Topical hydrophobic composition and method

• US 5,500,216 A
• Filed: 06/18/1993
• Issued: 03/19/1996
• Est. Priority Date: 06/18/1993
• Status: Expired due to Term

• Current Assignee: Slip-Not Corporation
• Original Assignee: Slip-Not Corporation
• Inventors: Garruto, John A., Julian, Jorge V.
• Primary Examiner(s): Page, Thurman K.
• Assistant Examiner(s): Benston, Jr., William E.
• Application Number:
  US08/079,333
• Time in Patent Office: 1,005 Days
• Field of Search: 424/401
• US Class Current: 424/401
• CPC Class Codes: A61K 8/25 Silicon; Compounds thereof
• CPC Class Codes: A61K 8/585 Organosilicon compounds
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61Q 17/00 Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin

Abstract

Drag is reduced during swimming by topically applying a film of rough particles of hydrophobic metal oxide such as organo silicon modified silicon oxide particles to certain skin surfaces of the swimmer. A uniform suspension of a long acting composition is formed by a mixture of 2 hydrophobic metal oxides in vaporizable liquid carrier such as ethanol containing a vaporizable plasticizer such as propylene glycol in which the amount of the larger hydrophobic metal oxide particles in the mixture predominates over the amount of smaller particles of hydrophobic metal oxide.

Claims

1. A method of reducing drag of a swimmer relative to water comprising the steps of:

before swimming, topically applying to body surfaces of a swimmer a dispersion of particles of hydrophobic metal oxide in a pharmacologically acceptable fluid carrier; and

removing the carrier to form a film of hydrophobic metal oxide particles on said surfaces.

2. A method according to claim 1 wherein the metal oxide is a silicon dioxide treated with hexamethyldisilazane or silicon dioxide treated with dimethyldichlorosilane or silicon dioxide treated with a polydimethyl siloxane polymer.

3. A method according to claim 2 wherein the carrier is a liquid vaporizable under ambient conditions, The carrier can be water, an alkanol containing 1-6 carbon atoms or mixtures thereof.

4. A method according to claim 3 wherein the liquid contains (a minor amount of a plasticizer) from 1-10% by weight of hypo-allergenic plasticizer such as a polyol containing from 2-8 carbon atoms such as ethylene glycol, propylene glycol, glycerol, or dimers, trimers and liquid polymers thereof or alkoxylated derivatives thereof such as methoxylated polyols.

5. A method according to claim 3 in which the particles have a rough surface.

6. A method according to claim 5 in which the particles are present in the dispersion in an amount of from 2-20% by weight and the surface of the particles contain silanol groups connected to organosilicon moieties which provide hydrophobic properties to the particles.

7. A method according to claim 6 in which at least 70% of the surface silanol groups are connected to organosilicon groups.

8. A method according to claim 7 in which the organo groups of the organosilicon moieties are selected from alkyl, aryl, arylalkyl, alkoxy or aryloxy containing from 1 to 20 carbon atoms.

9. A method according to claim 1 in which the metal oxides have a surface area from 10-800 sq. meter per gram.

10. A superhydrophobic, lotion composition for application to the skin of users comprising:

a uniform dispersion of a hydrophobic silicon oxide in a pharmacologically acceptable liquid carrier, vaporizable at ambient conditions and including a minor amount of a plasticizer.

11. A composition according to claim 10 in which the hydrophobic metal oxide is present in an amount from 2-20% by weight.

12. A composition according to claims 11 in which the hydrophobic metal oxide is a mixture of a minor amount of a first hydrophobic silicon oxide and a minor amount of a second hydrophobic silicon oxide having a surface area at least 1.5 times the surface area of the first hydrophobic metal oxide.

13. A composition according to claim 12 in which the liquid carrier is a lower alkanol present in an amount form 60-90% by weight and the plasticizer is a liquid polyol present in an amount from 1 to 10% by weight.

14. A composition according to claim 13 in which the alkanol is ethanol and the polyol is propylene glycol.

15. A composition according to claim 14 in which the first hydrophobic metal oxide contains polydimethyl siloxane polymeric groups on its surface and the second hydrophobic metal oxide contains trimethyl silyl groups on its surface.