Method for recharging flooded cell batteries

• US 5,499,234 A
• Filed: 04/26/1994
• Issued: 03/12/1996
• Est. Priority Date: 04/26/1994
• Status: Expired due to Fees

• Current Assignee: General Motors Corporation (General Motors Company)
• Original Assignee: General Motors Corporation (General Motors Company)
• Inventors: Rider, Robert A., Bendert, Richard M.
• Primary Examiner(s): Wong, Peter S.
• Assistant Examiner(s): TSO, EDWARD H
• Application Number:
  US08/233,795
• Time in Patent Office: 686 Days
• Field of Search: 320/4, 320/5, 320/21, 320/43, 320/46
• US Class Current: 320/132
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Maintenance free flooded electrolyte battery cycle life is extended by controlling charge acceptance and gassing during recharge. Charge acceptance is improved by periodically discharging the battery during a portion of the recharge which removes surface charge and reduces overall cell voltage. Gassing is purposefully introduced during periodic supply currents which are interspersed with the periodic discharges of the battery. The supply currents both restore energy to the battery and agitate the electrolyte sufficient to destratify same thereby reducing plate damage and charge gradients thereon. The method results in shorter charge times, full capacity recharges and extended cycle life resulting therefrom and from reductions in corrosive interactions of the electrolyte with the battery plates.

Claims

1. A method of improving cycle life of maintenance free flooded cell water-diluted electrolyte batteries comprising the steps of:

(a) during a bulk charge cycle,

charging the battery to substantially full capacity;

(b) during a charge restoral portion of a pulse charge/discharge cycle,

repetitively supplying a supply current to the battery for a supply duration at intervals interspersed with discharging a discharge current from the battery for a discharge duration, said supply current being apportioned between a gassing current effective to electrolyze water thereby evolving gas and a charge current effective to convert battery plate material thereby restoring charge, said supply duration apportioned between a charge duration wherein charge restoral dominates gas evolution and a gassing duration wherein gas evolution dominates charge restoral; and

,

controlling a combination of said supply current and said supply duration to contemporaneously yield a high charge restoral rate and a destratifying gas evolution rate.

2. A method of improving cycle life of maintenance free flooded cell water-diluted electrolyte batteries as claimed in claim 1 wherein:

said supply current is controlled substantially constant throughout said supply duration.

3. A method of improving cycle life of maintenance free flooded cell water-diluted electrolyte batteries as claimed in claim 1 wherein:

said supply current is controlled substantially to a first predetermined profile during said charge duration and to a second predetermined profile during said gassing duration.

4. A method of improving cycle life of maintenance free flooded cell water-diluted electrolyte batteries as claimed in claim 2 or 3 further comprising:

during a maintenance portion of said pulse charge/discharge cycle following said charge restoral portion thereof, controlling said supply current to a monotonically decreasing profile throughout said supply duration in accordance with a predetermined battery voltage lid.

5. A method of improving cycle life of maintenance free flooded cell water-diluted electrolyte batteries comprising the steps of:

(a) during a bulk charge cycle,

charging the battery to substantially full capacity by supplying the battery with a substantially constant current until a predetermined battery voltage lid is attained;

(b) during a charge restoral portion of a pulse charge/discharge cycle,

repetitively supplying a supply current to the battery in accordance with a predetermined profile for a predetermined supply duration at intervals interspersed with discharging a predetermined discharge current from the battery for a predetermined discharge duration, said supply current being apportioned between a gassing current effective to electrolyze water thereby evolving gas and a charge current effective to convert battery plate material thereby restoring charge, said supply duration apportioned between a charge duration wherein charge restoral dominates gas evolution and a gassing duration wherein gas evolution dominates charge restoral; and

,

wherein said predetermined profile and supply duration control the battery to a high charge acceptance rate and a destratifying gas evolution rate.