Desiccant-coated substrate and method of manufacture

• US 5,496,397 A
• Filed: 12/07/1994
• Issued: 03/05/1996
• Est. Priority Date: 01/06/1993
• Status: Expired due to Term

• Current Assignee: Semco LLC
• Original Assignee: Semco LLC
• Inventors: Mescher, Kirk T., Fischer, John C.
• Primary Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US08/350,653
• Time in Patent Office: 454 Days
• Field of Search: 502/401, 502/405, 502/407, 96/125, 96/150, 96/154, 95/117, 95/90
• US Class Current: 96/154
• CPC Class Codes: B01D 53/261 by adsorption
• CPC Class Codes: B01D 53/28 Selection of materials for use as drying agents
• CPC Class Codes: B01J 20/2803 Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
• CPC Class Codes: B01J 20/28045 Honeycomb or cellular structures; Solid foams or sponges
• CPC Class Codes: F24F 2203/1036 Details
• CPC Class Codes: F24F 3/1423 with a moving bed of solid desiccants, e.g. a rotary wheel supporting solid desiccants
• CPC Class Codes: Y10S 95/902 Molecular sieve

Abstract

Desiccant-coated substrates, regeneratable rotary dehumidification wheels and other devices for gas (e.g., air) treatment using those substrates, and processes for making them are disclosed. The substrates may have coatings in thicknesses of from about 2 to about 10 mils containing particles of one or more adsorbent desiccants and an organic water-based binder. The desiccant particles retain a high fraction of their original adsorption capacity because the pores of the desiccant particles contain a pore-clearing agent prior to the binder setting and the pore-clearing agent leaves the pores during the manufacturing process to prevent the binder from blocking the pores. In preferred embodiments a mixture of different desiccants is used and a particle suspending agent keeps the particles well-mixed so that the desiccant particles in the coated substrate will be as well-mixed as possible. The suspending agent may also function as the pore-clearing agent. A pH-adjusting agent may be used to control the pH of the coating if the binder or another constituent of the coating is pH-sensitive.

Claims

1. A process for making a device for gas treatment comprising a desiccant-coated substrate capable of being used at temperatures over 150 degrees Fahrenheit, the device having passageways for gas to flow through and contact the desiccant, the desiccant being in the form of particles and the particles having pores and being adhered to the substrate by a binder, the coated substrate being sufficiently flexible and the coating having sufficient adherence to the substrate so that the coated substrate can be formed into corrugated shapes, the desiccant particles in the coated substrate having at least 60% of their original adsorption capacity and the binder having good breathability;

said process comprising the steps;

(a) forming an aqueous suspension comprising particles of one or more desiccants, a water-based organic binder, a suspending agent to help maintain the desiccant particles in suspension, and an organic pore-clearing agent at least some of which enters at least some of the pores of the desiccant particles;

(b) depositing the suspension on the substrate;

(c) causing the binder of the deposited suspension to set so that the deposited desiccant particles adhere to the substrate and causing at least some of the pore-clearing agent to leave the pores of the desiccant particles to prevent the binder from occluding at least some of the pores of the adhered desiccant particles, thereby to form a desiccant-coated substrate of sufficient flexibility and a coating having sufficient adherence to the substrate so that the desiccant-coated substrate can be formed into corrugated shapes and in which the desiccant particles in the coated substrate have at least 60% of their original adsorption capacity and the binder has good breathability; and

(d) forming the desiccant-coated substrate into shapes having passageways for the flow of gas arranged so that gas flowing through the passageways comes into contact with the desiccant.

2. The process of claim 1 wherein the suspending agent is also the pore-clearing agent.

3. The process of claim 1 wherein the suspending agent is also the pore-clearing agent and is N-methyl-2-pyrrolidone.

4. The process of claim 1 wherein the binder is a polyurethane binder.

5. The process of claim 1 wherein the adhered desiccant coating on the substrate is at least 2 mils thick.

6. The process of claim 1 wherein the adhered desiccant coating on the substrate is at least 3 mils thick.

7. The process of claim 1 wherein the one or more desiccants are selected from the group consisting of molecular sieves and silica gels.

8. The process of claim 1 wherein the one or more desiccants comprise at least two desiccants.

9. The process of claim 1 wherein step (a) comprises forming an aqueous suspension comprising the particles of one or more desiccants, a suspending agent to help maintain the desiccant particles in suspension, and an organic pore-clearing agent at least some of which enters at least some of the pores of the desiccant particles and thereafter adding to the suspension a water-based organic binder.

10. The process of claim 1 wherein step (a) comprises forming an aqueous suspension comprising the particles of at least two desiccants;

a suspending agent to help maintain the desiccant particles in suspension;

a pH-adjusting agent to adjust the pH; and

an organic pore-clearing agent at least some of which enters at least some of the pores of the desiccant particles; and

thereafter adding to the suspension a water-based organic binder.

