Building material coating

• US 5,492,772 A
• Filed: 02/13/1995
• Issued: 02/20/1996
• Est. Priority Date: 04/05/1993
• Status: Expired due to Term

• Current Assignee: Revere Copper Products, Inc.
• Original Assignee: The Louis Berkman Company
• Inventors: Zamanzadeh, Mehrooz, Carey, Jay F. II
• Primary Examiner(s): ZIMMERMAN, JOHN J
• Application Number:
  US08/394,233
• Time in Patent Office: 372 Days
• Field of Search: 428/659, 428/658, 428/935, 428/939, 428/646-648, 428/650, 428/674, 428/685, 427/433, 148/242
• US Class Current: 428/648
• CPC Class Codes: C22C 1/11 Making amorphous alloys
• CPC Class Codes: C23C 2/024 by cleaning or etching
• CPC Class Codes: C23C 2/08 Tin or alloys based thereon
• CPC Class Codes: C23C 30/00 Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process C23C26/00, C23C28/00 take precedence
• CPC Class Codes: E04D 3/30 of metal
• CPC Class Codes: E04F 13/12 of metal or with an outer layer of metal or enameled metal E04F13/0864 takes precedence
• CPC Class Codes: Y10S 428/939 Molten or fused coating
• CPC Class Codes: Y10T 428/12715 Next to Group IB metal-base component
• CPC Class Codes: Y10T 428/12722 Next to Group VIII metal-base component
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/12799 Next to Fe-base component [e.g., galvanized]

Abstract

A corrosion-resistant colored architectural material which is essentially lead free and is not highly reflective. The coating on the material is a two-phase metallic coating comprised of a large weight percentage of zinc and a relatively large weight percentage of tin. The tin-zinc coating may also include nickel. The tin-zinc composition provides for both a highly corrosive-resistant coating which protects the surface of the architectural material from oxidation and also produces a gray, earth tone colored which is not highly reflective.

Claims

1. A coated metal material coated with a highly corrosive-resistant, two-phase tin-zinc alloy by immersing said metal material in a molten bath of said tin-zinc alloy to deposit an impervious layer of said tin-zinc alloy onto said metal material, said tin-zinc coating comprising tin, at least 30 weight percent zinc, nickel an effective amount of metal stabilizer of a metal selected from the group consisting of antimony, bismuth, copper and mixtures thereof.

2. A coated metal material as defined in claim 1, wherein said metal material is a metal strip supplied from a roll of strip and said strip having a thickness of less than 0.10 inch.

3. A coated metal material as defined in claim 2, wherein said metal strip is continuously passed through said molten alloy bath to deposit a coating alloy having a thickness of 0.0003-0.05 inch.

4. A coated metal material as defined in claim 1, wherein said alloy includes at least 0.3 weight percent nickel.

5. A coated metal material as defined in claim 1, wherein said alloy includes at least 15 weight percent tin.

6. A coated metal strip formed of a metal having a thickness of less than about 0.1 inch and continuously supplied from a coil of said metal strip and coated with a highly corrosive resistant, two-phase tin-zinc alloy by continuously passing said metal strip through a molten bath of said tin-zinc coating alloy to form a coating alloy having a thickness of 0.0003-0.05 inch, said tin-zinc coating alloy including at least 0.1 weight percent copper, at least 15 weight percent tin wherein said tin content plus the zinc content exceeds 80 weight percent of said coating alloy.

7. A coated metal material as defined in claim 6, wherein said alloy includes at least 30 weight percent zinc.

8. The metal strip as defined in claim 6, wherein said coating alloy includes a metal selected from the group consisting of antimony, bismuth, nickel and mixtures thereof.

9. A coated metal strip formed of a given metal, said metal strip having a thickness of less than about 0.10 inch and exposed surfaces supplied from a coil of said metal strip and coated with a highly corrosive-resistant two-phase tin and zinc alloy by continuously passing said continuous metal strip through a heated molten bath of said coating alloy to deposit an uninterrupted layer of said coating alloy having a thickness in the range of 0.0001 to 0.050 inch onto the exposed surfaces of said moving strip by a continuous hot dip procedure, said coating alloy including at least 15 percent by weight tin, at least about 30 weight percent zinc and a metal additive selected from the group consisting of antimony, bismuth, copper, iron, lead, nickel and mixtures thereof wherein the lead content of said metal additive is less than 0.05 weight percent, said zinc plus said tin comprising at least 80 weight percent of said coating alloy, said metal additive including an effective amount of copper as a coloring agent.

