Storage-stable encapsulated sodium percarbonate and process for its production

• US 5,505,875 A
• Filed: 05/20/1994
• Issued: 04/09/1996
• Est. Priority Date: 09/03/1991
• Status: Expired due to Fees

• Current Assignee: Degussa AG (Rag-Stiftung)
• Original Assignee: Degussa AG (Rag-Stiftung)
• Inventors: Beaujean, Hans-Josef, Bode, Jens, Carduck, Franz-Josef
• Primary Examiner(s): Lovering, Richard D.
• Application Number:
  US08/199,289
• Time in Patent Office: 690 Days
• Field of Search: 252/174.13, 252/186.27, 252/358, 252/99, 264/4.4, 427/213.36, 427/220, 427/240, 423/415.2, 428/402.24
• US Class Current: 252/186.27
• CPC Class Codes: C01B 15/106 Stabilisation of the solid compounds, subsequent to the preparation or to the crystallisation, by additives or by coating
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 3/394 Organic compounds
• CPC Class Codes: C11D 3/3942 Inorganic per-compounds C11D3/3902 takes precedence
• CPC Class Codes: Y10T 428/2989 Microcapsule with solid core [includes liposome]

Abstract

Storage stability of finely divided sodium percarbonate is improved by melt-coating of water-insoluble encapsulation agents.

Claims

1. A process for melt-coating a coating material that is solid at room temperature onto finely divided solid sodium percarbonate particles, comprising centrifugally atomizing a finely divided solid coating material in a continuous flow through a likewise continuously generated fog zone of said coating material in molten form to thereby obtain nonaqueous encapsulation of said solid sodium percarbonate with a hydrophobic protective coating of said coating material, wherein said coating material is a defoamer mixture free of siloxane polymer, emulsifying or dispersing tenside and is a homogeneous mixture of:

a) 25 to 60 percent by weight of a paraffin wax or a mixture of paraffin waxes,

b) 10 to 60 percent by weight of microcrystalline paraffin wax, whereby the proportion of liquid components in the mixture of (a) and (b), as determined by differential thermal analysis (DTA) is 0% at -15°

C., 0% to 5% at 0°

C., 2% to 25% at 25°

C., 20% to 80% at 50°

C., 80% to 100% at 75°

C. and 100% above 90°

C.,

c) 5 to 20 percent by weight of a diamide derived from C_2-7 diamines and saturated C_12-22 fatty acids, which is present in finely divided form and has a particle size of less than 50 μ

m, with at least 90% of the particles smaller than 30 μ

m.

2. The process according to claim 1 wherein said sodium percarbonate resides in said fog zone for less than one second.

3. The process according to claim 2 wherein said sodium percarbonate resides in said fog zone for less than 0.5 seconds.

4. The process according to claim 2 further comprising immediately cooling said sodium percarbonate after being coated.

5. The process according to claim 4 wherein said cooling is carried out by subjecting said sodium percarbonate to a cooling gas flow.

6. The process according to claim 5 wherein the cooling gas flow is air or liquid nitrogen.

7. The process according to claim 6 wherein the air or liquid nitrogen is added in such volume proportions that adhesions among the freshly coated protective coatings are largely prevented.

8. The process according to claim 1, further comprising immediately cooling said sodium percarbonate after being coated.

9. The process according to claim 8 wherein said cooling is carried out by subjecting said sodium percarbonate to a cooling gas flow.

10. The process according to claim 9 wherein said cooling gas flow is air or liquid nitrogen.

11. The process according to claim 10 further comprising maintaining the air or liquid nitrogen in such volume proportions that adhesions among the freshly coated protective coatings are largely prevented.

12. The process according to claim 1 wherein said coating material has a solidification temperature above 40°

C., which does not exceed 150°

C.

13. The process according to claim 12 wherein the solidification temperature is above about 50°

C.

14. The process according to claim 12 wherein the solidification temperature is 45°

to 110°

C.

15. The process according to claim 1 wherein said coating material has a narrow solidification range.

16. The process according to claim 15 wherein said narrow solidification range is not more than about 10°

C.

17. The process according to claim 15 wherein said narrow solidification range is not more than about 5°

C.

18. The process according to claim 1 further comprising adjusting the temperature of the atomized coating material in the fog zone to a value in the range of about 10°

to 50°

C. above the solidification temperature or range of the coating material.

19. The process according to claim 1 wherein said coating materials are at least predominantly of natural origin.

20. The process according to claim 1 further comprising wherein the protective coating layer is applied in the proportions of about 2% by weight at least based on the finished product, and the proportion of the protective layer as a whole is no more than about 15 to 20% by weight.

21. The process according to claim 20 wherein the amount is about 5% by weight.

22. Sodium percarbonate powder provided with a protective coating of a water-repelling coating material, suitable for mixing into solid washing and/or cleaning agents, wherein said protective coating is applied by the process of claim 1.

23. The sodium percarbonate powder according to claim 22 further comprising that it is a practically unagglomerated pourable material with particle sizes in the range of about 0.1 to 2 mm.

24. The sodium percarbonate powder according to claim 22 further comprising that it also contains in the sodium percarbonate core and/or in the coating material a stabilizer for sodium percarbonate.

25. The sodium percarbonate powder according to claim 24 wherein complexing agents for metal binding are present.