Toners of different size for electrophotography

• US 5,512,406 A
• Filed: 10/12/1994
• Issued: 04/30/1996
• Est. Priority Date: 10/14/1993
• Status: Expired due to Term

• Current Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Original Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Inventors: Itoh, Nobuyuki, Takeda, Kenichi, Nakano, Masao, Kemmochi, Kazuhisa, Itoh, Isami, Tada, Tatsuya
• Primary Examiner(s): MARTIN, ROLAND E
• Application Number:
  US08/321,903
• Time in Patent Office: 566 Days
• Field of Search: 430/110, 430/111
• US Class Current: 430/110.4
• CPC Class Codes: G03G 9/0819 characterised by the dimensions of the particles
• CPC Class Codes: G03G 9/097 Plasticisers; Charge controlling agents
• CPC Class Codes: G03G 9/09708 Inorganic compounds
• CPC Class Codes: G03G 9/09725 Silicon-oxides; Silicates

Abstract

A toner for electrophotography, comprising toner particles and an additive, is obtained by mixing toners A and B together which are obtained by respectively adding the additive to each of at least two toner particle groups (a) and (b) having different particle size distributions. The average particle size of the toner particle group (a) is smaller than that of the toner particle group (b), and the amount of additive in the toner A is larger than that in the toner B. The toner reduces the differences in development conditions between different particle sizes due to broadening of toner particle size distribution, thereby enabling a stable image quality to be obtained which maintains a high image density for an extended period of time and is relatively free from fog generation in non-image portions.

Claims

1. A toner for electrophotography comprising:

a first toner A comprising a toner particle group (a) having a first particle size distribution and an external additive; and

a second toner B comprising a toner particle group (b) having a second particle size distribution different from said first particle size distribution and an external additive;

wherein said toner particle group (a) has a smaller average particle size than that of said toner particle group (b) and the amount of said external additive in said first toner A is greater than the amount of said external additive in said second toner B, and

said external additive comprises at least one kind of fine particles selected from the group consisting of silica, titanium oxide, molybdenum disulfide, tungsten disulfide, boron nitride, lead oxide, antimony oxide, strontium sulfate, aluminum sulfate, calcium carbonate, strontium titanate, cerium oxide, strontium oxide, a metallic salt of a higher fatty acid, graphite, barium fluoride, calcium fluoride, carbon fluoride, carbon black, conductive tin oxide, styrene homopolymer powder, substituted styrene homopolymer powder, styrene copolymer powder, polymethyl methacrylate powder, polybutyl methacrylate powder, polyvinyl chloride powder, polyvinyl acetate powder, polyethylene powder, polypropylene powder, polyester powder, polyurethane powder, polyamide powder, epoxy resin powder, polyvinyl butyral powder, polyacrylic resin powder, rosin powder, denatured rosin powder, terpene resin powder, phenol resin powder, aliphatic hydrocarbon resin powder, alicyclic hydrocarbon resin powder, aromatic petroleum resin powder, chlorinated paraffin powder, paraffin wax powder, polytetrafluoroethylene powder and polyvinylidene fluoride powder.

2. A toner according to claim 1, wherein said toner particle group (a) and (b) are obtained by classifying a toner particle group having a specific particle size distribution into said toner particle group (a) having a small average particle size and said toner particle group (b) having a large average particle size.

3. A toner according to claim 1, wherein said toner particle groups (a) and (b) are separately prepared.

4. A toner according to claim 1, wherein said toner particle group (a) has a number average particle size of 2 to 8 μ

m, said toner particle group (b) has a number average particle size of 5 to 12 μ

m, and said toner has a number average particle size of 2 to 12 μ

m.

5. A toner according to claim 4, wherein said toner particle group (a) has a number average particle size of 3 to 7 μ

m, said toner particle group (b) has a number average particle size of 6 to 9 μ

m, and said toner has a number average particle size of 3 to 9 μ

m.

6. A toner according to claim 1, wherein the load at which said toners A and B are mixed together is smaller than the load at which said toner particle groups (a) and (b) are mixed with the external additive, respectively.

7. The toner according to claim 1, wherein said substituted styrene homopolymer powder is selected from the group consisting of poly-p-chlorostyrene powder and polyvinyl toluene powder.

8. The toner according to claim 1, wherein said styrene copolymer powder is selected from the group consisting of styrene-p-chlorostyrene copolymer powder, styrene-vinyltoluene copolymer powder, styrenevinylnapthalene copolymer powder, styrene-methyl-acrylate copolymer powder, styrene-ethyl-acrylate copolymer powder, styrene-butyl-acrylate copolymer powder, styrene-acryl-2-ethylhexyl copolymer powder, styrene-octyl-acrylate copolymer powder, styrene-methyl-methacrylate copolymer powder, styrene-ethyl-methacrylate copolymer powder, styrene-butyl-methacrylate copolymer powder, styrene-α

-methyl-chloromethacrylate copolymer powder, styrene-acrylonitrile copolymer powder, styrene-vinyl-methyl-ether copolymer powder, styrene-vinyl-methyl-ketone copolymer powder, styrene-butadiene copolymer powder, styrene-isoprene copolymer powder, styrene-actylonitrile-indene copolymer powder, styrene-maleic-acid copolymer powder, and styrene-maleate copolymer powder.

9. The toner according to claim 1, wherein said metallic salt of a higher fatty acid is zinc stearate.