of claim 1 wherein said gas vent cap has at least one draining channel therein extending from said gas vent to said interior surface of said case.

3. The apparatus of claim 1 wherein said case, said gas vent, and said gas vent cap comprise polypropylene.

4. The apparatus of claim 1 wherein said gas permeable, hydrophobic membrane comprises polytetrafluouroethylene ("PTFE").

5. The apparatus of claim 1 wherein gas vent defines a plurality of gas collection channels in communication with said membrane.

6. The apparatus of claim 5 wherein said gas collection channels are defined by a series of plateaus supporting said membrane.

7. The apparatus of claim 1 wherein said gas vent is dome-like in shape.

8. The apparatus of claim 1 wherein said gas vent cap comprises an annular ring and a plurality of tabs protruding therefrom into said cell.

9. The apparatus of claim 1 further comprising support pegs positioned on said interior surface on said anode side of said case.

10. The apparatus of claim 1 wherein said gas permeable, hydrophobic membrane is held in place by pinching said membrane between said gas vent and said gas vent cap.

11. The apparatus of claim 10 wherein said gas vent is encircled by a plurality of ribs that assist in pinching said gas permeable, hydrophobic membrane between said gas vent and said gas vent cap.

12. The apparatus of claim 1 wherein said gas vent and said gas vent cap are joined via ultrasonic welding.

13. The apparatus of claim 1 further comprising a valve positioned on the exterior surface of said case over each of said gas vents.

14. The apparatus of claim 13 wherein said valve provides pressure relief for said cell and prevents gas intrusion into said cell.

15. The apparatus of claim 13 wherein said valve comprises a strip of thin material with a slit therein that deforms while under pressure.

16. A system for venting gas from within a polypropylene case housing a metal-air cell having a cathode and an anode with a separator position therebetween, said case having an interior surface and an exterior surface, comprising:

at least one gas vent in said case on the anode side of said separator;

said gas vent extending from said interior surface of said case to said exterior surface of said case;

a gas vent cap covering each one of the said gas vents on said interior surface of said case; and

a polytetrafluouroethylene ("PTFE") membrane positioned between each pair of said gas vents and said gas vent cap;

said PTFE membrane held in place by pinching said membrane between said gas vent and said gas vent cap.

17. The apparatus of claim 16 wherein said gas vent cap has at least one draining channel therein extending from said gas vent to said interior surface of said case.

18. The apparatus of claim 16 wherein said gas vent cap is configured to prevent said anode from blocking the venting of gas through said membrane.

19. The apparatus of claim 16 wherein gas vent defines a plurality of gas collection channels in communication with said membrane.

20. The apparatus of claim 16 wherein said gas vent is dome-like in shape.

21. The apparatus of claim 16 further comprising support pegs positioned on said interior surface on said anode side of said case.

22. The apparatus of claim 16 wherein said gas vent cap comprises an annular ring and a plurality of tabs protruding therefrom into said cell.

23. The apparatus of claim 16 wherein said gas vent is encircled by a plurality of ribs that assist in pinching said gas permeable, hydrophobic membrane between said gas vent and said gas vent cap.

24. The apparatus of claim 16 wherein said gas vent and said gas vent cap are joined via ultrasonic welding.

25. The apparatus of claim 16 further comprising a valve positioned on the exterior surface of said case over each of said gas vents.

26. The apparatus of claim 25 wherein said valve provides pressure relief for said cell and prevents gas intrusion into said cell.

27. The apparatus of claim 25 wherein said valve comprises a strip of thin material with a slit therein that deforms while under pressure.

28. A system for venting gas from within a polypropylene case housing a metal-air cell having a cathode and an anode with a separator position therebetween, said case having an interior surface and an exterior surface, comprising:

at least one gas vent in said case on the anode side of said separator;

said gas vent extending from said interior surface of said case to said exterior surface of said case;

a gas vent cap covering each one of the said gas vents on said interior surface of said case;

said gas vent cap having at least one draining channel therein extending from said gas vent to said interior surface of said case; and

a polytetrafluouroethylene ("PTFE") membrane positioned between each pair of said gas vents and said gas vent caps.

29. The apparatus of claim 28 wherein gas vent defines a plurality of gas collection channels in communication with said membrane.

30. The apparatus of claim 28 wherein said gas vent cap is configured to prevent said anode from blocking the venting of gas through said membrane.

31. The apparatus of claim 28 wherein said gas vent is dome-like in shape.

32. The apparatus of claim 28 further comprising support pegs positioned on said interior surface on said anode side of said case.

33. The apparatus of claim 28 wherein said gas vent cap comprises an annular ring and a plurality of tabs protruding therefrom into said cell.

34. The apparatus of claim 28 wherein said gas permeable, hydrophobic membrane is held in place by pinching said membrane between said gas vent and said gas vent cap.

