Electrochemical sensors for motor oils and other lubricants

• US 5,518,590 A
• Filed: 06/21/1994
• Issued: 05/21/1996
• Est. Priority Date: 06/21/1994
• Status: Expired due to Fees

• Current Assignee: Pennzoil Products Co. (Shell Plc)
• Original Assignee: Pennzoil Products Co. (Shell Plc)
• Inventors: Fang, Jiafu
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US08/263,342
• Time in Patent Office: 700 Days
• Field of Search: 204/153.1, 204/415, 204/418, 204/412, 324/71.1, 324/439, 422/68.1, 422/82.01, 422/82.02, 422/82.03
• US Class Current: 205/780.5
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A sensitive and rapid electrochemical sensor monitors motor oil deterioration, particularly antioxidation property, by determining the antioxidant and antiwear agent level remaining in an oil formulation. The electrochemical sensor is a two- or three-electrode electrochemical cell having a conductive electrolyte liquid or gel-like interphase over the electrode surfaces. The degree of deterioration of a motor oil in service is monitored by measurements of antioxidation or antiwear capacity of the oil. The electrochemical sensor can be used for monitoring other lubricants and hydrocarbons which contain electroactive additives. The electrochemical sensor allows measurements to be performed in-situ, without any chemical or physical pretreatment of the oil.

Claims

1. A method of detecting electroactive components in a nonconductive environment which comprises:

a) providing an electrochemical sensor having at least two electrodes and a conductive liquid or gel interphase covering each of said at least two electrodes, said liquid or gel interphase is positioned between said at least two electrodes and a nonconductive environment containing electroactive components;

b) contacting the conductive liquid or gel interphase with said nonconductive environment containing electroactive components;

c) allowing said electroactive components in said nonconductive environment to pass through the conductive liquid or gel interphase of the electrochemical cell; and

d) utilizing the electrochemical cell to measure the concentration of said electroactive components in the conductive interphase.

2. The method according to claim 1, wherein said conductive liquid or gel interphase comprises an electrolyte solution.

3. The method according to claim 2, wherein said electrolyte comprises a lithium or sodium perchlorate salt solution, or other organic salts, of concentration between 10^-4 M to 1M.

4. The method according to claim 3, wherein said salt is soluble in an organic solvent.

5. The method according to claim 4, wherein said organic solvent comprises a polar solvent or mixture of solvents which has a medium or high dielectric constant, a large electrochemical window, solubilizes the electrolyte chosen, and selectively extracts the electroactive components in an oil phase while not being miscible with the oil phase.

6. The method according to claim 5, wherein said organic solvent is selected from the group consisting of acetonitrile and C₁ to C₅ alkanols.

7. The method according to claim 6, wherein the C₁ to C₅ alkanols are methanol, ethanol or propanol.

8. The method according to claim 3, wherein said salt comprises tetrabutyl ammonium tetrafluoro borate and is present at a concentration of about 10 ^-3 M up to 10 hu -1M.

9. The method according to claim 2, wherein said electrolyte comprises lithium or sodium perchlorate in an acetonitrile solvent.

10. The method according to claim 1, wherein said nonconductive environment comprises a hydrocarbon lubricant.

11. The method according to claim 1, wherein said electroactive components comprise antioxidant and/or antiwear agent.

12. The method according to claim 1, further comprising a hydrophilic membrane covering said conductive liquid or gel interphase.

18. The sensor according to claim 7, wherein said at least two electrodes comprise three electrodes.

19. The sensor according to claim 7, further comprising a hydrophilic membrane covering said conductive liquid or gel interphase.

20. The sensor according to claim 19, wherein said salt is tetrabutyl ammonium tetrafluoro borate and is present at a concentration of about 10^-3 M up to 10^-1 M.

13. A sensor for detecting electroactive components in a nonconductive environment which comprises:

at least two electrodes; and

a liquid conductive or gel conductive interphase covering said at least two electrodes, said conductive liquid or gel conductive interphase comprising an electrolyte solution which is selectively permeable to electroactive components of a nonconducting environment.

14. The sensor according to claim 13, wherein said electrolyte solution is selectively permeable to antioxidants and antiwear agents.

15. The sensor according to claim 13, wherein said electrolyte comprises a lithium or sodium perchlorate salt solution.

16. The sensor according to claim 15, wherein said salt is soluble in an organic solvent.

17. The sensor according to claim 16, wherein said electrolyte comprises a solution of-lithium perchlorate salt in an acetonitrile solvent.