Polymers capable of reversibly complexing acid gases and a method of using the same

• US 5,507,848 A
• Filed: 03/12/1993
• Issued: 04/16/1996
• Est. Priority Date: 03/12/1993
• Status: Expired due to Fees

• Current Assignee: University Of Pittsburgh (University of Pittsburgh of The Commonwealth System of Higher Education)
• Original Assignee: Eric J. Beckman
• Inventors: Beckman, Eric J.
• Primary Examiner(s): Lipman, Bernard
• Application Number:
  US08/030,995
• Time in Patent Office: 1,131 Days
• Field of Search: 55/522, 55/524, 55/528, 525/332.2
• US Class Current: 55/522
• CPC Class Codes: B01D 2253/202 Polymeric adsorbents
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/50 Carbon oxides
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01J 20/26 Synthetic macromolecular compounds
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Aminated polymers capable of reversibly complexing carbon dioxide and other acid gases including CO₂, SO₂, NO_x and H₂ S, a method of using such polymers and an operational unit including such polymers are disclosed. The polymers incorporate amine group which reversibly complex acid gases. Such polymers provide a significant advantages over presently used sorbents used to remove acid gas.

Claims

1. A method or removing an acid gas from a gas system, comprising the step of:

(a) exposing an acid gas sorbent comprising an aminated polymer to the gas system under conditions suitable to reactively complex the acid gas with said aminated polymer, said aminated polymer having a molecular weight greater than or equal to approximately 5000, said aminated polymer comprising covalently attached amino functional groups suitable to complex the acid gas.

2. The method of removing an acid gas from a gas system of claim 1 further comprising the step of:

(b) heating said complexed aminated polymer to a temperature sufficiently high to debond the acid gas.

3. The method of removing an acid gas of claim 2 wherein steps (a) and (b) are repeated.

4. The method of removing an acid gas of claim 1 wherein said at least one acid gas is complexed to pendant amine groups of said aminated polymer.

5. The method of removing an acid gas of claim 4 wherein said pendant amine groups are selected from the group consisting of diamines and triamines.

6. The method of removing an acid gas of claim 4 wherein said pendant amine groups are selected from the group consisting of primary and secondary amines.

7. The method of removing an acid gas of claim 5 wherein said amines groups are selected from the group consisting of primary and secondary amines.

8. The method of removing an acid gas of claim 1 wherein said aminated polymer comprises a copolymer of styrene and an amine functional vinylbenzyl moiety.

9. The method of removing an acid gas of claim 1 wherein said aminated polymer comprises a microporous, crosslinked polymer.

10. The method of removing an acid gas of claim 9 wherein said microporous, crosslinked polymer comprises a copolymer of divinylbenzene and an aminated vinylbenzyl moiety.

11. The method of removing an acid gas of claim 10 wherein said microporous, crosslinked polymer comprises a copolymer of divinylbenzene, styrene and an aminated vinylbenzyl moiety.