Process for production of styrene-based polymer moldings

• US 5,496,919 A
• Filed: 09/02/1993
• Issued: 03/05/1996
• Est. Priority Date: 01/13/1988
• Status: Expired due to Term

• Current Assignee: Idemitsu Kosan Company Limited
• Original Assignee: Idemitsu Kosan Company Limited
• Inventors: Nakano, Akikazu
• Primary Examiner(s): TESKIN, FRED M
• Application Number:
  US08/116,066
• Time in Patent Office: 915 Days
• Field of Search: 528/481, 528/503, 528/, 526/347.1, 526/347.2, 264/345, 264/346
• US Class Current: 528/481
• CPC Class Codes: B29C 71/02 Thermal after-treatment B29C71/0063 and B29C71/0072 take precedence
• CPC Class Codes: B29K 2025/00 Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material

Abstract

A process of producing a styrene polymer molding which comprises heat treating a molding of a crystalline styrene polymer having mainly a syndiotactic configuration and having a crystallinity of at least 10% as determined by X-ray diffraction analysis. The heat treating is carried out at a temperature of 150°to 250° C. for 20 seconds to 90 minutes.

Claims

1. A process for producing a styrene polymer molding which comprises heat treating a molding of a crystalline styrene polymer having mainly a syndiotactic configuration and having a crystallinity of more than 10% as determined by X-ray diffraction analysis, said heat treating being carried out at a temperature of 150°

to 250°

C. for a period of time of 20 seconds to 90 minutes.

2. The process as claimed in claim 1, wherein the heat treatment is carried out under an atmosphere of inert gas.

3. The process as claimed in claim 1, wherein said molding to be subjected to the heat treatment has a crystallinity of 12 to 55% as determined by X-ray diffraction analysis.

4. The process as claimed in claim 1, wherein said styrene polymer is a polystyrene homopolymer.

5. The process as claimed in claim 2, wherein said styrene polymer is a polystyrene homopolymer.

6. The process as claimed in claim 1, wherein said styrene polymer is a copolymer formed by polymerizing styrene and p-methylstyrene.

7. The process as claimed in claim 2, wherein said styrene polymer is a copolymer formed by polymerizing styrene and p-methylstyrene.

8. The process as claimed in claim 1, wherein said styrene polymer is selected from the group consisting of polystyrene, poly(alkylstyrene), poly(halogenated styrene), poly(alkoxystyrene) and polyvinyl benzoate and mixtures thereof.

9. The process as claimed in claim 2, wherein said styrene polymer is selected from the group consisting of polystyrene, poly(p-methylstyrene), poly(m-methylstyrene), poly(p-tert-butylstyrene), poly(p-chlorostyrene), poly(m-chlorostyrene), poly(p-fluorostyrene) and a copolymer of styrene and p-methylstyrene.

10. The process as claimed in claim 1, wherein said molding to be subjected to the heat treatment has a crystallinity of at least 12% as determined by X-ray diffraction analysis.

11. The process as claimed in claim 1, wherein said molding to be subjected to the heat treatment has a crystallinity of 13 to 50% as determined by X-ray diffraction analysis.

12. The process as claimed in claim 1, wherein said molding to be subjected to the heat treatment has a crystallinity of 13% as determined by X-ray diffraction analysis.

13. The process as claimed in claim 1, wherein said molding to be subjected to the heat treatment has a crystallinity of 15% as determined by X-ray diffraction analysis.

14. The process as claimed in claim 1, wherein said molding to be subjected to the heat treatment has a crystallinity of 16% as determined by X-ray diffraction analysis.