Method for the routine identification of plastics

• US 5,510,619 A
• Filed: 11/18/1994
• Issued: 04/23/1996
• Est. Priority Date: 11/27/1993
• Status: Expired due to Term

• Current Assignee: Bruker Optics, Inc. (Bruker Corporation)
• Original Assignee: Bruker Analytische Mestechnik GmbH
• Inventors: Zachmann, Gunter, Simon, Arno, Schubel, Reiner, Gast, Jurgen
• Primary Examiner(s): Hannaher, Constantine
• Assistant Examiner(s): Tyler, Virgil O.
• Application Number:
  US08/342,355
• Time in Patent Office: 522 Days
• Field of Search: 250/339.08, 250/339.06, 250/339.07, 250/339.11, 250/341.8, 250/341.5
• US Class Current: 250/339.08
• CPC Class Codes: B07C 5/342 according to optical properties, e.g. colour according to radiation transmittivity B07C5/3416
• CPC Class Codes: G01N 2021/3595 using FTIR
• CPC Class Codes: G01N 21/3563 for analysing solids; Preparation of samples therefor
• CPC Class Codes: G01N 33/442 Resins, plastics

Abstract

A method for routine identification of materials of plastic components with the assistance of infrared spectroscopy with which an infrared reflection spectrum is taken from the surface of a plastic component to be investigated and compared to a set of reference spectra, whereby the material of the plastic component under investigation is correlated to a class of plastic materials represented by one of the reference spectrum, is characterized in that the plastic component under investigation is positioned with the assistance of a video device (25, 26) and in that the infrared reflection spectrum is recorded in the range of the mid-infrared (MIR) in a wave length region between 400 and 4,000 cm^-1. In this fashion even plastics which, for example, are filled with carbon can be routinely identified. It is preferred when the first derivative of the recorded IR spectrum with respect to wave number is taken and compared to the first derivative of the IR spectra of the reference spectra.

Claims

1. An infrared spectroscopy method for the routine identification of a plastic component in refuse for the purpose of recycling, comprising the steps of:

a) taking an IR reflection spectrum of the plastic component in the near infrared range (NIR) of wave numbers between 4,000 and 10,000 cm^-1 ;

b) comparing the spectrum of step a) to reference spectra;

c) selecting the plastic component if steps a) and b) do not lead to a unique identification;

d) guiding light from a mid-infrared range (MIR) source having a wave number range between 400 and 4000 cm^-1 through a Fourier transform infrared (FTIR) spectrometer;

e) focussing the light of step d) onto a surface region of the plastic component selected in step c);

f) passing light reflected from the surface region through onto a mid-infrared detector;

g) recording an MIR spectrum of the selected plastic component;

h) comparing the MIR spectrum to a set of reference spectra having a plurality of member spectra, each member spectrum corresponding to a class of plastic materials; and

i) correlating the selected plastic component to one member spectrum of one class of plastic materials.

2. The method of claim 1, wherein the spectrum includes at least the MIR range between 600 to 3,600 cm^-1.

3. The method of claim 1, wherein the spectrum spans an MIR range of less than 1,000 cm^-1.

4. The method of claim 1, wherein prior to the comparison with the reference spectra, a first derivative of the recorded IR spectrum with respect to wave number is taken and a corresponding derivative of the IR spectrum of reference substances is likewise utilized.

5. The method of claim 1, wherein both measurements in the NIR and MIR ranges are carried out with the same IR spectrometer, simultaneously or sequentially.

6. The method of claim 1, wherein the two measurements in the NIR and MIR ranges are carried out with two separate IR spectrometers.

7. The method of claim 1, wherein a surface coating present in the surface region of the plastic component under investigation is removed.

8. The method of claim 1, wherein before the measurement, a flat surface is produced in the surface region of the plastic component under investigation.

9. The method of the claim 1, wherein the plastic component under investigation is oriented in such a fashion that the IR light mirror-reflected from the surface region impinges via the second IR beam onto the detector.