11. The process of claim 10 wherein the pH-adjusting agent is ammonium hydroxide.

12. The process of claim 1 wherein step (b) comprises using a double helically wound rod to deposit suspension on the substrate.

13. The process of claim 1 wherein step (c) comprises heating the suspension deposited on the substrate to cause the binder to set and to cause at least some of the pore-clearing agent to leave the pores of the desiccant particles to prevent the binder from occluding at least some of the pores of the adhered desiccant particles.

14. The process of claim 1 wherein the substrate has two major faces and steps (b) and (c) are carried out for each major face of the substrate, thereby adhering a desiccant coating to each face.

15. The process of claim 1 wherein step (c) comprises causing the pore-clearing agent to leave the pores of the desiccant particles to prevent the binder from occluding pores of the adhered desiccant particles so that the desiccant particles in the coated substrate have at least 75% of their original adsorption capacity.

16. The process of claim 1 wherein step (c) comprises causing the pore-clearing agent no leave the pores of the desiccant particles to prevent the binder from occluding pores of the adhered desiccant particles so that the desiccant particles in the coated substrate have at least 90% of their original adsorption capacity.

17. The process of claim 1 further comprising preloading the particles of desiccant with water before step (a) so that the water in the particles will be approximately in equilibrium with respect to water in the suspension.

18. The process of claim 1 wherein step (a) comprises forming an aqueous mixture of some of the particles of the one or more desiccants, thereafter adding the suspending agent and the organic pore-clearing agent, thereafter adding more of the particles of the one or more desiccants, and thereafter adding the water-based organic binder.

34. The process of claim 1 wherein the shapes formed in step (d) are corrugated shapes and they result from a corrugation process using corrugation gears having pressure angles of from about 7 to about 60 degrees.

35. The process of claim 1 wherein the shapes formed in step (d) are corrugated shapes and they have a bend angle measured at the interior of the apex of the bend of at least about 14 degrees.

36. The process of claim 1 wherein the shapes formed in step (d) are corrugated shapes and they have hydraulic diameters of at least 0.5 millimeters.

19. A device for gas treatment comprising a desiccant-coated substrate capable of being used at temperatures over 150 degrees Fahrenheit, the device having passageways for gas to flow through and contact the desiccant, the desiccant being in the form of particles and the particles having pores, the desiccant-coated substrate comprising a coating layer and a substrate, the coating layer being from about 2 mils to about 10 mils thick and comprising a water-based organic binder and at least 75% by weight desiccant, the coated substrate being sufficiently flexible and the coating layer having sufficient adherence to the substrate so that the coated substrate can be formed into corrugated shapes, the desiccant particles in the coated substrate having at least 75% of their original adsorption capacity and the binder having good breathability.

20. The device for gas treatment of claim 19 wherein the desiccant particles in the coated substrate have at least 90% of their original adsorption capacity.

21. The device for gas treatment of claim 20 wherein the desiccant comprises at least 85% by weight Of the coating layer.

22. The device for gas treatment of claim 19 wherein the coating layer is from about 3 mils to 8 mils thick.

23. The device for gas treatment of claim 22 wherein the desiccant comprises at least 85% by weight of the coating layer.

24. The device for gas treatment of claim 23 wherein the desiccant particles in the coated substrate have at least 90% of their original adsorption capacity.

25. The device for gas treatment of claim 19 wherein the binder is polyurethane.

26. The device for gas treatment of claim 25 wherein the desiccant comprises at least 85% by weight of the coating layer.

27. The device for gas treatment of claim 26 wherein the desiccant particles in the coated substrate have at least 90% of their original adsorption capacity.

28. The device for gas treatment of claim 19 wherein it is capable of being used at temperatures over 200 degrees Fahrenheit.

29. The device for gas treatment of claim 28 which is a dehumidification wheel.

30. The device for gas treatment of claim 19 which is a dehumidification wheel.

31. The device for gas treatment of claim 20 which is a dehumidification wheel.

32. The device for gas treatment of claim 19 in which the desiccant is hydrophobic.

33. The device for gas treatment of claim 19 in which the gas is air.

37. The device for gas treatment of claim 19 wherein the passageways are formed by corrugated shapes resulting from a corrugation process using corrugation gears having pressure angles of from about 7 to about 60 degrees.

38. The device for gas treatment of claim 19 wherein the passageways are formed by corrugated shapes having a bend angle measured at the interior of the apex of the bend of at least about 14 degrees.

39. The device for gas treatment of claim 19 wherein the passageways are formed by corrugated shapes having hydraulic diameters of at least 0.5 millimeters.