Fragrance extraction

• US 5,512,285 A
• Filed: 02/14/1994
• Issued: 04/30/1996
• Est. Priority Date: 02/22/1993
• Status: Expired due to Term

• Current Assignee: INEOS Fluor Holdings Limited (Orbia Advance Corporation, S.A.B. de C.V.)
• Original Assignee: Advanced Phytonics Limited
• Inventors: Wilde, Peter F.
• Primary Examiner(s): Robinson, Douglas W.
• Assistant Examiner(s): Lee, Howard C.
• Application Number:
  US08/195,786
• Time in Patent Office: 806 Days
• Field of Search: 424/195.1, 514/783
• US Class Current: 424/756
• CPC Class Codes: B01D 11/0288 Applications, solvents
• CPC Class Codes: C11B 9/025 Recovery by solvent extraction

Abstract

An improved process for extracting an organic component, including fragrant, flavorsome or pharmacologically active components, from an organic material of natural origin using tetrafluoroethane in the liquid phase as the solvent. The process essentially includes contacting the organic material with the tetrafluoroethane in its liquid phase, charging thereby the tetrafluoroethane with the organic component, collecting the mixture thereof, and removing the tetrafluoroethane therefrom so as to isolate the organic component. The process allows the more volatile components of plant derived materials, frequently lost by conventional methods of extraction, also to be extracted. The extracted components, as a result, bear a greater similarity to, and possess a larger number of the characteristics of the original material than conventionally obtained extracts.

Claims

1. A process for selectively extracting at least one natural organic component which is soluble in tetrafluoroethane from natural organic material containing the natural organic component, the process comprising

a) contacting the organic material in a vessel with liquid tetrafluoroethane solvent to dissolve the at least one organic component in the solvent

b) separating the solution of the at least one natural organic component in the solvent from the remaining organic material;

and

c) removing the solvent to isolate the at least one natural organic component.

2. The process of claim 1 wherein the tetrafluoroethane is 1,1,1,2-tetrafluoroethane.

3. The process of claim 2, wherein a solvent mixture containing the tetrafluoroethane is used to facilitate the selective dissolution of the at least one natural organic component.

4. The process of claim 2, wherein the material which is dissolved in the solvent is varied by varying the operating parameters of the process.

5. The process of claim 2, wherein the at least one organic component is a flavor or fragrance component.

6. The process of claim 2, wherein the process is conducted at a temperature no greater than about ambient temperature and in the substantial absence of air.

7. The process of claim 2, wherein the maximum pressure in the vessel in step a) reaches about 5.6 bar.

8. The process of claim 2, wherein the solvent is removed in step c) by evaporation to leave a solvent residue in the at least one natural organic component of no greater than about 0.02 ppm.

9. The process of claim 2, wherein the solvent further comprises at least one co-solvent.

10. The process of claim 2, wherein the temperature of the materials contacted in step a) is between -25°

C. and 40°

C.