Fabric softening bar compositions containing fabric softener and enduring perfume

• US 5,500,137 A
• Filed: 10/20/1994
• Issued: 03/19/1996
• Est. Priority Date: 10/20/1994
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Trinh, Toan, Mermelstein, Robert, Hartman, Frederick A., Bacon, Dennis R.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/326,574
• Time in Patent Office: 516 Days
• Field of Search: 252/8.6, 252/8.7, 252/8.75, 252/8.8, 252/8.9
• US Class Current: 510/102
• CPC Class Codes: C11D 1/04 Carboxylic acids or salts thereof soap C11D9/00
• CPC Class Codes: C11D 1/40 Monoamines or polyamines; Salts thereof
• CPC Class Codes: C11D 1/44 Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
• CPC Class Codes: C11D 1/46 Esters of carboxylic acids with amino alcohols; Esters of amino carboxylic acids with alcohols
• CPC Class Codes: C11D 1/525 Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/662 Carbohydrates or derivatives
• CPC Class Codes: C11D 1/667 Neutral esters, e.g. sorbitan esters
• CPC Class Codes: C11D 1/75 Amino oxides
• CPC Class Codes: C11D 1/86 Mixtures of anionic, cationic, and non-ionic compounds
• CPC Class Codes: C11D 17/006 containing mainly surfactants, but no builders, e.g. syndet bar
• CPC Class Codes: C11D 3/001 Softening compositions
• CPC Class Codes: C11D 3/0026 Low foaming or foam regulating compositions
• CPC Class Codes: C11D 3/38645 containing cellulase
• CPC Class Codes: C11D 3/50 Perfumes

Abstract

The present invention relates to a fabric softening bar composition comprising: from about 40% to about 90% by weight of the composition of a hydrophobic fabric softening compound, from about 0.1% to about 10% of an enduring perfume composition, and optionally, but preferably, from about 5% to about 30% by weight of the composition of a nonionic surfactant, and from about 5% to about 30% by weight of the composition, water. These compositions are low sudsing, low lathering, non-detersive fabric softening compositions which provide long lasting perfume effects.

Claims

1. A low sudsing, fabric softening bar composition comprising:

(A) from about 40% to about 90%, by weight of the composition, of a hydrophobic, fabric softening compound selected from the group consisting of quaternary ammonium compounds, carboxylic acid salts of tertiary amines, carboxylic acid salts of tertiary ester amines, sorbitan esters of fatty alcohols, glycerol and polyglycerol esters, fatty amines, fatty acids, alkyl or alkenyl succinic acids, and mixtures thereof;

(B) from about 0.01% to about 10% of an enduring perfume composition;

(C) optionally, from about 5% to about 30%, by weight of the composition, of a nonionic surfactant;

(D) optionally, from about 5% to about 30%, by weight of the composition, water; and

;

(E) optionally, cellulase, at a level equivalent to an activity from about 1 to about 100 Cellulase Equivalent Viscosity Units/gram (CEVU/gram) of the composition;

wherein when (A) is a sorbitan ester of a fatty alcohol, glycerol ester, or a polyglycerol ester, then (C) cannot also be a sorbitan ester of a fatty alcohol, glycerol ester, or a polyglycerol ester, said composition being essentially free of detergent builders and anionic detergents.

2. The composition of claim 1 wherein said fabric softening compound is biodegradable and said nonionic surfactant is a solid with a melting point above about 25°

C.

3. The composition of claim 2 wherein the nonionic surfactant is a solid with a melting point above about 30°

C.

4. The composition of claim 2 wherein the enduring perfume has at least about 70% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

5. The composition of claim 2 wherein the enduring perfume has at least about 75% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

6. The composition of claim 2 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

7. The composition of claim 2 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

8. The composition of claim 1 wherein the enduring perfume has at least about 70% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

9. The composition of claim 1 wherein the enduring perfume has at least about 75% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

10. The composition of claim 1 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

11. The composition of claim 1 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

12. The composition of claim 1 wherein the level of said enduring perfume composition is from about 0.05% to about 5%.

13. The composition of claim 12 wherein the level of said enduring perfume composition is from about 0.1% to about 4%.

14. The composition of claim 13 wherein the level of said enduring perfume composition is from about 0.15% to about 3%.

15. The composition of claim 14 wherein the enduring perfume has a least about 75% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

16. The composition of claim 15 wherein the enduring perfume has a least about 85% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

17. The composition of claim 12 wherein the enduring perfume has a least about 75% of the total weight of components with a ClogP ≧

3.0 and a boiling point of ≧

250°

C.

18. The composition of claim 1 wherein the nonionic surfactant is selected from the group consisting of ethoxylated amines, ethoxylated alcohols, alkyl phenol ethoxylates, sorbitan esters of fatty alcohols, glycerol and polyglycerol esters, polyoxyethylene/polyoxypropylene block polymers;

polyoxyethylene/polyoxypropylene block polymers of ethylene diamine, polyhydroxy fatty acid amides, amine oxides, alkylpolysaccharides, and mixtures thereof.

