Comminution with small particle milling media

• US 5,500,331 A
• Filed: 05/25/1994
• Issued: 03/19/1996
• Est. Priority Date: 05/25/1994
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Seaman, Larry P., Czekai, David A.
• Primary Examiner(s): Bowers, Jr., Charles L.
• Assistant Examiner(s): Huff, Mark F.
• Application Number:
  US08/248,774
• Time in Patent Office: 664 Days
• Field of Search: 430/546, 430/377, 430/449, 430/631, 241/184
• US Class Current: 430/449
• CPC Class Codes: B02C 17/20 Disintegrating members
• CPC Class Codes: G03C 1/005 Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein catalytic amounts of silver halide in dry silver systems or thermographic systems using noble metal compounds G03C1/494
• CPC Class Codes: G03C 7/388 Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor incorporation of additives other than couplers G03C1/005

Abstract

A method of preparing submicron particles of a material, such as a pigment useful in paints or a compound useful in imaging elements, which comprises milling the agent in the presence of milling media having a mean particle size of less than about 100 microns. In a preferred embodiment, the milling media is a polymeric resin. The method provides extremely fine particles, e.g., less than 100 nm in size, free of unacceptable contamination.

Claims

1. A method of preparing submicron particles of a compound useful in imaging elements in the presence of rigid milling media having a mean particle size of less than 100 microns.

2. The method of claim 1, wherein said media is a polymeric resin.

3. The method of claim 1, wherein said media have a mean particle size of less than 75 microns.

4. The method of claim 1, wherein said media have an average size of about 50 microns.

5. The method of claim 1, wherein said milling media comprises polystyrene crosslinked with divinyl benzene.

6. The method of claim 1, wherein said milling media comprises polymethylmethacrylate.

7. The method of claim 1, wherein said method is a wet milling process.

8. The method of claim 1, wherein said milling takes place in a mill selected from an airjet mill, a roller mill, a ball mill, an attritor mill, a vibratory mill, a planetary mill, a sand mill and a bead mill.

9. The method of claim 1, wherein the compound useful in imaging elements is selected from the group consisting of dye-forming couplers, development inhibitor release couplers (DIR'"'"'s), development inhibitor anchimeric release couplers (DI(A)R'"'"'s), masking couplers, filter dyes, optical brighteners, nucleators, development accelerators, oxidized developer scavengers, ultraviolet radiation absorbing compounds, sensitizing dyes, development inhibitors, antifoggants, bleach accelerators, magnetic particles, lubricants, and matting agents.

10. A dispersion for use in the preparation of an imaging element comprising a liquid medium having dispersed therein solid particles of a compound useful in imaging elements having an average particle diameter of less than 100 nm milled in accordance with claim 1.

11. An imaging element comprising a support having thereon at least one dispersion according to claim 10.