Copper salts for laser marking of thermoplastic compositions

• US 5,489,639 A
• Filed: 08/18/1994
• Issued: 02/06/1996
• Est. Priority Date: 08/18/1994
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Hoeks, Theodorus L., Volkers, Andre, Faber, Rein M.
• Primary Examiner(s): SANDERS, KRIELLION ANTIONETTE
• Application Number:
  US08/292,644
• Time in Patent Office: 537 Days
• Field of Search: 430/200, 430/945, 523/137, 524/417, 524/418, 524/423
• US Class Current: 524/417
• CPC Class Codes: B41M 5/267 Marking of plastic artifacts, e.g. with laser
• CPC Class Codes: C08K 3/30 Sulfur-, selenium- or tellurium-containing compounds
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

A laser markable thermoplastic composition which contains a copper phosphate salt such as copper phosphate, copper sulfate, cupric hydroxide phosphate and copper thiocyanate. The copper phosphate salt is preferably added in an amount ranging from about 0.1 to 5 parts by weight and the copper phosphate salt preferably has a particle size less than 10 μm. The laser markable thermoplastic composition can be laser marked to provide a visibly distinct and separately identifiable region which preferably differs in overall color from the base material by a Delta E value of at least 10-20.

Claims

1. A laser markable thermoplastic composition, comprising:

(a) at least one thermoplastic resin composition suitable for laser marking; and

(b) at least one copper salt selected from the group consisting of copper phosphate, copper sulfate, and copper thiocyanate, wherein said copper salt is present in an amount sufficient to cause said laser markable thermoplastic con, position to absorb a laser light outside the visible spectrum such that the portion of said composition which absorbs said laser light has a visibly distinct and separately identifiable color.

2. The thermoplastic composition of claim 1, wherein the wavelength of said laser light is above about 900 nm.

3. The thermoplastic composition of claim 1, wherein said copper salt is copper phosphate or copper thiocyanate.

4. The thermoplastic composition of claim 1 wherein said thermoplastic resin comprises at least one resin selected from polycarbonate, polyester, rubber modified monovinylidene aromatics, polyetherimide, polyesteramides, polyamide, polyester carbonates, polyphenylene sulfide, polyamideimide, polyether esters, polyetherimide esters, polyarylate, polymethylpentene, polysulfone, polyethersulfone, polystyrene, rubber modified high impact polystyrene, acetyl, polyphenylene ether, polyether ketone, chlorinated polymer, fluorinated polymer, liquid crystal polymer, copolymers of the above, or blends of the above.

5. The thermoplastic composition of claim 4, wherein said thermoplastic resin comprises polyester, polycarbonate, polyestercarbonate, rubber modified monovinylidene aromatics, polyetherimides, polyesteramides, polyetherester, polyetherimide ester, or copolymers or blends of the above.

6. The thermoplastic composition of claim 5, wherein said thermoplastic resins comprises polycarbonate, polyalkylene terephthalate, rubber modified monovinylidene aromatics, or copolymers or blends of the above.

7. The thermoplastic composition of claim 2, wherein the amount of said copper salt ranges from about 0.05 to about 10 parts by weight of the thermoplastic composition.

8. The thermoplastic composition of claim 7, wherein the amount of said copper salt ranges from about 0.1 to about 5 parts by weight of the thermoplastic composition.

9. The thermoplastic composition of claim 1, wherein the amount of said copper salt ranges from about 0.5 to about 3 parts by weight of the thermoplastic composition.

10. The thermoplastic composition of claim 2, wherein the particle size of said copper salt is less than about 10 μ

m.

11. The thermoplastic composition of claim 10, wherein the particle size of said copper salt is less than about 1 μ

m.

12. The thermoplastic composition of claim 2, wherein the total color difference between the base composition and the portion which absorbed said laser light is at least 10 units as measured by the Delta E.

13. The thermoplastic composition of claim 12, wherein the total color difference between the base composition and the portion which absorbed said laser light is at least 15 units as measured by the Delta E.

14. The thermoplastic composition of claim 13, wherein the total color difference between the base composition and the portion which absorbed said laser light is at least 20 units as measured by the Delta E.

15. The thermoplastic composition of claim 2, wherein said composition further comprises carbon black or titanium dioxide.

16. A laser markable article of manufacture comprising the composition of claim 1.

17. A process for producing a laser markable thermoplastic composition comprising extruding the composition of claim 1.