Microfiltration enhanced reverse osmosis for water treatment

• US 5,501,798 A
• Filed: 04/06/1994
• Issued: 03/26/1996
• Est. Priority Date: 04/06/1994
• Status: Expired due to Term

• Current Assignee: Zenon Environmental Incorporated
• Original Assignee: Zenon Environmental Incorporated
• Inventors: Al-Samadi, Riad A., Benedek, Andrew
• Primary Examiner(s): Fortuna, Ana M.
• Application Number:
  US08/225,454
• Time in Patent Office: 720 Days
• Field of Search: 210/651, 210/652, 210/650, 210/705, 210/712, 210/714, 210/733, 210/737, 210/195.2, 210/805, 210/688, 210/712, 210/638, 210/700, 210/641, 210/749
• US Class Current: 210/652
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/12 Addition of chemical agents
• CPC Class Codes: B01D 2311/18 pH control
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/04 Feed pretreatment
• CPC Class Codes: B01D 61/147 Microfiltration
• CPC Class Codes: B01D 61/58 Multistep processes
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 1/66 by neutralisation; pH adjustment for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58
• CPC Class Codes: C02F 5/08 Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents

Abstract

Disclosed is an improved method for extending the useful life of a reverse osmosis membrane having a high pressure side and a low pressure side, the membrane used for separating soluble and sparingly soluble inorganic materials from an aqueous solution, the process comprising introducing an aqueous solution containing the soluble and sparingly soluble inorganic materials to the high pressure side of a reverse osmosis membrane and pressurizing the aqueous solution on said high pressure side to produce liquid on the low pressure side substantially free of said inorganic materials. Solution containing concentrated inorganic materials is transformed from the high pressure side of the reverse osmosis membrane to a high pressure side of a microfiltration membrane, and soluble inorganic materials transferred to the high pressure side of the microfiltration membrane was precipitated to provide solution containing particles of the inorganic materials.

Claims

1. An improved method of extending the useful life of a reverse osmosis (RO) membrane having a high pressure side and a low pressure side, the membrane used for separating sparingly soluble inorganic materials from an aqueous liquid, the method capable of 90% to 99% recovery of purified liquid, comprising:

(a) introducing and aqueous liquid containing sparingly soluble inorganic materials to which have been added antiscalant to the high pressure side of a RO membrane;

(b) pressurizing said aqueous liquid on said high pressure side to produce purified liquid on the low pressure side substantially free of said inorganic materials;

(c) removing liquid containing concentrate sparingly soluble inorganic materials from the high pressure side of said RO membrane, the liquid being removed before precipitation of said concentrated sparingly soluble inorganic material on the RO membrane;

(d) recovering purified liquid as treated water on the low pressure side of said RO membrane at a rate of at least 70% the rate of introducing said aqueous liquid containing sparingly soluble inorganic materials to the high pressure side of said RO;

(e) precipitating said sparingly soluble inorganic materials removed from the high pressure side of the RO membrane to provide liquid containing inorganic precipitate;

(f) passing said liquid containing inorganic precipitate to a high pressure side of a microfiltration (MF) membrane;

(g) passing liquid form the high pressure side of said MF membrane to a low pressure side of said MF membrane thereby providing substantially precipitate-free liquid and concentrating said particles of said inorganic materials on the high pressure side of said MF membrane;

(h) removing particles of said inorganic materials from the high pressure side of said MF membrane; and

(i) recirculating precipitate-free liquid from the low pressure side of said MF membrane and introducing to the high pressure side of the RO membrane thereby providing for high levels of recovery of said purified liquid and extending the life of said RO membrane.

2. The method in accordance with claim 1 including operating said RO membrane at a pressure in the range of 100 to 200 psig in excess of said membrane osmotic pressure.

3. The method in accordance with claim 1 including operating said RO membrane at a pressure in the range of 500 to 1000 psig.

4. The method in accordance with claim 1 including removing said concentrated soluble inorganic material from the high pressure side of said RO membrane at a rate in the range of 25% to 50% of the rate of said introducing an aqueous liquid containing sparingly soluble inorganic materials to said high pressure side of said RO membrane.

5. The method in accordance with claim 4 including removing said concentrated soluble inorganic material from the high pressure side of said RO membrane at a rate in the range of 20% to 30% of the rate of said introducing an aqueous liquid containing sparingly soluble inorganic materials to said high pressure side of said RO membrane.

