Transparent panel heater

• US 5,493,102 A
• Filed: 01/27/1994
• Issued: 02/20/1996
• Est. Priority Date: 01/27/1993
• Status: Expired due to Fees

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Original Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Inventors: Fukuda, Nobuhiro, Dodo, Toshihiro, Takase, Mitsuo
• Primary Examiner(s): Lateef, Marvin M.
• Assistant Examiner(s): PAIK, SANG YEOP
• Application Number:
  US08/186,922
• Time in Patent Office: 754 Days
• Field of Search: 219/538, 219/546, 219/547, 219/203, 219/522
• US Class Current: 219/547
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10018 comprising only one glass sheet
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B60S 1/026 using electrical means
• CPC Class Codes: H05B 2203/013 Heaters using resistive films or coatings
• CPC Class Codes: H05B 3/86 the heating conductors being embedded in the transparent or reflecting material H05B3/845 takes precedence
• CPC Class Codes: Y10T 428/31529 Next to metal
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Abstract

A transparent panel heater which can be used for heating a window portion of liquid crystal displays, refrigerated showcases, freezed showcases, defrosters of windshields, and the like. The panel heater has a transparent substrate, a transparent conductive film formed on the substrate, a substantially light-transmittable metallic electrode-underling-layer formed on the transparent conductive film and a pair of metallic electrodes which are provided for electrifying the conductive film and formed on the electrode-underlying-layer. The transparent conductive film is a laminate of at least one transparent thin layer made of a nitride and/or a carbide and at least one substantially light-transmittable metallic layer. The transparent conductive film and electrode-underlying-layer are preferably formed by a dry process, and the electrodes are preferably formed by a wet plating method.

Claims

1. A transparent panel heater having a transparent conductive film which is formed on a transparent substrate and which can be used as a heating surface, and a pair of metallic electrodes deposited by a wet plating process using an acidic solution for electrifying the transparent conductive film;

said transparent panel heater comprising;

an acid-resistant transparent protective film formed on the transparent conductive film and a light-transmittable metallic electrode-underlying-layer formed on the transparent protective film, said metallic electrodes being formed on said electrode-underlying-layer by a wet plating process in an acidic solution.

3. The transparent panel heater according to claim 1 which further comprises a first transparent resin protective layer for covering a portion of the electrode-underlying-layer on which the metallic electrodes are not formed, thereby defining places where the metallic electrodes are formed by the wet plating process.

4. The transparent panel heater according to claim 3 which further has a second transparent resin protective layer for covering the metallic electrodes and the first transparent resin protective layer.

2. A transparent panel heater having a transparent conductive film which is formed on a transparent substrate and which can be used as a heating surface, and a pair of metallic electrodes deposited by a wet plating process using an acidic solution for electrifying the transparent conductive film;

said transparent panel heater comprising;

a light-transmittable metallic electrode-underlying-layer formed on the transparent conductive film, said transparent conductive film being a laminate of at least one transparent thin layer made of at least one of a nitride or a carbide and at least one light-transmittable metallic layer, said metallic electrodes being formed on the electrode-underlying-layer by a wet plating process in an acidic solution.

5. The transparent panel heater according to claim 2 which further comprises a first transparent resin protective layer for covering a portion of the electrode-underlying-layer on which the metallic electrodes are not formed, thereby defining places where the metallic electrodes are formed by the wet plating process.

6. The transparent panel heater according to claim 5 which further comprises a second transparent resin protective layer for covering the metallic electrodes and the first transparent resin protective layer.

7. The transparent panel heater according to claim 2 wherein said transparent thin layer is a transparent thin film having a high refractive index which comprises at least one selected from the group consisting of aluminum nitride, indium nitride, gallium nitride, silicon nitride, tin nitride, boron nitride, silicon carbide, amorphous carbon and diamond-like carbon.

8. The transparent panel heater according to claim 2 wherein a material constituting the transparent thin layer is partially oxidized.

9. The transparent panel heater according to claim 2 wherein a material constituting the transparent thin layer is partially hydrogenated.

10. The transparent panel heater according to claim 2 wherein said electrode-underlying-layer comprises at least one metal selected from the group consisting of copper, nickel, chromium, palladium, lead, platinum, gold and silver, or an alloy thereof.

11. The transparent panel heater according to claim 2 wherein said metallic electrodes comprise a single layer or a laminate of at least one metal selected from the group consisting of copper, nickel, chromium, gold, tin, lead, silver and solder, or an alloy thereof.

12. The transparent panel heater according to claim 2 wherein said electrode-underlying-layer is a metallic thin film having a thickness of 0.5 nm to 20 nm formed on the transparent conductive film by a dry process.

13. The transparent panel heater according to claim 2 wherein said metallic layer contains silver as a main component.

14. The transparent panel heater according to claim 2 wherein said metallic layer is a laminate of a thin layer containing silver as a main component and another thin layer containing a metal other than silver as a main component.

15. The transparent panel heater according to claim 2 wherein a transparent intermediate layer is interposed between the transparent thin layer and the electrode-underlying-layer.

16. The transparent panel heater according to claim 2 wherein an adhesive layer is formed on the transparent substrate.

17. The transparent panel heater according to claim 6 wherein an adhesive layer is formed on the second transparent resin protective layer.