Phosphorescent and fluorescent marking composition

• US 5,498,280 A
• Filed: 11/14/1994
• Issued: 03/12/1996
• Est. Priority Date: 11/14/1994
• Status: Expired due to Term

• Current Assignee: Crayola LLC (Hallmark Cards Incorporated)
• Original Assignee: Binney & Smith Inc.
• Inventors: Fistner, David C., Snedeker, Colin M.
• Primary Examiner(s): Klemanski, Helene
• Application Number:
  US08/338,694
• Time in Patent Office: 484 Days
• Field of Search: 106/19 B, 106/21 R, 106/21 A
• US Class Current: 106/31.64
• CPC Class Codes: C09D 13/00 Pencil-leads; Crayon compositions; Chalk compositions
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/565 with zinc cadmium

Abstract

A phosphorescent and fluorescent marking composition, e.g., a crayon, comprising both high and low molecular weight polyethylene glycols in combination with phosphorescent and fluorescent pigments. The composition advantageously preferably further includes at least one filler, which preferably includes a water-miscible filler, a water-soluble surfactant, and a plasticizer.

Claims

1. A marking composition comprising

(a) a high molecular weight polyethylene glycol having a molecular weight of at least about 10,000;

(b) a low molecular weight polyethylene glycol having a molecular weight ranging from about 100 to about 1,000;

(c) a phosphorescent pigment; and

(d) a fluorescent pigment.

2. The marking composition of claim 1, wherein the ratio of high molecular weight polyethylene glycol to low molecular weight polyethylene glycol in the composition on a weight percent basis is from about 2:

1 to about 1;

1.

3. The marking composition according to claim 2, wherein the high molecular weight polyethylene glycol is present in an amount ranging from about 3 wt. % to about 30 wt. % and the low molecular weight polyethylene glycol is present in an amount ranging from about 2 wt. % to about 50 wt. %, all based upon the weight of the composition.

4. The marking composition according to claim 3, wherein the high molecular weight polyethylene glycol is present in an amount ranging from about 5 wt. % to about 10 wt. % and the low molecular weight polyethylene glycol is present in an amount ranging from about 3 wt. % to about 20 wt. %, all based upon the weight of the composition.

5. The marking composition of claim 1, wherein the high molecular weight polyethylene glycol has a molecular weight which ranges from about 17,000 to about 23,000.

6. The marking composition of claim 1, wherein the low molecular weight polyethylene glycol has a molecular weight which ranges from about 400 to about 800.

7. The marking composition of claim 1, wherein the total pigment in the composition is at least about 15 wt. %.

8. The marking composition of claim 1, wherein the phosphorescent pigment has an average diameter of about 11 microns to about 15 microns.

9. The marking composition of claim 8, wherein the phosphorescent pigment is present in the composition in an amount of from about 15 wt. % to about 25 wt. %.

10. The marking composition of claim 9, wherein the fluorescent pigment is present in the composition in an amount of from about 0.5 wt. % to about 2.0 wt. %.

11. The marking composition according to claim 1 further comprising a filler.

12. The marking composition of claim 11, wherein the filler is selected from the group consisting of clay, calcium carbonate, talc, mica, and mixtures thereof.

13. The marking composition of claim 12, wherein the filler is present in an amount of up to about 60% by weight.

14. The marking composition of claim 11, wherein the filler comprises a water-miscible filler.

15. The marking composition of claim 14, wherein the water-miscible filler is a stearyl alcohol.

16. The marking composition of claim 15, wherein the stearyl alcohol is present in the composition in an amount of from about 5 wt. % to about 40 wt. %.

17. The marking composition of claim 11 further comprising a surfactant.

18. The marking composition of claim 17, wherein the surfactant is selected from the group consisting of mono esters of polyols and fatty acids, diesters of polyols and fatty acids, nonionic block copolymers of propylene oxide and ethylene oxide, ethylene oxide condensation products, nonylphenol ethoxylates, ethyleneoxy ethanols, polyoxyethylene ether alcohol, and mixtures thereof.

19. The marking composition of claim 18, wherein the surfactant is selected from the group consisting of polyethylene glycol monostearate, polyethylene glycol distearate, glycerol monostearate, and mixtures thereof.

20. The marking composition of claim 19, wherein the surfactant is present in an amount of up to about 30% by weight.

21. The marking composition of claim 17 further comprising a plasticizer.

22. The marking composition of claim 21, wherein the plasticizer is oleyl alcohol.

23. The marking composition of claim 22, wherein the plasticizer is present in an amount of up to 10% by weight.

24. The marking composition of claim 1, wherein the composition comprises:

(a) from about 3 wt. % to about 30 wt. % of the high molecular weight polyethylene glycol;

(b) from about 2 wt. % to about 50 wt. % of the low molecular weight polyethylene glycol;

(c) from about 5 wt. % to about 50 wt. % of the phosphorescent pigment, wherein the phosphorescent pigment has an average particle size of about 11 microns to about 15 microns; and

(d) up to about 10 wt. % of the fluorescent pigment.

25. The marking composition of claim 24, wherein said composition further comprises:

(e) up to about 90 wt. % of a filler, wherein the filler comprises about 5 wt. % to about 40 wt. % of a water-miscible filler;

(f) up to about 30 wt. % of a surfactant, said surfactant being other than a liquid at room temperature; and

(g) up to about 10 wt. % of a plasticizer.

26. The marking composition of claim 25, wherein said composition comprises:

(a) from about 5 wt. % to about 10 wt. % of the high molecular weight polyethylene glycol, wherein the molecular weight of the high molecular weight polyethylene glycol ranges from about 17,000 to about 23,000;

(b) from about 3 wt. % to about 20 wt. % of the low molecular weight polyethylene glycol, wherein the molecular weight of the low molecular weight polyethylene glycol ranges from about 400 to about 800;

(c) from about 15 wt. % to about 25 wt. % of the phosphorescent pigment, wherein the phosphorescent pigment has a particle size of about 14 microns;

(d) from about 0.5 wt. % to about 2 wt. % of the fluorescent pigment;

(e) from about 25 wt. % to about 40 wt. % of the filler, wherein the filler comprises about 25 wt. % to about 35 wt. % of a water-miscible filler;

(f) from about 10 wt. % to about 20 wt. % of the surfactant; and

(g) from about 2.5 wt. % to about 7.5 wt. % of the plasticizer.

27. The marking composition of claim 26, wherein said filler is talc, said water-miscible filler is stearyl alcohol, said surfactant is polyethylene glycol distearate, and said plasticizer is oleyl alcohol.