10. An FTIR spectrometer for carrying out the method according to claim 1, wherein axes of the first and the second IR beams are each perpendicular to surfaces of the first and second windows respectively.

11. The FTIR spectrometer according to claim 10, wherein the angle between the axes of the two beams lies between 5°

and 30°

.

12. The FTIR spectrometer according to claim 10, wherein the windows comprise one of the materials KBr, KCl, ZnSe, KRS5, CaF₂, MgF₂.

13. The FTIR spectrometer according to claim 10, wherein the detector is a DTGS detector (deuterated triglycine sulfate).

14. The FTIR spectrometer according to claim 10, wherein the plastic component to be investigated is positioned with the assistance of the video device.

15. The FTIR spectrometer according to claim 14, wherein an endoscope with an attached video camera is provided for as the video device.

16. The FTIR spectrometer according to claim 14, wherein an endoscope is positioned between the two windows and is oriented perpendicularly to the plastic component to be investigated.

17. The FTIR spectrometer according to claim 14, wherein the plastic component to be investigated can be illuminated via an endoscope for purposes of positioning.

18. The FTIR spectrometer according to claim 14, wherein the plastic component to be investigated can be illuminated for purposes of positioning by an illumination device provided between the two windows.

19. The FTIR spectrometer according to claim 14, wherein additional visualization devices are provided for by means of which the plastic component to be investigated can be observed from the direction of the measuring position.

20. An infrared spectroscopy method for the routine identification of a plastic component in refuse for the purpose of recycling comprising the steps of:

a) taking an IR reflection spectrum of the plastic component in the near infrared range (NIR) of wave numbers between 4,000 and 10,000 cm^-1 ;

b) comparing the spectrum of step a) to reference spectra;

c) selecting the plastic component if steps a) and b) do not lead to a unique identification;

d) guiding light from a mid-infrared range (MIR) source having a wave number range between 400 and 4000 cm^-1 through a Fourier transform infrared (FTIR) spectrometer;

e) focussing the light of step d) as a first light beam through a first MIR transparent window in a direction perpendicular to a plane of the first window onto a surface region of the plastic component selected in step c);

f) passing light reflected from the surface region as a second light beam through a second MIR transparent window in a direction perpendicular to a plane of the second window onto a mid-infrared detector within the FTIR spectrometer, the first and second light beams having an opening angle between 5° and

30°

;

g) recording an MIR spectrum of the selected plastic component;

h) comparing the MIR spectrum to a set of reference spectra having a plurality of member spectra, each member spectrum corresponding to a class of plastic materials; and

i) correlating the selected plastic component to one member spectrum of one class of plastic materials.

21. An infrared spectroscopy method for the routine identification of a plastic component in refuse for the purpose of recycling comprising the steps of:

a) taking an IR reflection spectrum of the plastic component in the near infrared range (NIR) of wave numbers between 4,000 and 10,000 cm^-1 ;

b) comparing the spectrum of step a) to reference spectra;

c) selecting the plastic component if steps a) and b) do not lead to a unique identification;

d) positioning the selected plastic component with a video device, the video device comprising an endoscope and video camera;

e) guiding light from a mid-infrared range (MIR) source having a wave number range between 400 and 4000 cm^-1 through a Fourier transform infrared (FTIR) spectrometer;

f) focussing the light of step d) as a first light beam through a first MIR transparent window in a direction perpendicular to a plane of the first window onto a surface region of the plastic component selected in step c);

g) passing light reflected from the surface region as a second light beam through a second MIR transparent window in a direction perpendicular to a plane of the second window onto a mid-infrared detector within the FTIR spectrometer, the first and second light beams having an opening angle between 5° and

30°

;

h) recording an MIR spectrum of the selected plastic component;

i) comparing the MIR spectrum to a set of reference spectra having a plurality of member spectra, each member spectrum corresponding to a class of plastic materials; and

j) correlating the selected plastic component to one member of one class of plastic materials.