35. The apparatus of claim 34 wherein said gas vent is encircled by a plurality of ribs that assist in pinching said gas permeable, hydrophobic membrane between said gas vent and said gas vent cap.

36. The apparatus of claim 28 wherein said gas vent and said gas vent cap are joined via ultrasonic welding.

37. The apparatus of claim 28 further comprising a valve positioned on the exterior surface of said case over each of said gas vents.

38. The apparatus of claim 37 wherein said valve provides pressure relief for said cell and prevents gas intrusion into said cell.

39. The apparatus of claim 37 wherein said valve comprises a strip of thin material with a slit therein that deforms while under pressure.

40. A system for venting gas from within a case housing a metal-air cell having a cathode and an anode with a separator position therebetween, said case having an interior surface and an exterior surface, comprising:

at least one gas vent in said case on the anode side of said separator;

said gas vent extending from said interior surface of said case to said exterior surface of said case;

a gas vent cap covering each one of the said gas vents on said interior surface of said case;

a gas permeable, hydrophobic membrane positioned between each pair of said gas vents and said gas vent caps; and

a plurality of support pegs positioned on said interior surface on said anode side of said case;

said support pegs and said gas vents with said gas caps positioned thereon defining a gas collection area on said interior surface of said case.

41. The apparatus of claim 40 wherein said gas vent cap has at least one draining channel therein extending from said gas vent to said interior surface of said case.

42. The apparatus of claim 40 wherein said case, said gas vent, and said gas vent cap comprise polypropylene.

43. The apparatus of claim 40 wherein said gas permeable, hydrophobic membrane comprises polytetrafluouroethylene ("PTFE").

44. The apparatus of claim 40 wherein said gas vent defines a plurality of gas collection channels in communication with said membrane.

45. The apparatus of claim 40 wherein said gas vent cap is configured to prevent said anode from blocking the venting of gas through said membrane.

46. The apparatus of claim 40 wherein said gas vent cap comprises an annular ring and a plurality of tabs protruding therefrom into said cell.

47. The apparatus of claim 40 wherein said gas permeable, hydrophobic membrane is held in place by pinching said membrane between said gas vent and said gas vent cap.

48. The apparatus of claim 47 wherein said gas vent is encircled by a plurality of ribs that assist in pinching said gas permeable, hydrophobic membrane between said gas vent and said gas vent cap.

49. The apparatus of claim 40 wherein said gas vent and said gas vent cap are joined via ultrasonic welding.

50. The apparatus of claim 40 further comprising a valve positioned on the exterior surface of said case over each of said gas vents.

51. The apparatus of claim 50 wherein said valve provides pressure relief for said cell and prevents gas intrusion into said cell.

52. The apparatus of claim 50 wherein said valve comprises a strip of thin material with a slit therein that deforms while under pressure.

53. A system for venting gas from within a case housing a metal-air cell having a cathode and an anode with a separator position therebetween, said case having an interior surface and an exterior surface, comprising:

at least one gas vent in said case on the anode side of said separator;

said gas vent extending from said interior surface of said case to said exterior surface of said case;

a gas vent cap covering each one of the said gas vents on said interior surface of said case;

a gas permeable, hydrophobic membrane positioned between each pair of said gas vents and said gas vent caps; and

a strip of thin material with a slit therein that deforms while under pressure positioned on the exterior surface of said case over each of said gas vents.

54. The apparatus of claim 53 wherein said case, said gas vent, and said gas vent cap comprise polypropylene.

55. The apparatus of claim 53 wherein said gas permeable, hydrophobic membrane comprises polytetrafluouroethylene ("PTFE").

56. The apparatus of claim 53 wherein said gas vent cap has at least one draining channel therein on said interior surface of said case.

57. The apparatus of claim 53 wherein said gas vent cap is configured to prevent said anode from blocking the venting of gas through said membrane.

58. The apparatus of claim 53 wherein said gas vent is dome-like in shape.

59. The apparatus of claim 53 further comprising support pegs positioned on said interior surface on said anode side of said case.

60. The apparatus of claim 53 wherein said gas vent cap comprises an annular ring and a plurality of tabs protruding therefrom into said cell.

61. The apparatus of claim 53 wherein said gas permeable, hydrophobic membrane is held in place by pinching said membrane between said gas vent and said gas vent cap.

62. The apparatus of claim 61 wherein said gas vent is encircled by a plurality of ribs that assist in pinching said gas permeable, hydrophobic membrane between said gas vent and said gas vent cap.

63. The apparatus of claim 53 wherein said gas vent and said gas vent cap are joined via ultrasonic welding.

64. The apparatus of claim 53 wherein said strip of thin material with a slit therein that deforms while under pressure provides pressure relief for said cell and prevents gas intrusion into said cell.

65. The apparatus of claim 53 wherein said gas vent defines a plurality of gas collection channels in communication with said membrane.