Fabric softener compositions with improved environmental impact

• US 5,500,138 A
• Filed: 10/20/1994
• Issued: 03/19/1996
• Est. Priority Date: 10/20/1994
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Trinh, Toan, Bacon, Dennis R.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/326,555
• Time in Patent Office: 516 Days
• Field of Search: 252/8.6, 252/8.8, 252/8.7, 252/8.75
• US Class Current: 510/102
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/645 Mixtures of compounds all of which are cationic
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/75 Amino oxides
• CPC Class Codes: C11D 1/835 Mixtures of non-ionic with cationic compounds
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/50 Perfumes

Abstract

The present invention relates to liquid and solid biodegradable fabric softener compositions combined with highly enduring substantive perfumes. These compositions are naturally, or synthetically, derived perfumes which are hydrophobic, defined by having a low rinse water solubility (ClogP is greater than or equal to 3.0). These perfumes also have low volatility, a boiling point of 250° C., or greater. These compositions provide better perfume deposition on treated fabric, and consequently are not substantially lost during the rinse and drying cycle for less impact on the environment. Also, these perfumes improve the physical stability of the softener composition.

Claims

1. A rinse-added liquid fabric softening composition comprising:

(A) from about 0.5% to about 80% of biodegradable cationic fabric softening compound;

(B) from about 0.01% to about 10% of an enduring perfume which has at least about 70% of components with a ClogP≧

3.0 and a boiling point of≧

250°

C., ClogP being the calculated octanol/water partitioning coefficient (P) expressed as the logarithm to the base 10, logP;

(C) optionally, from about 0% to about 30% of dispersibility modifier; and

(D) the balance comprising a liquid carrier selected from the group consisting of;

water, C_1-4 monohydric alcohol;

C_2-6 polyhydric alcohol;

propylene carbonate;

liquid polyethylene glycols; and

mixtures thereof;

and wherein the dispersibility modifier affects the viscosity of said liquid fabric softening composition.

2. The composition of claim 1 wherein the quaternary ammonium fabric softening compound has the formula:

space="preserve" listing-type="equation">(R).sub.4-m --.sup.+ N--[(CH.sub.2).sub.n --Y--R.sup.2 ].sub.m X.sup.-

wherein;

each Y is --O--(O)C--, or --C(O)--O--;

m is 2 or 3;

n is 1 to 4;

each R is a C₁ -C₆ alkyl group, hydroxyalkyl group, benzyl group, or mixtures thereof, each R² is a C₁₂ -C₂₂ hydrocarbyl or substituted hydrocarbyl substituent; and

X^- is any softener-compatible anion.

3. The composition of claim 2 wherein the quaternary ammonium compound is derived from C₁₂ -C₂₂ fatty acyl groups having an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation of the fatty acyl groups being less than about 65% by weight.

4. The composition of claim 2 wherein the enduring perfume has at least about 75% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

5. The composition of claim 2 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

6. The composition of claim 2 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

7. The composition of claim 1 wherein the the enduring perfume has a least about 75% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

8. The composition of claim 1 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

9. The composition of claim 1 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

10. The composition of claim 1 wherein said enduring perfume composition is present at a level of from about 0.05% to about 8%.

11. The composition of claim 10 wherein said enduring perfume composition is present at a level of from about 0.1% to about 6%.

12. The composition of claim 11 wherein said enduring perfume composition is present at a level of from about 0.15% to about 4%.

13. The composition of claim 11 wherein the enduring perfume has a least about 85% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

14. The composition of claim 10 wherein the enduring perfume has a least about 75% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

15. The composition of claim 1 wherein said dispersibility modifier is selected from the group consisting of:

single-long-chain-C₁₀ -C₂₂ alkyl, cationic surfactant;

nonionic surfactant with at least 8 ethoxy moieties;

amine oxide surfactant; and

mixtures thereof.

16. The composition according to claim 15 wherein the dispersibility modifier is a single-long-chain-alkyl cationic surfactant which is present in an effective amount to affect the viscosity of up to about 15% of the composition.