19. The composition of claim 1 wherein the fabric softening compound is a carboxylic acid salt of a tertiary amine, a carboxylic acid salt of a tertiary ester amine, and mixtures thereof of the formula:

##STR12## wherein R⁵ is a long chain aliphatic group containing from about 8 to about 30 carbon atoms;

each R⁴ and R⁶ are selected from the group consisting of an aliphatic group containing from about 1 to about 30 carbon atoms, a hydroxyalkyl group of the formula;

R⁸ OH wherein R⁸ is an alkylene group of from about 2 to about 30 carbon atoms, an alkyl ether group of the formula;

R⁹ O(C_s H_2s O)_r wherein R⁹ is alkyl or alkenyl group having from about 1 to about 30 carbon atoms or a hydrogen atom, s is from 1 to 5, and r is from about 1 to about 30, and mixtures thereof;

wherein R⁴, R⁵, R⁶, R⁸, and R⁹ can be ester interrupted groups; and

wherein R⁷ is selected from the group consisting of unsubstituted alkyl, alkenyl, aryl, alkaryl and aralkyl groups having from about 8 to about 30 carbon atoms and substituted alkyl, alkenyl, aryl, alkaryl, and aralkyl groups having from about 1 to about 30 carbon atoms, wherein the substituents are selected from the group consisting of halogen, carboxyl, and hydroxyl group.

20. The composition of claim 19 wherein the carboxylic acid salt of a tertiary amine and the carboxylic acid salt of a tertiary ester amine has a carboxylic acid salt forming anion moiety and a starting amine salt moiety, wherein the carboxylic acid salt forming anion moiety is selected from the group consisting of lauric, myristic, palmitic, stearic, oleic acid, and mixtures thereof.

21. The composition of claim 20 wherein the carboxylic acid salt of a tertiary amine and ester amine is selected from the group consisting of oleyldimethylamine stearate, dioleylmethylamine stearate, linoleyldimethylamine stearate, dilinoleylmethylamine stearate, stearyldimethylamine stearate, distearylmethylamine myristate, stearyldimethylamine palmitate, distearylmethylamine palmitate, distearylmethylamine myristate, distearylmethylamine palmitate, distearylmethylamine laurate, dioleyldistearylmethylamine oleate, distearylmethylamine oleate, tallowyldimethylamine stearate, and mixtures thereof.

22. The composition of claim 1 wherein the fabric softening compound is a quaternary ammonium compound selected from the group consisting of:

space="preserve" listing-type="equation">(R).sub.4-m --N.sup.+ --[(CH.sub.2).sub.n --Y--R.sup.2 ].sub.m X.sup.-(I)

space="preserve" listing-type="equation">(R).sub.4-m --N.sup.+ --[R.sup.2 ].sub.m X.sup.- (IV)

and mixtures thereof and wherein;

each Y is --O--(O)C--, --C(O)--O--;

--NH--C(O)--;

--(O)C--NH--; and

mixtures thereof;

m is 1 to 3;

each n is 1 to 4;

each R substituent is H, a branched or straight chained C₁ -C₆ alkyl group, (C_y H_2y O)_w H where y is from 1 to 5, and w is from 1 to 5;

benzyl group, and mixtures thereof;

each R² is a long chain, saturated or unsaturated (Iodine Value of from about 3 to about

     60), C₈ -C₃₀ hydrocarbyl, or substituted hydrocarbyl substituent and mixtures thereof, and

the counterion, X^-, can be any softener-compatible anion.

23. The composition of claim 22 wherein:

each Y is --O--(O)C--, --C(O)--O--; and

mixtures thereof;

m is 2;

each n is 2;

each R substituent is a C₁ -C₃, alkyl group;

each R² is a saturated C₁₂ -C₁₈ alkyl group.

24. The composition of claim 1 wherein said enduring perfume composition contains at least 70% of materials selected from the group consisting of:

Allyl cyclohexane propionate;

Ambrettolide;

Amyl benzoate;

Amyl cinnamate;

Amyl cinnamic aldehyde;

Amyl cinnamic aldehyde dimethyl acetal;

iso-Amyl salicylate;

Hydroxycitronellal-methylanthranilate;

Benzophenone;

Benzyl salicylate;

para-tert-Butyl cyclohexyl acetate;

iso-Butyl quinoline;

beta-Caryophyllene;

Cadinene;

Cedrol;

Cedryl acetate;

Cedryl formate;

Cinnamyl cinnamate;

Cyclohexyl salicylate;

Cyclamen aldehyde;

Dihydro isojasmonate;

Diphenyl methane;

Diphenyl oxide;

Dodecalactone;

1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-ethanone;

Ethylene brassylate;

Ethylmethyl phenyl glycidate;

Ethyl undecylenate;

15-Hydroxypentadecanoic acid, tactone;

1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran;

Geranyl anthranilate;

Geranyl phenyl acetate;

Hexadecanolide;

Hexenyl salicylate;

Hexyl cinnamic aldehyde;

Hexyl salicylate;

alpha-Irone;

para-tertiary-Butyl-alpha-methyl hydrocinnamic aldehyde;

Linalyl benzoate;

2-Methoxy naphthalene;

Methyl dihydrojasmone;

gamma-n-Methyl ionone;

Musk indanone;

Musk ketone;

Musk tibetine;

Myristicin;

Oxahexadecanolide-10;

Oxahexadecanolide-11;

Patchouli alcohol;

5-Acetyl-1,1,2,3,3,6-hexamethyl indan;

Phenyl ethyl benzoate;

Phenylethylphenylacetate;

Phenyl heptanol;

Phenyl hexanol;

alpha-Santalol;

15-Hydroxypentadecanoic acid, lactone;

delta-Undecalactone;

gamma-Undecalactone;

Vetiveryl acetate;

yara-yara;

Ylangene; and

mixtures thereof.

25. A method of conditioning fabrics in a laundering process comprising a wash cycle which comprises a wash step and a rinsing step, wherein an effective amount of the bar composition of claim 1 sufficient to soften said fabrics, is contacted with said fabrics after the wash cycle.