Composite mirrors

• US 5,517,338 A
• Filed: 10/20/1992
• Issued: 05/14/1996
• Est. Priority Date: 10/20/1992
• Status: Expired due to Fees

• Current Assignee: Laird Technologies Incorporated (DuPont de Nemours, Inc.)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Vaughn, George D., Graham, Charles R.
• Primary Examiner(s): Epps, Georgia Y.
• Assistant Examiner(s): PAPALAS, MICHAEL
• Application Number:
  US07/963,650
• Time in Patent Office: 1,302 Days
• Field of Search: 359/1, 359/15, 359/566, 359/572, 428/208, 428/209, 427/304, 427/404, 369/100, 369/103
• US Class Current: 359/15
• CPC Class Codes: C23C 18/08 characterised by the deposition of metallic material
• CPC Class Codes: C23C 18/143 Radiation by light, e.g. photolysis or pyrolysis

Abstract

Composite mirrors on a substrate comprising a mixture of up to 20 percent of polymer and at least 80 percent of metal clusters, e.g. of gold, palladium or silver, which have a nominal diameter less than 100 nanometers and which are agglomerated in a layer conforming to the surface of the substrate. Composite mirrors are produced by coating a substrate with a solution comprising at least 80 percent solvent, e.g. water and alcohol, and up to 20 percent of a mixture of up to 20 percent polymer, e.g. methylcellulose, and at least 80 percent metal, present as a salt of volatiles-forming anion, e.g. silver lactate or palladium acetate; dry films of polymer and salt are exposed to heat or ultraviolet light to convert the salt to metal clusters. Polymeric mirrors are especially useful for making reflection holograms on polymeric surfaces embossed with a latent holographic image in a relief pattern.

Claims

1. A hologram comprising a polymeric substrate having a relief-patterned, image-forming surface coated with a light-reflecting composite mirror layer consisting of a mixture of a up to 20 weight percent of polymer and at least 80 weight percent of metal clusters having a nominal diameter less than 100 nanometers, wherein said metal clusters are agglomerated in a layer conforming to said relief-patterned, image-forming surface so that light reflects from said mirror in a holographic image.

2. A hologram according to claim 1 wherein said clusters are generally spherical and have an average diameter less than 50 nanometers.

3. A hologram according to claim 1 printed on a security document.