Copolyestercarbonate composition derived from dihydricphenol, carbonate precursor and alpha omega-dicarboxylic acid

• US 5,510,448 A
• Filed: 01/17/1995
• Issued: 04/23/1996
• Est. Priority Date: 12/22/1989
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Claesen, Christianus A. A., Quinn, Clayton V., van Es, Peter W., Fontane, Luca P., Miller, Kenneth F., Campbell, Richard W., de Vroomen, Theodorus O. N.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): BOYKIN, TERRESSA M
• Application Number:
  US08/373,155
• Time in Patent Office: 462 Days
• Field of Search: 528/179, 528/176, 528/480, 528/502, 528/125, 528/171, 528/185, 528/193, 528/196
• US Class Current: 528/196
• CPC Class Codes: C08G 63/64 Polyesters containing both carboxylic ester groups and carbonate groups
• CPC Class Codes: C08G 63/79 Interfacial processes, i.e. processes involving a reaction at the interface of two non-miscible liquids
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/2913 Rod, strand, filament or fiber
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

A composition comprising a copolyestercarbonate derived from a dihydric phenol, a carbonate precursor, and an aliphatic alpha omega dicarboxylic acid or ester precursor wherein the dicarboxylic acid or ester precursor has from 10 to about 20 carbon atoms, inclusive, and is present in the copolyestercarbonate in quantities of from about 2 to 30 mole percent of the dihydric phenol.

Claims

1. A composition comprising a copolyestercarbonate derived from a dihydric phenol, a carbonate precursor, and an aliphatic alpha omega dicarboxylic acid or ester precursor wherein the dicarboxylic acid or ester precursor has from 10 to about 20 carbon atoms, inclusive, is present in the copolyestercarbonate in quantities of from about 2 to 30 mole percent of the dihydric phenol and is converted to a salt before reaction with the dihydric phenol and the carbonate precursor and wherein the carbonate precursor is added over a period of time and, from about 0 to about 95% of the period of time, the pH of the reaction is from about 8 to 8.5 and, for the remainder of the period, the pH of the reaction is from about 10 to 12.

2. The composition in accordance with claim 1 wherein the dicarboxylic acid or ester precursor has from 10 to about 14 carbon atoms, inclusive.

3. The composition in accordance with claim 2 wherein the dicarboxylic acid has 10 carbon atoms.

4. The composition in accordance with claim 2 wherein the dicarboxylic acid has 12 carbon atoms.

5. The composition in accordance with claim 1 wherein the mole percent is from about 8 to 15 mole percent.

6. The composition in accordance with claim 2 wherein the mole percent is from about 8 to 15 mole percent.

7. A composition comprising a copolyester-carbonate having repeating units of the structure ##STR6## wherein:

R is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals;

R¹ is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals;

W is selected from divalent hydrocarbon radicals,

n and n¹ are independently selected from integers having a value of from 0 to 4 inclusive;

b is either zero or one;

X is an aliphatic group of about 8 to 18 carbon atoms, inclusive;

##STR7## c is from about 2 to 30 mole percent of the total units c+d and wherein the composition is derived from a dihydric phenol, a carbonate precursor, and an aliphatic alpha omega dicarboxylic acid or ester precursor wherein the dicarboxylic acid or ester precursor is converted to a salt before reaction with the dihydric phenol and the carbonate precursor and wherein the carbonate precursor is added over a period of time and, from about 0 to about 95% of the period of time, the pH of the reaction is from about 8 to 8.5 and, for the remainder of the period, the pH of the reaction is from about 10 to 12.

8. An extruded article prepared from the copolyester carbonate of claim 7.

9. An article in accordance with claim 8 prepared as a sheet form.

10. An article in accordance with claim 9 prepared in film form.

11. An article in accordance with claim 7 comprising at least 90 weight percent by weight of the copolyestercarbonate of claim 7.

12. The thermoformed sheet in accordance with claim 9.

13. The thermoformed film in accordance with claim 10.

14. The composition in accordance with claim 7 wherein the polymer has less than about 0.5 mole % anhydride.