17. The composition according to claim 16 wherein the dispersibility modifier is a quaternary ammonium salt of the general formula:

space="preserve" listing-type="equation">[R.sup.2 N.sup.+ R.sub.3 ] X.sup.-

wherein the R² group is a C₁₀ -C₂₂ hydrocarbon group, or the corresponding ester linkage interrupted group with a short alkylene (C₁ -C₄) group between the ester linkage and the N, and having a similar hydrocarbon group, each R is a C₁ -C₄ alkyl or substituted alkyl, or hydrogen; and

the counterion X^- is a softener compatible anion.

18. The composition according to claim 17 wherein the dispersibility modifier is C₁₂ -C₁₄ choline ester.

19. The composition according to claim 15 wherein the dispersibility modifier is a nonionic surfactant which is present in an effective amount to affect the viscosity of up to about 15% of the composition.

20. The composition according to claim 19 wherein the dispersibility modifier is C_10-14 alcohol with poly(10-18)ethoxylate.

21. The composition according to claim 15 wherein the dispersibility modifier is amine oxide with one alkyl, or hydroxyalkyl, moiety of about 8 to about 22 carbon atoms and two alkyl moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from one to about three carbon atoms.

22. The composition of claim 1 wherein the composition comprises:

(A) from about 1% to about 35% of biodegradable quaternary ammonium fabric softening compound;

(B) from about 0.05% to about 6% of an enduring perfume composition;

(C) from about 0.5% to about 10% of dispersibility modifier wherein the dispersibility modifier affects the composition'"'"'s viscosity, dispersibility in a laundry process rinse cycle, or both; and

(D) the balance comprising a liquid carrier selected from the group consisting of water;

C₁ -C₄ monohydric alcohols;

C₂ -C₆ polyhydric alcohols;

propylene carbonate;

liquid polyalkylene glycols; and

mixtures thereof.

23. The composition of claim 1 wherein the composition comprises:

(A) from about 15% to about 50% of biodegradable quaternary, ammonium fabric softening compound;

(B) from about 0.05% to about 6% of an enduring perfume composition;

(C) from about 0.5% to about 5% of dispersibility modifier wherein the dispersibility modifier affects the composition'"'"'s viscosity;

the balance comprising a liquid carder selected from the group consisting of water;

C₁ -C₄ monohydric alcohols;

C₂ -C₆ polyhydric alcohols;

propylene carbonate;

liquid polyalkylene glycols; and

mixtures thereof,

and wherein said composition further comprises from 0% to about 1% of a stabilizer; and

from about 0.01% to about 2% electrolyte.

24. The composition of claim 23 wherein the quaternary ammonium fabric softening compound has the formula:

space="preserve" listing-type="equation">(R).sub.4-m --.sup.+ N--[(CH.sub.2).sub.n --Y--R.sup.2 ].sub.m X.sup.-

wherein;

each Y is --O--(O)C--, or --C(O)--O--;

m is 2 or 3;

n is 1 to 4;

each R is a C₁ -C₆ alkyl group, hydroxyalkyl group, benzyl group, or mixtures thereof;

each R² is a C₁₂ -C₂₂ hydrocarbyl or substituted hydrocarbyl substituent; and

X^- is any softener-compatible anion.

25. The composition of claim 24 wherein the quaternary ammonium compound is derived from C₁₂ -C₂₂ fatty acyl groups having an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation of the fatty acyl groups being less than about 65% by weight.

26. The composition of claim 24 wherein the enduring perfume has at least about 75% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

27. The composition of claim 24 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

28. The composition of claim 24 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.

29. The composition of claim 24 wherein the level of said enduring perfume composition is from about 0.15% to about 4%.

30. The composition of claim 23 wherein the level of said enduring perfume composition is from about 0.15% to about 4%.

31. The composition of claim 1 wherein said enduring perfume composition contains at least 70% of materials selected from the group consisting of:

Allyl cyclohexane propionate;

Ambrettolide;

Amyl benzoate;

Amyl cinnamate;

Amyl cinnamic aldehyde;

Amyl cinnamic aldehyde dimethyl acetal;

iso-Amyl salicylate;

Hydroxycitronellal-methylanthranilate;

Benzophenone;

Benzyl salicylate;

para-tert-Butyl cyclohexyl acetate;

iso-Butyl quinoline;

beta-Caryophyllene;

Cadinene;

Cedrol;

Cedryl acetate;

Cedryl formate;

Cinnamyl cinnamate;

Cyclohexyl salicylate;

Cyclamen aldehyde;

