Process for reconcentrating overspray from one-component coating compositions

• US 5,490,939 A
• Filed: 02/24/1995
• Issued: 02/13/1996
• Est. Priority Date: 03/03/1994
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Bruck, Jochen, Gerigk, Markus, Hovestadt, Wieland
• Primary Examiner(s): Fortuna, Ana M.
• Application Number:
  US08/393,646
• Time in Patent Office: 354 Days
• Field of Search: 210/650, 210/651, 210/652, 210/653, 210/654, 210/641, 134/38
• US Class Current: 210/652
• CPC Class Codes: B01D 2317/022 Reject series
• CPC Class Codes: B01D 2317/025 Permeate series
• CPC Class Codes: B01D 2317/08 Use of membrane modules of different kinds
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/026 comprising multiple reverse osmosis steps
• CPC Class Codes: B01D 61/027 Nanofiltration
• CPC Class Codes: B01D 61/029 Multistep processes comprising different kinds of membrane processes selected from reverse osmosis, hyperfiltration or nanofiltration
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B01D 61/58 Multistep processes
• CPC Class Codes: B05B 14/462 and separating the excess material from the washing liquid, e.g. for recovery
• CPC Class Codes: B05B 14/463 by means of ultrafiltration
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/442 by nanofiltration
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 2103/14 Paint wastes
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage
• CPC Class Codes: C08J 11/00 Recovery or working-up of waste materials recovery of plastics B29B17/00; polymerisation processes involving purification or recycling of waste polymers or their depolymerisation products C08B, C08C, C08F, C08G, C08H
• CPC Class Codes: Y02P 70/10 Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

The present invention relates to a multi-stage membrane filtration process for reconcentrating the overspray from a one-component, aqueous coating composition containing high molecular weight components having a weight average molecular weight of at least 2000 and at least 5% by weight, based on the total weight of the organic components of the coating composition, of a low molecular weight component having a weight average molecular weight of less than 2000, that has been diluted with spray booth water from spray booths having wet flushing to form a booth/water overspray mixture by

a) preconcentrating the booth water/overspray mixture in an ultrafiltration unit to obtain a first retentate containing high molecular weight components and a first permeant containing water and at least a portion of the low molecular weight components,

b) treating said first permeant and the third permeant obtained in step c) below in a reverse osmosis unit to obtain a second permeant containing essentially pure water for recycle as booth water and a retentate containing low molecular weight components,

c) treating said first and second retentates in a nanofiltration unit to obtain a third permeant containing water and a minor portion of low molecular weight components and a third retentate which largely corresponds in composition and concentration to said one-component, aqueous coating composition.

Claims

1. A multi-stage membrane filtration process for reconcentrating overspray from a one-component aqueous coating composition containing high molecular weight components having a weight average molecular weight of at least 2000, and at least 5 % by weight of a low molecular weight component having a weight average molecular weight of less than 2000, based on the total weight of organic components of the coating composition, said overspray having been dilutated with spray booth water from spray booths having wet flushing, to form a booth/water overspray mixture, said process comprising

a) preconcentrating the booth water/overspray mixture in an ultrafiltration unit to obtain a first retentate containing high molecular weight components and a first permeant containing water and at least a portion of the low molecular weight components,

b) treating said first permeant in a reverse osmosis unit to obtain a second permeant containing essentially pure water for recycled as booth water and a second retentate containing low molecular weight components,

c) treating said first and second retentate in a nanofiltration unit to obtain a third permeant containing water and a minor portion of low molecular weight components and a third retentate which largely corresponds in composition and concentration to said one-component aqueous coating composition, and

d) recycling said third permeant to the reverse osmosis unit for treatment in accordance with step b).

2. The process of claim 1 which comprises maintaining a differential pressure of 1 to 10 bar in the ultrafiltration unit, and maintaining a different pressure of 12 to 40 bar in the nanofiltration unit.

3. The process of claim 1 which comprises introducing said booth water/overspray mixture into a first intermediate tank before it is preconcentrated in accordance with step a).

4. The process of claim 1 which comprises introducing said second permeant into a second intermediate tank before it is recycled as boot water.

5. The process of claim 1 which comprises introducing said first and third retentates (4) and (7) into a third intermediate tank (14) before they are treated in accordance with step c).

6. The process of claim 1 which comprises introducing said third permeant into a fourth intermediate tank before it is treated together with said first permeant in accordance with step b).