Method of reclaiming styrene and other products from polystyrene based products

• US 5,502,263 A
• Filed: 01/10/1995
• Issued: 03/26/1996
• Est. Priority Date: 01/28/1993
• Status: Expired due to Term

• Current Assignee: Henry T. Ponsford, Thomas E. Ponsford
• Original Assignee: Henry T. Ponsford, Thomas E. Ponsford
• Inventors: Ponsford, Henry T., Ponsford, Thomas E.
• Primary Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US08/370,682
• Time in Patent Office: 441 Days
• Field of Search: 585/241, 585/240, 585/439
• US Class Current: 585/241
• CPC Class Codes: C07C 15/46 Styrene; Ring-alkylated styrenes
• CPC Class Codes: C07C 4/22 by depolymerisation to the original monomer, e.g. dicyclopentadiene to cyclopentadiene
• CPC Class Codes: C09K 5/10 Liquid materials
• CPC Class Codes: C10G 1/10 from rubber or rubber waste
• CPC Class Codes: C10L 1/04 essentially based on blends of hydrocarbons
• CPC Class Codes: C10M 105/06 aromatic
• CPC Class Codes: C10M 127/04 well-defined aromatic
• CPC Class Codes: C10M 2203/06 Well-defined aromatic compounds
• CPC Class Codes: C10N 2040/06 Instruments or other precision apparatus, e.g. damping fluids
• CPC Class Codes: C10N 2040/08 Hydraulic fluids, e.g. brake-fluids
• CPC Class Codes: C23F 15/00 Other methods of preventing corrosion or incrustation
• CPC Class Codes: G21D 5/08 with engine working medium heated in a heat exchanger by the reactor coolant
• CPC Class Codes: Y02E 30/00 Energy generation of nuclear origin

Abstract

In the method for reclaiming styrene monomer from polystyrene, polystyrene is mixed with a solvent and heated to approximately 300° C. to 400° C. to depolymerize the polystyrene to produce a styrene monomer fraction and a heavier fraction of partial depolymerization products. The styrene fraction is separated from the heavier fraction to recover the styrene monomer and polystyrene partial depolymerization products. In a preferred embodiment, the solvent comprises a "styrene oil" which results from the incomplete depolymerization of polystyrene, at least a portion of which is recycled to mix with polystyrene. The method is useful in reclaiming styrene monomer from napalm, foamed polystyrene, and other polystyrene products. In the case of reclamation of napalm, the method also includes the steps of separating and recovering benzene and gasoline.

Claims

1. A method for reclamation of styrene from polystyrene in polystyrene based products, comprising the steps of:

mixing the polystyrene based product with a solvent to form a polystyrene solution having a sufficiently low viscosity to allow free boiling of said polystyrene solution, said solvent being selected from the group consisting of vinylbenzene, and styrene oil resulting from the partial depolymerization of polystyrene, said styrene oil having a pour point below -20°

C. and a boiling point between about 300°

C. and 320°

C.;

heating the polystyrene solution to a temperature of from approximately 300°

C. to 400°

C. to depolymerize the polystyrene and to produce a vinylbenzene fraction and a heavier containing said styrene oil as a result of the partial depolymerization of polystyrene;

separating the vinylbenzene fraction from the heavier fraction; and

recycling at least a portion of said styrene oil to provide at least a portion of said solvent in the step of mixing said polystyrene with said solvent to form a polystyrene solution prior to said step of heating the polystyrene solution.

2. The method of claim 1, wherein said step of separating the vinylbenzene fraction from the heavier fraction comprises heating the vinylbenzene fraction and the heavier fraction to a temperature of from about 145°

C. to about 325°

C. to distill the vinylbenzene and heavier fractions; and

separating the vinylbenzene fraction from the heavier fraction by continuous fractional distillation.

3. The method of claim 2, wherein said vinylbenzene fraction includes toluene, and said step of separating the vinylbenzene fraction from the heavier fraction comprises distilling said vinylbenzene, said toluene and said heavier fraction by continuous fractional distillation.

4. A method for reclamation of vinylbenzene from polystyrene based products, comprising the steps of:

mixing the polystyrene based product with a solvent selected from the group consisting of vinylbenzene, and styrene oil resulting from the partial depolymerization of polystyrene, said styrene oil having a pour point below -20°

C. and a boiling point between about 300°

C. and about 320°

C., and mixtures thereof, to form a polystyrene solution having a sufficiently low viscosity to allow free boiling of said polystyrene solution;

heating the polystyrene solution to a temperature of from about 300°

C. to about 400°

C. to depolymerize the polystyrene and to produce a vinylbenzene fraction and a heavier fraction of partial depolymerization products containing said styrene oil as a result of the partial depolymerization of polystyrene;

separating the vinylbenzene fraction from the heavier fraction by continuous fractional distillation; and

recycling at least a portion of said styrene oil to mix with said polystyrene in forming said polystyrene solution.

5. The method of claim 4, wherein said vinylbenzene fraction includes toluene, and said step of separating the vinylbenzene fraction from the heavier fraction comprises heating the vinylbenzene fraction and the heavier fraction to a temperature of about 110°

C. to about 325°

C. to distill said vinylbenzene, said toluene and said heavier fraction by continuous fractional distillation.

6. A method for reclamation of styrene from polystyrene in polystyrene based products, comprising the steps of:

mixing the polystyrene based product with a solvent selected from the group consisting of vinylbenzene and a mixture of vinylbenzene with styrene oil resulting from the partial depolymerization of polystyrene, said styrene oil having a pour point below -20°

C. and a boiling point between about 300°

C. and about 320°

C., to form a polystyrene solution having a sufficiently low viscosity to allow free boiling of said polystyrene solution;

heating the polystyrene solution to a temperature of from about 300°

C. to about 400°

C. to depolymerize the polystyrene and to produce a vinylbenzene fraction and a heavier fraction containing said styrene oil as a result of the partial depolymerization of polystyrene;

separating the vinylbenzene fraction from the heavier fraction by continuous fractional distillation; and

recycling at least a portion of said styrene oil to mix with said polystyrene in forming said polystyrene solution prior to said step of heating the polystyrene solution.