Cathode material for use in an electrochemical cell and method for preparation thereof

• US 5,514,492 A
• Filed: 06/02/1995
• Issued: 05/07/1996
• Est. Priority Date: 06/02/1995
• Status: Expired due to Fees

• Current Assignee: Pacesetter Incorporated (Abbott Laboratories Incorporated)
• Original Assignee: Pacesetter Incorporated (Abbott Laboratories Incorporated)
• Inventors: Marincic, Nikola, Rabadjija, Luka
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/459,685
• Time in Patent Office: 340 Days
• Field of Search: 429/209, 429/212, 429/217, 429/215, 429/216, 429/94, 429/194, 29/623.5, 29/623.1
• US Class Current: 429/217
• CPC Class Codes: H01M 2006/106 Elliptic wound cells
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0402 Methods of deposition of the material
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0416 involving impregnation with a solution, dispersion, paste or dry powder H01M4/0438 takes precedence
• CPC Class Codes: H01M 4/043 involving compressing or compaction
• CPC Class Codes: H01M 4/5835 Comprising fluorine or fluoride salts
• CPC Class Codes: H01M 4/621 Binders
• CPC Class Codes: H01M 50/103 prismatic or rectangular H01M50/109, H01M50/11 take precedence
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

A cathode material is fabricated using two binder compounds, polyethylene oxide and acrylic resin, which react during processing to achieve enhanced bonding. The cathode material is formed by dissolving acrylonitril resin within the acetonitrile solvent. Polyethylene oxide powder is added yielding a homogenous solution. A powder mix containing a carbon material, such as high surface area carbon powder, and an active cathode compound, such as polycarbon monoflouride, is added to the binder mixture to produce a slurry. In one embodiment, the slurry is heated to evaporate the solvents, yielding a thin flexible cathode material for mounting to an expanded screen current collector. In an alternative embodiment, the slurry is spread directly onto a foil current collector. The solvents thereafter evaporate from the slurry yielding excellent mechanical and electrical coupling between the active cathode compound and the current collector. The resulting cathode structure and a lithium anode structure are mounted to opposing sides of a polymeric separator for use within an electrochemical cell of an implantable medical device.

Claims

1. A method for preparing a cathode material for use in an electrochemical cell of an implantable device, the method comprising the steps of:

mixing a first binding material with a liquid solvent to produce a solution, wherein the first binding material is soluble in the solvent;

adding a second binding material to the solution, wherein the second binding material is also soluble in the solvent; and

adding carbon and an active cathode compound to the solution forming a cathode material;

wherein the first and second binding materials are selected from a group of binding materials soluble in the solvent to react with each other.

2. The method of claim 1, wherein the first binding material is acrylonitril resin, the second binding material is poly ethyhylene oxide and the solvent is acetonitrile.

3. The method of claim 1, further comprising the step of forming a cathode structure by:

heating the cathode material until a portion of the solvent has evaporated and the cathode material achieves a spreadable consistency;

spreading the cathode material onto a metal surface until dry, yielding a flexible film; and

mounting the flexible film to a current collector.

4. The method of claim 3, wherein the current collector is an expanded screen current collector.

5. The method of claim 1, further comprising the step of forming a cathode structure by:

spreading the cathode material onto a metal foil current collector before a substantial portion of the solvent within the cathode material evaporates; and

allowing the solvent to evaporate from the cathode material while the cathode material is spread on the metal foil current collector.

6. The method according to claim 1, wherein the active cathode compound is selected from a group consisting of manganese dioxide, polycarbon monoflouride, cobalt oxide, and nickel oxide.

7. The method of claim 1, wherein the first and second binding materials are provide in quantities of 2 percent to 15 percent by weight of the active cathode compound.

8. A cathode material for use in an electrochemical cell of an implantable device, wherein the cathode material is prepared by performing the steps of:

mixing a first binding material with a liquid solvent to produce a solution, wherein the first binding material is soluble in the solvent;

adding a second binding material to the solution, wherein the second binding material is also soluble in the solvent; and

adding carbon and an active cathode compound to the solution forming a cathode material;

wherein the first and second binding materials are selected from a group of binding materials soluble in the solvent to react with each other.

9. The cathode material of claim 8, wherein the first binding material is acrylonitril resin, the second binding material is poly ethyhylene oxide and the solvent is acetonitrile.

10. The cathode material of claim 8, prepared with the further steps of:

heating the cathode material until a portion of the solvent has evaporated and the cathode material achieves a spreadable consistency;

spreading the cathode material onto a metal surface until dry, yielding a flexible film; and

mounting the flexible film to a current collector.

11. The cathode material of claim 9, wherein the current collector is an expanded screen current collector.

12. The method of claim 8, prepared with the further steps of:

spreading the cathode material onto a metal foil current collector before a substantial portion of the solvent within the cathode material evaporates; and

allowing the solvent to evaporate from the cathode material while the cathode material is spread on the metal foil current collector.

13. The cathode structure of claim 8, wherein the active cathode compound is selected from a group consisting of manganese dioxide, polycarbon monoflouride, cobalt oxide, and nickel oxide.

14. The cathode material of claim 8, wherein the first and second binding materials are provide in quantities of 2 percent to 15 percent by weight of the active cathode compound.

16. The electrochemical cell of claim 14, wherein the current collector is an expanded screen current collector.

17. The electrochemical cell of claim 14, wherein the active material is selected from a group consisting of manganese dioxide, polycarbon monoflouride, cobalt oxide, and nickel oxide.

18. The electrochemical cell of claim 14, wherein the first and second binding materials are provide in quantities of 2 percent to 15 percent by weight of the active cathode compound.

19. The electrochemical cell of claim 14, wherein the anode comprises lithium.

15. An electrochemical cell for use in an implantable device, the electrochemical cell comprising:

an electrode structure comprising;

a cathode structure having a cathode material mounted on a metal current collector, the cathode material formed of acrylonitril resin and poly ethyhylene oxide, carbon and an active cathode compound,

an anode, and

a separator between the anode and the cathode;

a housing surrounding the electrode structure; and

a non-aqueous electrolyte filling a portion of the housing.