6. The method in accordance with claim 1 including adjusting the pH of the aqueous liquid to precipitate said sparingly soluble inorganic material prior to MF.

7. The method in accordance with claim 1 including increasing the pH of the aqueous liquid to a pH in the range or 8 to 12 to precipitate said soluble inorganic material prior to MF.

8. The method in accordance with claim 1 including increasing the pH of the aqueous liquid to a pH in the range of 10 to 11 to precipitate said soluble inorganic material prior to MF.

9. The method in accordance with claim 1 including the step of adjusting the pH of the precipitate-free liquid from the high pressure side of said RO membrane to a pH in the range of 5 to 7.

10. The method in accordance with claim 1 including the step of adding an inorganic seed to said aqueous liquid removed from the high pressure side of the RO membrane to precipitate sparingly soluble inorganic material therefrom.

11. The method in accordance with claim 10 wherein said seed is selected from the group consisting of CaCO₃, SiO₂, CaSO₄ and FeCl₃.

12. The method in accordance with claim 1 including the step of heating the liquid removed from the high pressure side of said RO membrane for precipitating said sparingly soluble inorganic materials.

13. The method in accordance with claim 1 wherein said antiscalant is selected from the group consisting of polyacrylates, EDTA and sodium hexametaphosphate.

14. The method in accordance with claim 1 including the step of removing liquid from said inorganic precipitate removed from the high pressure side of said MF membrane and recirculating said liquid to said body of aqueous liquid.

15. An improved method of extending the useful life of a membrane having a high pressure side and low pressure side, the membrane used for separating sparingly soluble inorganic materials from an aqueous liquid, the method capable of providing 90% to 99% recovery of purified liquid, the method comprising:

(a) providing a body of aqueous liquid containing sparingly soluble inorganic material;

(b) precipitating a portion of said sparingly soluble inorganic material from said body of aqueous liquid to provide inorganic precipitate;

(c) introducing a stream of aqueous liquid from said body to a high pressure side of a first membrane suited to separate said inorganic precipitate from the aqueous liquid;

(d) passing aqueous liquid in said high pressure side to produce a precipitate-free liquid on a low pressure side of said first membrane, thereby concentrating said inorganic precipitate on the high pressure side;

(e) recirculating said inorganic precipitate from the high pressure side of said first membrane to said precipitation step;

(f) adding an antiscalant to said precipitate free liquid to maintain sparingly soluble inorganic material contained in the liquid in solution;

(g) adding precipitate-free liquid containing said antiscalant to the high pressure side of a second membrane suited for separating soluble inorganic from the liquid;

(h) pressurizing said precipitate free liquid on the high pressure side of said second membrane to produce purified permeate on the low pressure side and to provide concentrate sparingly soluble inorganic material in the high pressure side of said second membrane;

(i) removing concentrate sparingly soluble inorganic material in liquid from said high pressure side of said second membrane at a rate sufficient to avoid precipitation of said concentrate sparingly soluble inorganic material on said second membrane;

(j) recovering purified permeate from the low pressure side of said second membrane at a rate of at lest 70% the rate of said adding said stream of aqueous liquid containing said sparingly soluble inorganic material to said body; and

(k) recirculating concentrate sparingly soluble inorganic material in liquid for precipitating of said concentrated sparingly soluble inorganic material.

16. The method in accordance with claim 15 including operating said second membrane at a pressure in the range of 100 to 200 psig in excess of said membrane osmotic pressure.

17. The method in accordance with claim 15 including operating said second membrane at a pressure in the range of 500 to 1000 psig.

18. The method in accordance with claim 15 including removing said concentrated soluble inorganic material from the high pressure side of said second membrane at a rate in the range of 25% to 50% of the rate of said adding precipitate-free liquid containing said antiscalant to said high pressure side of said second membrane.

19. The method in accordance with claim 18 including removing said concentrated soluble inorganic material from the high pressure side of said second membrane at a rate in the range of 20% to 30% of the rate of said adding precipitate-free liquid containing said antiscalant to said high pressure side of said second membrane.

20. The method in accordance with claim 15 including the step of adding an inorganic seed to said liquid removed from the high pressure side of said second membrane to precipitate sparingly soluble inorganic material therefrom.

21. The method in accordance with claim 20 wherein said seed is selected from the group consisting of CaCO₃, SiO₂, CaSO₄ and FeCl₃.

22. The method in accordance with claim 15 including the step of heating the liquid removed from the high pressure side of said first membrane for precipitating said sparingly soluble inorganic materials.