10. A coated metal strip as defined in claim 9, wherein any one of the metals of said metal additive is not more than 5.0 weight percent.

11. A coated metal strip as defined in claim 10, wherein any one of the metals of said metal additive is not more than 2.0 weight percent.

12. A coated metal strip as defined in claim 9, wherein said zinc plus said tin content is at least 90 weight percent.

13. A coated metal strip as defined in claim 9, wherein said metal additive includes at least 0.3 weight percent nickel.

14. A coated metal strip as defined in claim 9, wherein said metal additive includes at least 0.1 weight percent copper.

15. A coated metal strip as defined in claim 9, including a metal layer interposed between said strip surface and said coating alloy.

16. A coated metal strip as defined in claim 15, wherein said metal layer is up to 3 microns thick.

17. A coated metal strip as defined in claim 15, wherein said metal layer is nickel.

18. A coated metal strip as defined in claim 9, wherein said given metal is stainless steel.

19. A coated metal strip as defined in claim 9, wherein said metal additive includes at least 0.05 weight percent metallic stabilizer.

20. A coated metal strip as defined in claim 19, wherein said metallic stabilizer is selected from the group consisting of antimony, bismuth and mixtures thereof.

21. A coated metal strip as defined in claim 9, wherein said metal strip is immersed in said molten bath for a residence time of 0.166-10 minutes.

22. A coated metal strip as defined in claim 21, wherein said residence time is less than one minute.

23. A coated metal strip formed of a strip selected from the group consisting of carbon steel, stainless steel, copper, aluminum and bronze, said strip having a thickness 0.005-0.1 inch and supplied for a coil and coating said strip by continuously passing said strip in a longitudinal direction through a molten bath of metal alloy having a temperature of at least 449°

F. such that the residence time of said plated strip in said molten bath is 0.166-10 minutes to deposit an impervious layer of a two-phase tin-zinc coating alloy on the surface of said strip, said coating alloy having generally uniform thickness of 0.0001-0.05 inch along the length of said strip and including at least 15 weight percent tin, at least about 30 weight percent zinc and a metal additive, said zinc content plus tin content being at least 90 weight percent of said coating alloy, said metal additive selected from the group consisting of a corrosion additive, a color additive, a metal stabilizing additive, and mixtures thereof, said corrosion additive is an effective amount of nickel, said color additive is an effective amount of copper, and said metal stabilizing additive an effective amount of a metal selected from the group consisting of antimony, bismuth, and mixtures thereof.

24. A coated metal material as defined in claim 23, wherein said zinc content plus said tin content being at least 95 weight percent of said coating alloy.

25. A coated metal material as defined in claim 24, wherein an intermediate metal layer is applied to said metal strip prior to continuously passing said strip through said molten bath.

26. A coated metal material as defined in claim 25, wherein said metal additive includes less than 0.05 weight percent lead.

27. A coated metal material as defined in claim 26, wherein said metal additive includes an effective amount of metallic stabilizer.

28. A coated metal material as defined in claim 24, wherein said metal additive includes less than 0.05 weight percent lead.

29. A coated metal material as defined in claim 28, wherein said metal additive includes an effective amount of metallic stabilizer.

30. A coated metal material as defined in claim 24, wherein said metal additive includes an effective amount of metallic stabilizer.

31. A coated metal material as defined in claim 23, wherein an intermediate metal layer is applied to said metal strip prior to continuously passing said strip through said molten bath.

32. A coated metal material as defined in claim 31, wherein said metal additive includes less than 0.05 weight percent lead.

33. A coated metal material as defined in claim 32, wherein said metal additive includes an effective amount of metallic stabilizer.

34. A coated metal material as defined in claim 23, wherein said metal additive includes less than 0.05 weight percent lead.

35. A coated metal material as defined in claim 34, wherein said metal additive includes an effective amount of metallic stabilizer.

36. A coated metal material as defined in claim 23, wherein said metal additive includes an effective amount of metallic stabilizer.