Cleansing articles with controlled detergent release and method for their manufacture

• US 5,507,968 A
• Filed: 12/14/1994
• Issued: 04/16/1996
• Est. Priority Date: 12/14/1994
• Status: Expired due to Term

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Palaikis, Liana V.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Douyon, Lorna M.
• Application Number:
  US08/355,678
• Time in Patent Office: 489 Days
• Field of Search: 252/90, 252/91, 252/93, 252/174.23
• US Class Current: 15/229.11
• CPC Class Codes: A47L 13/17 containing cleaning agents A47L13/19 takes precedence ; chemical compositions C11D17/049
• CPC Class Codes: C11D 17/049 Cleaning or scouring pads; Wipes
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines

Abstract

A cleansing article along with its method for manufacture are provided. The cleansing article comprises a porous pad which includes a controlled detergent release composition comprising: polyacrylamide (preferably having a weight average molecular weight greater than 200,000) and detergent preferably blended to provide a weight ratio of polymer solids:detergent solids between about 1:9 and about 1:100 and more preferably between about 1:12 and about 1:30. The method comprises preparing a coatable polymer/detergent blend comprising polyacrylamide, detergent and a liquid vehicle which on drying forms a controlled detergent release composition, applying said coatable blend to a porous pad, and drying said blend to provide said controlled detergent release composition. The controlled detergent release composition is substantially retained within the pad for subsequent use and thereafter slowly released when used.

Claims

1. A cleansing article comprising:

a porous pad; and

a water swellable controlled detergent release composition incorporated within said pad, said composition comprising polyacrylamide having detergent blended therein, said polyacrylamide having a weight average molecular weight of at least 5 million, said polyacrylamide and said detergem blended within said composition to allow for the controlled release of said detergent when said composition is exposed to water.

2. The cleansing article as defined in claim 1 wherein said polyacrylamide and said detergent are present in said controlled detergent release composition at a weight ratio of polymer solids:

detergent solids between about 1;

9 and about 1;

100.

3. The cleansing article as defined in claim 1 wherein said polyacrylamide and said detergent are contained within said controlled detergent release composition at a weight ratio of polymer solids:

detergent solids between about 1;

12 and about 1;

30.

4. The cleansing article as defined in claim 1 wherein said polyacrylamide has a weight average molecular weight within a range from about 5 million to about 15 million.

5. The cleansing article as defined in claim 1 wherein said controlled release detergent composition comprises surfactant.

6. The cleansing article as defined in claim 5 wherein said surfactant is selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants and mixtures including more than one of said surfactants.

7. The cleansing article as defined in claim 6 wherein said anionic surfactants are selected from the group consisting of sodium or ammonium salts of sulfonated alkyls, sulfonic acids, sulfated alkyl ethers, sulfated fatty esters and lauryl sulfates.

8. The cleansing article as defined in claim 6 wherein said amphoteric surfactants are selected from the group consisting of cocamidopropyl betaine, coco/oleoamidopropyl betaine and combinations thereof.

9. The cleansing article as defined in claim 6 wherein said nonionic surfactants are selected from the group consisting of ethoxylated amines and amides, fatty alkanolamides and combinations thereof.

10. The cleansing article as defined in claim 6 wherein said cationic surfactants are selected from the group consisting of lauramine oxide, lauramidopropylamine oxide, stearamide oxide and combinations thereof.

11. The cleansing article as defined in claim I wherein said porous pad comprises a material selected from the group consisting of sponge, paper, fabric, plastic fibers, plastic ribbons, metal fibers, metal ribbons, and composite structures incorporating one or more of the foregoing materials.

12. The cleansing article as defined in claim 11 wherein said metal fibers are steel wool.

13. The cleansing article as defined in claim 11 wherein said porous pad is a nonwoven lofty low density abrasive scouring pad.

14. A cleansing article, comprising:

a pad comprising a lofty nonwoven, open, three-dimensional network of fibers; and

a water swellable controlled detergent release composition coated on said fibers, said composition comprising a polyacrylamide having a detergent therein to provide a weight ratio of polymer solids;

detergent solids between about 1;

9 and about 1;

100 and, said polyacrylamide having a weight average molecular weight of at least 5 million, wherein said composition provides the controlled release of said detergent when wet.

15. The cleansing article as defined in claim 14 wherein said weight ratio of polymer solids:

detergent solids is between about 1;

12 and about 1;

30.

16. The cleansing article as defined in claim 14 wherein said detergent comprises surfactant.

17. The cleansing article as defined in claim 16 wherein said surfactant is selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants and mixtures including more than one of said surfactants.

18. The cleansing article as defined in claim 17 wherein said anionic surfactants are selected from the group consisting of sodium or ammonium salts of sulfonated alkyls, sulfonic acids, sulfated alkyl ethers, sulfated fatty esters and lauryl sulfates.

19. The cleansing article as defined in claim 17 wherein said amphoteric surfactants are selected from the group consisting of cocamidopropyl betaine, coco/oleoamidopropyl betaine and combinations thereof.

20. The cleansing article as defined in claim 17 wherein said nonionic surfactants are selected from the group consisting of ethoxylated amines and amides, fatty alkanolamides and combinations thereof.

21. The cleansing article as defined in claim 17 wherein said cationic surfactants are selected from the group consisting of lauramine oxide, lauramidopropylamine oxide, stearamide oxide and combinations thereof.

22. A process for the manufacture of a cleansing article, the process comprising:

preparing a coatable composition comprising polyacrylamide having a weight average molecular weight of at least 5 million, detergent and a liquid vehicle, said coatable composition on drying forms a controlled detergent release composition which releases said detergent in a controlled manner when wet;

applying said coatable composition to a porous pad; and

drying said coatable composition to provide said controlled detergent release composition within said porous pad.

23. The process as defined in claim 22 wherein said detergent comprises surfactant selected from the group consisting or anionic surfactants, amphoteric surfactants, nonionic surfactants, cationic surfactants and mixtures of one or more of said surfactants;

blending said polyacrylamide and said detergent in water to provide said coatable composition with a polymer solids;

detergent solids weight ratio between about 1;

12 and about 1;

30.

24. The process as defined in claim 23 wherein said anionic surfactant is selected from the group consisting of sodium or ammonium salts of sulfonated alkyls, sulfonic acids, sulfated alkyl ethers, sulfated fatty esters and lauryl sulfates.

25. The process as defined in claim 23 wherein said amphoteric surfactant is selected from the group consisting of cocamidopropyl betaine, coco/oleoamidopropyl betaine and combinations thereof.

26. The process as defined in claim 23 wherein said nonionic surfactant is selected from the group consisting of ethoxylated amines and amides, fatty alkanolamides and combinations thereof.

27. The process as defined in claim 23 wherein said cationic surfactant is selected from the group consisting of lauramine oxide, lauramidopropylamine oxide, stearamide oxide and combinations thereof.

28. The process as defined in claim 23 wherein said polyacrylamide has a weight average molecular weight from about 5 million to about 15 million.

29. The process as defined in claim 22 wherein said pad comprises a material selected from the group consisting of sponge, paper, fabric, plastic fibers, plastic ribbons, metal fibers, metal ribbons, and composite structures incorporating one or more of the foregoing materials.

30. The process as defined in claim 22 wherein said applying comprises roll coating, spray coating, immersion coating or injection coating.

31. The process as defined in claim 22 wherein said drying is accomplished by heating.

32. The process as defined in claim 31 wherein said heating is accomplished in an oven at a temperature between about 93°

C. and about 149°

C. for between about 5 and about 45 minutes.