Dihydro isojasmonate;

Diphenyl methane;

Diphenyl oxide;

Dodecalactone;

1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-ethanone;

Ethylene brassylate;

Ethylmethyl phenyl glycidate;

Ethyl undecylenate;

15-Hydroxypentadecanoic acid, lactone;

1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethytcyclopenta-gamma-2-benzopyran;

Geranyl anthranilate;

Geranyl phenyl acetate;

Hexadecanolide;

Hexenyl salicylate;

Hexyl cinnamic aldehyde;

Hexyl salicylate;

alpha-Irone;

para-tertiary-Butyl-alpha-methyl hydrocinnamic aldehyde;

Linalyl benzoate;

2-Methoxy naphthalene;

Methyl dihydrojasmone;

gamma-n-Methyl ionone;

Musk indanone;

Musk ketone;

Musk tibetine;

Myristicin;

Oxahexadecanolide-10;

Oxahexadecanolide-11;

Patchouli alcohol;

5-Acetyl-1,1,2,3,3,6-hexamethyl indan;

Phenyl ethyl benzoate;

Phenylethylphenylacetate;

Phenyl heptanol;

Phenyl hexanol;

alpha-Santalol;

delta-Undecalactone;

gamma-Undecalactone;

Vetiveryl acetate;

yara-yara;

Ylangene; and

mixtures thereof.

32. A solid particulate composition comprising:

(A) from about 50% to about 95% of biodegradable cationic fabric softening compound;

(B) from about 0.01% to about 15% of an enduring perfume composition which has at least about 70% of components with a ClogP≧

3.0 and a boiling point of≧

250°

C.;

ClogP being the calculated octanol/water partitioning coefficient (P) expressed as the logarithm to the base 10, logP;

(C) optionally, from 0% to about 30% of dispersibility improver; and

(D) optionally, from 0% to about 15% of pH modifier.

33. The composition of claim 32 wherein the composition comprises:

(A) from about 60% to about 90% of biodegradable cationic, diester, quaternary ammonium fabric softening compound;

(B) from about 0.05% to about 8% of an enduring perfume composition;

(C) from 3% to about 15% of dispersibility modifier; and

(D) optionally, from 0% to about 10% of pH modifier.

34. The composition of claim 32 wherein said enduring perfume composition contains at least 70% of materials selected from the group consisting of:

Allyl cyclohexane propionate;

Ambrettolide;

Amyl benzoate;

Amyl cinnamate;

Amyl cinnamic aldehyde;

Amyl cinnamic aldehyde dimethyl acetal;

iso-Amyl salicylate;

Hydroxycitronellal-methylanthranilate;

Benzophenone;

Benzyl salicylate;

para-tert-Butyl cyclohexyl acetate;

iso-Butyl quinoline;

beta-Caryophyllene;

Cadinene;

Cedrol;

Cedryl acetate;

Cedryl formate;

Cinnamyl cinnamate;

Cyclohexyl salicylate;

Cyclamen aldehyde;

Dihydro isojasmonate;

Diphenyl methane;

Diphenyl oxide;

Dodecalactone;

1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-ethanone;

Ethylene brassylate;

Ethylmethyl phenyl glycidate;

Ethyl undecylenate;

15-Hydroxypentadecanoic acid, lactone;

1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran;

Geranyl anthranilate;

Geranyl phenyl acetate;

Hexadecanolide;

Hexenyl salicylate;

Hexyl cinnamic aldehyde;

Hexyl salicylate;

alpha-Irone;

para-tertiary-Butyl-alpha-methyl hydrocinnamic aldehyde;

Linalyl benzoate;

2-Methoxy naphthalene;

Methyl dihydrojasmone;

gamma-n-Methyl ionone;

Musk indanone;

Musk ketone;

Musk tibetine;

Myristicin;

Oxahexadecanolide-10;

Oxahexadecanolide-11;

Patchouli alcohol;

5-Acetyl-1,1,2,3,3,6-hexamethyl indan;

Phenyl ethyl benzoate;

Phenylethylphenylacetate;

Phenyl heptanol;

Phenyl hexanol;

alpha-Santalol;

delta-Undecalactone;

gamma-Undecalactone;

Vetiveryl acetate;

yara-yara;

Ylangene; and

mixtures thereof.