Antibacterial fiber, textile and water-treating element using the fiber and method of producing the same

• US 5,496,860 A
• Filed: 12/28/1993
• Issued: 03/05/1996
• Est. Priority Date: 12/28/1992
• Status: Expired due to Fees

• Current Assignee: Nitivy Co., Ltd. (Katakura Industries Company Limited), Suntory Ltd (Kotobuki Realty Co., Ltd.), Takuma Company Limited
• Original Assignee: Nitivy Co., Ltd. (Katakura Industries Company Limited), Suntory Ltd (Kotobuki Realty Co., Ltd.), Takuma Company Limited
• Inventors: Horie, Hiroshi, Kawanaka, Asaichi, Matsumoto, Nobuya, Kunisaki, Shinichi, Masuda, Mitsunobu, Fujiwara, Goro
• Primary Examiner(s): Lipman, Bernard
• Application Number:
  US08/174,368
• Time in Patent Office: 798 Days
• Field of Search: 521/31, 525/362, 525/370, 525/371
• US Class Current: 521/31
• CPC Class Codes: C08F 8/04 Reduction, e.g. hydrogenation
• CPC Class Codes: C08F 8/42 Introducing metal atoms or metal-containing groups
• CPC Class Codes: Y10T 428/1369 Fiber or fibers wound around each other or into a self-sustaining shape [e.g., yarn, braid, fibers shaped around a core, etc.]
• CPC Class Codes: Y10T 442/475 Including a free metal or alloy constituent
• CPC Class Codes: Y10T 442/648 Including a free metal or alloy constituent

Abstract

An antibacterial fiber includes an ion exchange fiber and an antibacterial metal ion entrapped within the ion exchange fiber through an ion exchange reaction. The invention also discloses antibacterial textiles and water-treating element using the fibers.

Claims

1. A method of producing an antibacterial fiber comprising the steps of:

bonding, through an ion exchange reaction, complex ion of silver, copper or zinc with ion exchange group of cation exchange fiber having sulfonic or carboxyl group as ion exchange group thereof; and

reducing the complex ion.

2. A method of producing an antibacterial fiber comprising the steps of:

bonding, through an ion exchange reaction, complex ion of silver, copper or zinc with ion exchange groups of an anion exchange fiber having primary through tertiary amine groups and quaternary ammonium group; and

reducing the complex ion.

3. A method of producing an antibacterial fiber containing at least silver ion, which comprises the steps of:

bonding, through an ion exchange reaction, a cation of more than one kind of alkali metals or alkaline earth metals selected from the group consisting of Na, K, Ca and Mg with entire ion exchange groups of a cation exchange fiber having sulphonic acid groups or carboxyl groups as ion exchange groups thereof; and

replacing a portion of said alkali metals or alkaline earth metals bonded to said ion exchange groups with said silver ion alone or with said silver ion and either copper ion or zinc ion in combination.

4. A method according to claim 3, wherein an amount of the exchange exchanged by said silver, copper and zinc ions is less than 50% of a total cation exchange capacity of said ion exchange fiber.

5. A method according to claim 3, wherein an amount of the exchange exchanged by said silver, copper and zinc ions is less than 20% of a total cation exchange capacity of said ion exchange fiber.