Gas spectroscopy

• US 5,491,341 A
• Filed: 04/15/1994
• Issued: 02/13/1996
• Est. Priority Date: 04/16/1993
• Status: Expired due to Term

• Current Assignee: Bruce W. Mccaul
• Original Assignee: Bruce W. Mccaul
• Inventors: Thorson, Eric K., Doggett, David E., McCaul, Bruce W.
• Primary Examiner(s): Willis, David L.
• Assistant Examiner(s): HANIG, RICHARD E
• Application Number:
  US08/228,964
• Time in Patent Office: 669 Days
• Field of Search: 250/343, 250/340, 250/341.1, 250/341.5, 250/352, 356/319
• US Class Current: 250/343
• CPC Class Codes: G01N 2021/399 Diode laser
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/39 using tunable lasers
• CPC Class Codes: G02B 6/4207 with optical elements reducing the sensitivity to optical feedback anti-reflection devices specially adapted for lasers, see H01S3/0064
• CPC Class Codes: G02B 6/4209 Optical features
• CPC Class Codes: G02B 6/4246 Bidirectionally operating package structures
• CPC Class Codes: H01S 5/0064 Anti-reflection components, e.g. optical isolators
• CPC Class Codes: H01S 5/06216 Pulse modulation or generation

Abstract

A spectroscopy device comprises a laser diode/lens assembly driven by a periodic stepped laser diode drive current. Each period of the stepped laser diode drive current has a plurality of constant current intervals: a left baseline interval, a left skirt interval, a peak interval, a right skirt interval, and a right baseline interval. The left and right skirt constant current intervals are used to lock the laser radiation emitted during the peak interval onto a preselected absorption line. The left and right skirt intervals are also used to obtain a value indicative of line width. The peak interval is used to obtain a value indicative of peak absorbance. Multiplying the peak and line width values together yields a value indicative of a gas concentration which is substantially independent of foreign gas line-broadening effects.

Claims

1. A method, comprising:

generating laser radiation with a laser diode and passing said laser radiation through a sample gas;

obtaining a first value indicative of a peak absorption of said laser radiation by said sample gas substantially at a peak of an absorption line of said sample gas;

obtaining a second value indicative of a line width of said absorption line; and

using said values indicative of said peak absorption and said line width to determine a third value indicative of a number of molecules of said sample gas through which said laser radiation passes, said third value being substantially independent of line-broadening effects,

wherein said generating comprises supplying said laser diode with a driving current, said driving current having a periodic waveform comprising a plurality of constant current intervals, a first, a second and a third of said constant current intervals causing said laser diode to emit laser radiation at first, second and third wavelengths respectively, said first wavelength being smaller than said second wavelength, said third wavelength being greater than said second wavelength, said second wavelength corresponding with the peak of said absorption line, the first and third wavelengths corresponding with locations on said absorption line having substantially identical absorptions.

2. The method of claim 1, wherein a difference between said driving currents in said first and third constant current intervals is said second value, said line-broadening effects including foreign gas line-broadening effects.

3. The method of claim 1, wherein the magnitude of said substantially identical absorptions during said first and third constant current intervals is approximately half the magnitude of said absorption during said second constant current interval, said line-broadening effects including foreign gas line-broadening effects.

4. The method of claim 1, wherein said absorption line is an absorption line of oxygen, said line-broadening effects including foreign gas line-broadening effects.

5. The method of claim 4, wherein at least some of said line-broadening effects are due to anesthetic gasses in said sample gas affecting said absorption line of oxygen.

6. The method of claim 1, further comprising:

detecting a temperature of said sample gas and using said detected temperature to correct for line-broadening effects due to temperature.

7. The method of claim 1, further comprising:

detecting a pressure of said sample gas and using said detected pressure to correct for line-broadening effects due to pressure.

8. The method of claim 1, further comprising:

detecting a pressure and a temperature of said sample gas and using said detected pressure and temperature to correct for line-broadening effects due to pressure and temperature.

9. The method of claim 1, further comprising:

obtaining a first value indicative of a peak absorption of a calibration gas and obtaining a second value indicative of a line width of said calibration gas; and

using said first and second values obtained from said calibration gas in determining third values, said third values being indicative of numbers of molecules of sample gases through which said laser radiation passes, said third values being substantially independent of foreign gas line-broadening effects on said sample gases.

10. A spectroscopy device, comprising:

a laser diode emitting laser radiation, said laser radiation having only a first wavelength during a first time period, only a second wavelength during a second time period, and only a third wavelength during a third time period, said second wavelength being greater than said first wavelength but smaller than said third wavelength;

a radiation detector operatively disposed to receive a portion of said laser radiation after said portion of said laser radiation has passed through a sample gas, said sample gas comprising at least a first gas and a second gas, said second wavelength being the wavelength of a peak of an absorption line of said first gas; and

means for determining a value indicative of a concentration of said first gas, said value being substantially independent of line-broadening effects on said first gas due to said second gas.

11. The spectroscopy device of claim 10, further comprising a pressure sensor coupled to said means for determining.

12. The spectroscopy device of claim 11, wherein said means for determining comprises a microcontroller, said microcontroller also correcting for line-broadening effects on said absorption line of said first gas due to pressure.

13. The spectroscopy device of claim 10, further comprising a temperature sensor coupled to said means for determining.

14. The spectroscopy device of claim 11, wherein said means for determining comprises a microcontroller, said microcontroller also correcting for line-broadening effects on said absorption line of said first gas due to temperature.

15. The spectroscopy device of claim 10, wherein said means for determining multiplies a value indicative of a line width of said absorption line of said first gas with a value indicative of a peak absorption of said absorption line of said first gas.

16. A method, comprising:

transmitting laser diode laser radiation through a mixture of a first gas and a second gas, said laser radiation having only a first wavelength during a first time period, only a second wavelength during a second time period, and only a third wavelength during a third time period, said second wavelength being greater than said first wavelength but smaller than said third wavelength;

centering the second wavelength on the peak of an absorption line of said first gas by using absorption information obtained during said first and third time periods to indicate left and right skirts of said absorption line, absorption of said laser radiation during said first time period being substantially equal to absorption of said laser radiation during said third time period; and

determining a concentration of said first gas by measuring absorption of said laser radiation during said second time period and using line width information obtained during said first and third time periods to correct for foreign gas line-broadening effects on said first gas due to said second gas.